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Start Over Author "Fan, Shuaixin" Topic palladium
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1. Palladium-catalyzed coupling of amides and cyclopropanols for the synthesis of γ-diketones.

Author

Fang, Lili, Jia, Shuqi, Fan, Shuaixin, and Zhu, Jin

Subjects
AMIDES, PALLADIUM, ACHIEVEMENT
Abstract

A palladium catalytic method has been developed for the coupling of amides and cyclopropanols to γ-diketones, through simultaneous C–N and C–C activation. Heteroatom ligand exchange and heteroatom-to-carbon ligation mode switching enable the achievement of molecular cross-coupling in an amide N-atom structural context-dependent manner, avoiding any stoichiometric organometallic reagent or base. [ABSTRACT FROM AUTHOR]

Published
2023
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