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The Borkewehr section near Balve at the southeastern end of the Remscheid-Altena Anticline is currently the best and most complete Devonian/Carboniferous Boundary (DCB) succession of the Rhenish Massif, Germany. Based on a multidisciplinary approach, focusing on refined conodont and ammonoid biostratigraphy, microfacies analyses, sequence stratigraphy, carbon isotopes (Corg and Ccarb), trace element geochemistry, including REE data, and cyclostratigraphy, the section is proposed as a candidate for the new basal Carboniferous GSSP. The succession represents a pelagic “seamount” setting. It spans the upper Famennian to lower Viséan, with a condensed development of most Rhenish lithostratigraphic units and sedimentary sequences. It is the type-section of the oxic and strongly cyclic, fossiliferous Wocklum Limestone and of important uppermost Famennian and basal Carboniferous index species. The First Appearance Datum (FAD) of Protognathodus kockeli s.str., in a phylogenetic succession from the ancestral Pr. semikockeli n. sp., is proposed as future GSSP level. This FAD is sandwiched between many other marker levels for global correlation. Below are, from base to top, the transgressive base of the at least partly anoxic Hangenberg Black Shale (base Lower Hangenberg Crisis Interval), the Hangenberg Regression (onset of siltstones of the basal Middle Crisis Interval), the level of maximum regression, indicated by maximum Zr/Al values, and the initial transgression of the basal Upper Crisis Interval, marked by the re-onset of carbonate deposition. Above follow the locally cryptogenic FAD of Siphonodella (Eosiphonodella) sulcata s.l. at the base of the post-Crisis Interval (Hangenberg Limestone), associated with a conodont biofacies shift, the FAD of Si. (Eo.) bransoni, and, much higher, the sharp Lower Alum Shale Event at the base of the classical middle Tournaisian. The significance of the section is greatly enlarged by its precise correlation with numerous other Rhenish DCB sections that provide important additional data on faunas, geochemistry, geochronological ages, and magnetic susceptibility. The new Borkewehr data suggest changes of weathering intensity, based on Rb/K and K/Al trends, and Milankovitch cyclicity associated with the climate changes of the Hangenberg Crisis. The local conodont extinction rate at the top of the Wocklum Limestone lies at 57 % while there are no survivors in ammonoids, trilobites, or deep-water corals. Positive carbon isotopic shifts of carbonate in the Upper Crisis Interval and of Corg in the Middle Crisis Interval are decoupled, which suggests complex underlying processes that are not yet understood.

Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High-resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well-suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408-U1410 are highly complex with several hiatuses. Here, we built a two-site composite and constructed a conservative age-depth model to provide a reliable chronology for this rhythmic, highly resolved (

The Pliocene sedimentary record provides a window into Earth's climate dynamics under warmer-than-present boundary conditions. However, the Pliocene cannot be considered a stable warm climate that constitutes a solid baseline for middle-of-the-road future climate projections. The increasing availability of time-continuous sedimentary archives (e.g., marine sediment cores) reveals complex temporal and spatial patterns of Pliocene ocean and climate variability on astronomical timescales. The Perth Basin is particularly interesting in that respect because it remains unclear if and how the Leeuwin Current sustained the comparably wet Pliocene climate in Western Australia, as well as how it influenced Southern Hemisphere paleoclimate variability. To constrain Leeuwin Current dynamics in time and space, this project obtained eight clumped-isotope Δ47 paleotemperatures and constructed a new orbitally resolved planktonic foraminifera (Trilobatus sacculifer) stable isotope record (δ18O) for the Plio-Pleistocene (4–2 Ma) interval of International Ocean Discovery Program (IODP) Site U1459. These new data complement an existing TEX86 record from the same site and similar planktonic isotope records from the Northern Carnarvon Basin (Ocean Drilling Program (ODP) Site 763 and IODP Site U1463). The comparison of TEX86 and Δ47 paleothermometers reveals that TEX86 likely reflects sea surface temperatures (SSTs) with a seasonal warm bias (23.8–28.9 ∘C), whereas T. sacculifer Δ47 calcification temperatures probably echo mixed-layer temperatures at the studied Site U1459 (18.9–23.2 ∘C). The isotopic δ18O gradient along a 19–29∘ S latitudinal transect, between 3.9 and 2.2 Ma, displays large variability, ranging between 0.5 ‰ and 2.0 ‰. We use the latitudinal δ18O gradient as a proxy for Leeuwin Current strength, with an inverse relationship between both. The new results challenge the interpretation that suggested a tectonic event in the Indonesian Throughflow as the cause for the rapid steepening of the isotopic gradient (0.9 ‰ to 1.5 ‰) around 3.7 Ma. The tectonic interpretation appears obsolete as it is now clear that the 3.7 Ma steepening of the isotopic gradient is intermittent, with flat latitudinal gradients (∼0.5 ‰) restored in the latest Pliocene (2.9–2.6 Ma). Still, the new analysis affirms that a combination of astronomical forcing of wind patterns and eustatic sea level controlled Leeuwin Current intensity. On secular timescales, a period of relatively weak Leeuwin Current is observed between 3.7 and 3.1 Ma. Notably, this interval is marked by cooler conditions throughout the Southern Hemisphere. In conclusion, the intensity of the Leeuwin Current and the latitudinal position of the subtropical front are both long-range effects of the same forcing: heat transport through the Indonesian Throughflow (ITF) valve and its propagation through Indian Ocean poleward heat transport. The common ITF forcing explains the observed coherence of Southern Hemisphere ocean and climate records.

Ocean gateways facilitate circulation between ocean basins, thereby impacting global climate. The Indonesian Gateway transports water from the Pacific to the Indian Ocean via the Indonesian Throughflow (ITF) and drives the strength and intensity of the modern Leeuwin Current, which carries warm equatorial waters along the western coast of Australia to higher latitudes. Therefore, ITF dynamics are a vital component of global thermohaline circulation. Plio‐Pleistocene changes in ITF behavior and Leeuwin Current intensity remain poorly constrained due to a lack of sedimentary records from regions under its influence. Here, organic geochemical proxies are used to reconstruct sea surface temperatures on the northwest Australian shelf at IODP Site U1463, downstream of the ITF outlet and under the influence of the Leeuwin Current. Our records, based on TEX86 and the long‐chain diol index, provide insight into past ITF variability (3.5–1.5 Ma) and confirm that sea surface temperature exerted a control on Australian continental hydroclimate. A significant TEX86 cooling of ~5°C occurs within the mid‐Pliocene Warm Period (3.3–3.1 Ma) suggesting that this interval was characterized by SST fluctuations at Site U1463. A major feature of both the TEX86 and long‐chain diol index records is a strong cooling from ~1.7 to 1.5 Ma. We suggest that this event reflects a reduction in Leeuwin Current intensity due to a major step in ongoing ITF constriction, accompanied by a switch from South to North Pacific source waters entering the ITF inlet. Our new data suggest that an additional ITF constriction event may have occurred in the Pleistocene.

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

International audience; The geologic time scale for the Cenozoic Era has been notably improved over the last decades by virtue of integrated stratigraphy, combining high-resolution astrochronologies, biostratigraphy and magnetostratigraphy with high-precision radioisotopic dates. However, the middle Eocene remains a weak link. The so-called “Eocene time scale gap” reflects the scarcity of suitable study sections with clear astronomically-forced variations in carbonate content, primarily because large parts of the oceans were starved of carbonate during the Eocene greenhouse. International Ocean Discovery Program (IODP) Expedition 369 cored a carbonate-rich sedimentary sequence of Eocene age in the Mentelle Basin (Site U1514, offshore southwest Australia). The sequence consists of nannofossil chalk and exhibits rhythmic clay content variability. Here, we show that IODP Site U1514 allows for the extraction of an astronomical signal and the construction of an Eocene astrochronology, using 3-cm resolution X-Ray fluorescence (XRF) core scans. The XRF-derived ratio between calcium and iron content (Ca/Fe) tracks the lithologic variability and serves as the basis for our U1514 astrochronology. We present a 16 million-year-long (40-56 Ma) nearly continuous history of Eocene sedimentation with variations paced by eccentricity and obliquity. We supplement the high-resolution XRF data with low-resolution bulk carbon and oxygen isotopes, recording the long-term cooling trend from the Paleocene-Eocene Thermal Maximum (PETM – ca. 56 Ma) into the middle Eocene (ca. 40 Ma). Our early Eocene astrochronology corroborates existing chronologies based on deep-sea sites and Italian land sections. For the middle Eocene, the sedimentological record at U1514 provides a single-site geochemical backbone and thus offers a further step towards a fully integrated Cenozoic geologic time scale at orbital resolution.

A high-resolution potassium content record of sediments from Integrated Ocean Drilling Program (IODP) Site U1422 drilled in the northern Sea of Japan was employed to yield an astronomical timescale for this ∼205 m thick sedimentary archive. The K content was quantified using the natural gamma radiation (NGR) data routinely measured on DV JOIDES Resolution. The U1422 K (wt.%) series shows an increasing trend with time, which parallels the growth of North Hemisphere ice sheets since ∼4 Ma, as revealed by the global benthic foraminifer's oxygen isotope stack (LR04). We propose that K content variations reflect changes in the relative contributions of Asian eolian dust and volcanic weathering products, in response to changes in global ice volume. Using the shipboard age model, constrained by palaeomagnetism and nanofossils datums, we tuned the U1422 K content variations to the LR04 stack. Our tuned age model for site U1422 goes back to 3.9 Ma. The studied record indicates that Asian dust generation is enhanced during periods of global cooling. The synchronous variations between the U1422 K record and the LR04 stack also suggest that global cooling played a dominant role in promoting the central Asian aridification since ∼3.9 Ma, while the uplift of Tibetan Plateau plays a secondary role, considering many disagreements still exists between the timing and amplitude of the Qinghai-Tibetan uplift and the evolution of central Asian aridity since the early Pliocene.

North Atlantic Deep Water (NADW) currently redistributes heat and salt between Earth's ocean basins, and plays a vital role in the ocean-atmosphere CO2 exchange. Despite its crucial role in today's climate system, vigorous debate remains as to when deep-water formation in the North Atlantic started. Here, we present datasets from carbonate-rich middle Eocene sediments from the Newfoundland Ridge, revealing a unique archive of paleoceanographic change from the progressively cooling climate of the middle Eocene. Well-defined lithologic alternations between calcareous ooze and clay-rich intervals occur at the ∼41-kyr beat of axial obliquity. Hence, we identify obliquity as the driver of middle Eocene (43.5–46 Ma) Northern Component Water (NCW, the predecessor of modern NADW) variability. High-resolution benthic foraminiferal δ 18 O and δ 13 C suggest that obliquity minima correspond to cold, nutrient-depleted, western North Atlantic deep waters. We thus link stronger NCW formation with obliquity minima. In contrast, during obliquity maxima, Deep Western Boundary Currents were weaker and warmer, while abyssal nutrients were more abundant. These aspects reflect a more sluggish NCW formation. This obliquity-paced paleoceanographic regime is in excellent agreement with results from an Earth system model, in which obliquity minima configurations enhance NCW formation.

The Pliocene was characterized by a gradual shift of global climate toward cooler and drier conditions. This shift fundamentally reorganized Earth's climate from the Miocene state toward conditions similar to the present. During the Pliocene, the progressive restriction of the Indonesian Throughflow (ITF) is suggested to have enhanced this shift toward stronger meridional thermal gradients. Reduced ITF, caused by the northward movement of Australia and uplift of Indonesia, impeded global thermohaline circulation, also contributing to late Pliocene Northern Hemisphere cooling via atmospheric and oceanographic teleconnections. Here we present an orbitally tuned high-resolution sediment geochemistry, calcareous nannofossil, and X-ray fluorescence record between 3.65 and 2.97 Ma from the northwest shelf of Australia within the Leeuwin Current. International Ocean Discovery Program Site U1463 provides a record of local surface water conditions and Australian climate in relation to changing ITF connectivity. Modern analogue-based interpretations of nannofossil assemblages indicate that ITF configuration culminated similar to 3.54 Ma. A decrease in warm, oligotrophic taxa such as Umbilicosphaera sibogae, with a shift from Gephyrocapsa sp. to Reticulofenestra sp., and an increase of mesotrophic taxa (e.g., Umbilicosphaera jafari and Helicosphaera spp.) suggest that tropical Pacific ITF sources were replaced by cooler, fresher, northern Pacific waters. This initial tectonic reorganization enhanced the Indian Oceans sensitivity to orbitally forced cooling in the southern high latitudes culminating in the M2 glacial event (similar to 3.3 Ma). After 3.3 Ma the restructured ITF established the boundary conditions for the inception of the Sahul-Indian Ocean Bjerknes mechanism and increased the response to glacio-eustatic variability.

In this paper we formulate answers to three important questions related to Givetian carbonate records and their use for reconstructing million-year-scale past palaeoenvironmental changes. First, we provide detailed illustrations of the fascinating diversity that shaped a significant shallow reefal platform during early to late Givetian time in the Rhenohercynian Ocean; secondly we improve the sedimentological model of the extensive Givetian carbonate platform in the Dinant Basin; and thirdly we evaluate the application of magnetic susceptibility as a tool for long-term trend correlations and palaeoenvironmental reconstructions. These goals are reached by making a sedimentological, geophysical and geochemical study of the La Thure section. Through the early–late Givetian interval we discerned 18 microfacies ranging from a homoclinal ramp to a discontinuously rimmed shelf and then a drowning shelf. The comparison of these sedimentological results with those published for the south of the Dinant Syncline allowed us to provide an up to date model of the vertical and lateral environmental development of one of the largest Givetian carbonate platforms in Europe. This comparison also increased the knowledge on the distribution of facies belts in the Dinant Basin and allowed us to highlight the Taghanic Event. Palaeoredox proxies reveal a substantial change in the oxygenation level, from oxygen-depleted to more oxic conditions, between middle and late Givetian time. We demonstrated the relationship between variation in magnetic susceptibility values and proxies for siliciclastic input (such as Si, Al). The La Thure section is considered a key section for the understanding of internal shelf settings bordering Laurussia9s southeastern margin.

A detailed paleoenvironment reconstruction from the Mozambique Channel, western Indian Ocean, based on the calcareous nannoplankton assemblages was conducted for the interval between 2.85 and 1.85 Myr. This study covers the period during which the successive extinction of the last five species of discoasters occurred. New productivity data obtained from the abundances of the Discoaster species (Discoaster brouweri, D. triradiatus, D. pentaradiatus, D. surculus, and D. tamalis) and other indicative calcareous nannoplankton taxa showed abundance variations, which were at paced with the 100, 41, and 23 kyr astronomical periodicities. A shift in the productivity and water-column stratification proxies occurred at ~2.4 Ma, after the onset of the Northern Hemisphere glaciation. Here we propose that the variability recorded at International Ocean Discovery Program Site U1476 reflects the interplay between forcing associated with warm tropical Pacific and cold southern ocean influences. The former is shown by consistent occurrence of warm water taxa (Calcidiscus leptoporus, Oolithotus spp., Rhabdosphaera clavigera, Syracosphaera spp., Umbellosphaera spp.), typical of Indonesian Throughflow surface waters. On the other hand, the occurrence of Coccolithus pelagicus indicates the influence of cold, nutrient-rich sub-Antarctic surface waters. A more mixed water column initiated at ~2.4 Ma, and a consequent productivity increase led to the gradual reduction of the Discoaster species, until their extinction at 1.91 Ma. This period was characterized by the low values of the Florisphaera profunda index and high abundances of upper photic zone flora, indicative of nutrient-rich surface water conditions. High productivity at the location during this period could have also been amplified by localized upwelling events driven by the Mozambique Channel eddies.

The Frasnian–Famennian boundary records one of the most catastrophic mass extinctions of the Phanerozoic Eon. Several possible causes for this extinction have been suggested, including extra-terrestrial impacts and large-scale volcanism. However, linking the extinction with these potential causes is hindered by the lack of precise dating of either the extinction or volcanic/impact events. In this study, a bentonite layer in uppermost-Frasnian sediments from Steinbruch Schmidt (Germany) is re-analysed using CA-ID-TIMS U-Pb zircon geochronology in order to constrain the date of the Frasnian–Famennian extinction. A new age of 372.36 ± 0.053 Ma is determined for this bentonite, confirming a date no older than 372.4 Ma for the Frasnian–Famennian boundary, which can be further constrained to 371.93–371.78 Ma using a pre-existing Late Devonian age model. This age is consistent with previous dates, but is significantly more precise. When compared with published ages of the Siljan impact crater and basalts produced by large-scale volcanism, there is no apparent correlation between the extinction and either phenomenon, not clearly supporting them as a direct cause for the Frasnian–Famennian event. This result highlights an urgent need for further Late Devonian geochronological and chemostratigraphic work to better understand the cause(s) of this extinction.

Cyclostratigraphic analyses rely on techniques that trace astronomical components in paleoclimate signals. These techniques have demonstrated their value but rely on certain assumptions on the presence and quality of the astronomical imprint. Here we explore a new conceptual approach to time series analysis. Specifically, we evaluate the potential of spectral moments to characterize the full spectral characteristics of a record and thus not only the frequency ranges of interpreted astronomical components. Mathematically speaking, moments are unique quantities describing a specific set of points. In the case of spectral moments, we apply the concept of moments on the distribution of spectral power in a signal's periodogram. We present four case studies that illustrate the advantages and disadvantages of the spectral moment approach in gaining insight in the (astronomical) features of a particular data record. We discuss the effects of outliers in a series, variable sedimentation rate, and changing climate dynamics on the spectral moments of a power spectrum. At the same time, we carry out a sedimentation rate reconstruction based on the spectral moment approach and compare that reconstruction to results obtained through classic approaches. Compared to classic approaches, the spectral moments approach is robust and requires less strict assumptions to obtain similar first‐order information. Yet such assumptions are still necessary to achieve more precise sedimentation rate reconstructions. In summary, we show that the spectral moments approach is suitable to obtain first‐order insights in variable components embedded in a depth series.

The Wetteldorf section is the Global Stratotype Section and Point (GSSP) locality of the Lower–Middle Devonian boundary. The section is characterized by an alternation of marls, limestones, and siltstones, with the base of the Eifelian stage defined by the first occurrence of the conodont Polygnathus costatus partitus. The well-established conodont biostratigraphy for this section permits correlations with other time-equivalent sections; however, a cyclostratigraphic framework does not yet exist for this section. Here, we construct such a framework that provides an additional tool for long-distance correlation, and at the same time constrains the amount of geologic time represented by this stratigraphic interval. Microfacies analysis indicates that the entire section has been deposited in an open-marine shelf paleoenvironment, below the storm wave base and under oxygen-rich conditions. We collected high-resolution (5-cm spaced) geochemical data, using a handheld X-ray fluorescence (XRF) spectrometer, and quantified net intensity results for 23 chemical elements. By using factor analysis, we explain 52% of the observed variance in those elements by a model that consists of four factors. The most important factor, factor 1, is driven by geochemical elements related to detrital input (e. g. K, Rb, Si, Ti). Factor 2 is interpreted as a pyrite-indicator, while Factor 3 is driven by Ca and Sr and is thus tied to lithological variations in carbonate content. Factor 1 and 3 are used for cyclo-stratigraphy, as their respective power spectra show similar characteristics. Both factors exhibit a strong 58-cm period, which can be interpreted, according to the available biostratigraphic constraints, either as the imprint of the 18-kyr precession cycle or as the imprint of the 33-kyr obliquity cycle. However, the ratio between different spectral peaks in the different proxies’ power spectra strongly advocates the first option. Our interpretation in terms of astronomical climate forcing implies that the 8.65 meter thick Wetteldorf section (within the Happel Hut) is characterized by an average sedimentation rate of ∼ 3.2 cm/kyr and represents ∼ 250 kyr. From a paleoclimatological point of view, our results indicate that detrital input into the Rhenohercynian Basin was spurred under high-eccentricity configurations, which allowed for strongly enhanced seasonal rainfall. Under astronomical configurations that avoided extremes in seasonality for a prolonged period of time (simultaneously low eccentricity and obliquity), Factor 2 indicates the occurrence of pyrite, which we associate with temporary deteriorations of generally well-oxygenated conditions.

International audience; Until now, the middle Eocene has remained a poorly constrained interval of efforts to produce an astrochronological timescale for the entire Cenozoic. This has given rise to a so-called "Eocene astronomical timescale gap" (Vandenberghe et al., 2012). A high-resolution astrochronological calibration for this interval has proven to be difficult to realize, mainly because carbonate-rich deep-marine sequences of this age are scarce. In this paper, we present records from middle Eocene carbonate-rich sequences from the North Atlantic Southeast Newfoundland Ridge (IODP Exp. 342, Sites U1408 and U1410), of which the cyclical sedimentary patterns allow for an orbital calibration of the geologic timescale between ∼38 and ∼48 Ma. These carbonate-rich cyclic sediments at Sites U1408 and U1410 were deposited as drift deposits and exhibit prominent lithological alternations (couplets) between greenish nannofossil-rich clay and white nannofossil ooze. The principal lithological couplet is driven by the obliquity of Earth's axial tilt, and the intensity of their expression is modulated by a cyclicity of about 173 kyr. This cyclicity corresponds to the interference of secular frequencies s3 and s6 (related to the precession of nodes of the Earth and Saturn, respectively). This 173-kyr obliquity amplitude modulation cycle is exceptionally well recorded in the XRF (X-ray fluorescence)-derived Ca/Fe ratio. In this work, we first demonstrate the stability of the (s3-s6) cycles using the latest astronomical solutions. Results show that this orbital component is stable back to at least 50 Ma, and can thus serve as a powerful geochronometer in the mid-Eocene portion of the Cenozoic timescale. We then exploit this potential by calibrating the geochronology of the recovered middle Eocene timescale between magnetic polarity Chrons C18n.1n and C21n. Comparison with previous timescales shows similarities, but also notable differences in durations of certain magnetic polarity chrons. We present a revision of previous astronomical timescales from the Equatorial and South Atlantic, to overcome the differences between different mid-Eocene astrochronologies. Using our new records from the North Atlantic, combined with existing records from the South Atlantic (ODP Site 1263 and Hole 702B) and Equatorial Atlantic (ODP Site 1260), we revise the durations of magnetic polarity Chrons C18n.1n to C21n, thereby arriving at a robust and self-consistent closure of the middle Eocene astronomical timescale gap.

International audience; The Japan Sea is directly influenced by the Asian monsoon, a system that transports moisture and heat across southeast Asia during the boreal summer, and is a major driver of the Earth's ocean-atmospheric circulation. Foraminiferal and facies analyses of a 460-kyr record from Integrated Ocean Drilling Program Expedition 346 Site U1427 in the Japan Sea reveal a record of nutrient flux and oxygenation that varied due to sea level and East Asian monsoon intensity. The East Asian summer monsoon (EASM) was most intense during marine isotope stage (MIS) 5e, MIS 7e, MIS 9e, and MIS 11c when the Tsushima Warm Current flowed into an unrestricted well-mixed normal salinity Japan Sea, whereas East Asian winter monsoon (EAWM) conditions dominated MIS 2, MIS 4, MIS 6, and MIS 8 when sea level minima restricted the Japan Sea resulting in low-salinity and oxygen conditions in the absence of Tsushima flow. Reduced oxygen stratified, low-salinity, and higher productivity oceanic conditions characterize Terminations TV, TIII, TII, and TI when East China Sea coastal waters breached the Tsushima Strait. Chinese loess, cave, and Lake Biwa (Japan) and U1427 proxy records suggest EASM intensification during low to high insolation transitions, whereas the strongest EAWM prevailed during lowest insolation periods or high to low insolation transitions. Ice sheet/CO 2 forcing leads to the strongest EAWM events in glacials and enhanced EASM in interglacials. Mismatches between proxy patterns suggest that latitudinal and land/sea thermal contrasts played a role in East Asian monsoon variability, suggesting that a complex interplay between ice sheet dynamics, insolation, and thermal gradients controls monsoonal intensity.

The Late Devonian envelops one of Earth’s big five mass extinction events at the Frasnian–Famennian boundary (374 Ma). Environmental change across the extinction severely affected Devonian reef-builders, besides many other forms of marine life. Yet, cause-and-effect chains leading to the extinction remain poorly constrained as Late Devonian stratigraphy is poorly resolved, compared to younger cataclysmic intervals. In this study we present a global orbitally calibrated chronology across this momentous interval, applying cyclostratigraphic techniques. Our timescale stipulates that 600 kyr separate the lower and upper Kellwasser positive δ13C excursions. The latter excursion is paced by obliquity and is therein similar to Mesozoic intervals of environmental upheaval, like the Cretaceous Ocean-Anoxic-Event-2 (OAE-2). This obliquity signature implies coincidence with a minimum of the 2.4 Myr eccentricity cycle, during which obliquity prevails over precession, and highlights the decisive role of astronomically forced “Milankovitch” climate change in timing and pacing the Late Devonian mass extinction., Understanding of Late Devonian mass extinction mechanisms is poor due to imprecise stratigraphies. Here, using cyclostratigraphic techniques, the authors present a global orbitally-calibrated chronology and reveal the key role of astronomically-forced Milankovitch climate change.

Few climate proxies provide information on paleo-wind directions. However, fossilized bedform elements can provide insight into the direction of flow that formed them. Wave-formed ripple marks, for example, which developed in shallow waters, extend transversely to the wind direction. In this study, Middle Devonian paleo-wind directions are reconstructed by measuring the orientation of 511 fossilized wave ripple marks in the Rousay Flagstone Formation on the island of Westray, Orkney, Scotland. The orientation of ripple marks was measured in four different localities on the island. A chi-squared test demonstrates that these four ripple-mark subsets show the same distribution of ripple mark orientation and thus indicates that the studied ripple marks display the same distribution of paleo-winds. Two dominant ripple mark orientations were observed at all studied localities. The most abundant ripple mark orientation suggests paleo-winds from the present-day North or South. Second most abundant are ripple marks that suggest paleo-winds from the present-day ENE or WSW (70° or 250°). When a 40° clockwise rotation of Orkney since the Middle Devonian is taken into account, the ripple marks suggest that the dominant wind directions were south-southeast (SSE) and north-northeast (NNE) in the tropical setting of the Orcadian basin. The SSE wind-direction is represented by the abundant ripple marks, with a present-day near N–S orientation of the line perpendicular to the crests. These ripple marks are also characterized by the largest wavelengths. The abundance of the latter ripple marks with long wavelengths is the result of a lower water level and thus a larger wave-exposed surface during the dry winter season, from April to July, which was mainly characterized by SSE paleo-trade winds.

Eifelian dolomites in the Zacheomie Quarry exhibit metre-scale depositional cyclicity, both in the lower, lagoonal part of the section and in the upper, shallow subtidal portion. Magnetic properties were studied in 30 samples (at c. 1 m intervals), including magnetic susceptibility (MS) and anhysteretic and isothermal remanent magnetization. The rock magnetic parameters are com- pared with the results of thin-section study and elemental chemistry. The forcing factors driving the MS pattern are identified. The MS signal is mostly related to a finely dispersed hematite, controlled by terrigenous input. Magnetite plays a subordinate role and it is confined to less terrigenous hor- izons relatively enriched in uranium and phosphorus. Results of high-resolution (c. 8 cm intervals) MS field measurements show a good correlation with depositional shallowing-upwards cycles, especially in the lagoonal part of the section, where variations of rock magnetic properties and geo- chemical (redox and productivity) indices are very small. High MS values occur in the bottom part of the cycles and they decrease upwards. Time-series analyses of the MS signal reveal the domi- nance of c. 1.7 m cycles, grouped into c. 10 m bundles. The former cycles probably reflect preces- sion-driven changes in monsoonal intensity, whereas the latter may have been controlled by 100 kyr eccentricity.

Recent opening of the La Thure quarry in Western Belgium allowed the collection of new data from a poorly outcropping area of the Belgian Frasnian platform. The studied section covers an interval extending from the falsiovalis to hassi s.l. Zones. Sedimentological analyses allowed the reconstruction of depositional settings in the northwestern part of the Dinant Synclinorium after the demise of the extended Givetian carbonate platform. Two depositional models are distinguished: (a) siliciclastic drowned platform during the Early Frasnian; and (b) a fore-reef depositional setting belonging to a rimmed shelf during the Middle Frasnian. Moreover, interpreted depositional settings in the northwestern part of the Dinant Synclinorium allowed to constraint the direction of the main facies belts for the Belgian Frasnian platform. Combination of MS and geochemistry demonstrates the inherent-parallel link existing between variation in MS values and proxy for terrestrial input (such as Si and Al). This observation meansthat, despite the remagnetization occurring within the Belgian Frasnian lithologies, the main trends in the MS signal from the La Thure section still reflect some syn-sedimentary conditions. The increase in MS and clastic input proxies recorded in distal fore-reef deposit within the punctata Zone are likely to be considered as enhanced by rapid and strong shallowing events recognized in the 'puncata Event' interval.

The discovery of elevated concentrations of the cosmogenic radionuclide 3He in deep- sea sediments from Ocean Drilling Program (ODP) Site 926 (Atlantic Ocean) and ODP Site 757 (Indian Ocean) points toward ac- cretion of extraterrestrial matter, probably as a result of the catastrophic disruption of a large asteroid that produced the Veritas fam- ily of asteroids at ca. 8.3 ± 0.5 Ma, and which may have had important effects on the global climatic and ecologic systems. Here, we in- vestigated the signatures possibly related to the Veritas event by performing a high- resolution multiproxy stratigraphic analysis through the late Tortonian–early Messinian Monte dei Corvi section near Ancona, Italy. Closely spaced bulk-rock samples through a 36-m-thick section, approximately spanning from ca. 9.9 Ma to ca. 6.4 Ma, show an ~5- fold 3He anomaly starting at ca. 8.5 Ma and returning to background values at ca. 6.9 Ma, con rming the global nature of the event. We then analyzed, at 5 cm intervals, bulk-rock samples for sedimentary and environmen- tal proxies such as magnetic susceptibility, calcium carbonate content, total organic carbon, and bulk carbonate d18O and d13C, through a 21-m-thick section encompassing the 3He anomaly. Available high-resolution sea-surface temperature data (via alkenone analyses) for this site show a temperature decrease starting exactly at the inception of the 3He anomaly. Cyclostratigraphic fast- Fourier-transform spectral analyses of the proxies indicate an age of 8.47 ± 0.05 Ma for the inception of the 3He anomaly. A search for impact ejecta (analogous to what is pres- ent in the late Eocene, where both a 3He anomaly and large-scale impact events are recorded) was not successful. Detailed cy- clostratigraphic analyses of our data suggest that the changes in the stable isotope series and environmental proxy series through this late Tortonian time interval had a common forcing agent, and that perturbations of or- bitally forced climate cycles are present ex- actly through the interval with the enhanced in ux of extraterrestrial 3He. Thus, the che- mostratigraphic evidence for a collisional event that created the Veritas family of aster- oids, coinciding with climate perturbations on Earth, suggests yet another form of inter- action between Earth and the solar system.

Dealing with uncertainties is inherent to the scientific process. In the process of building geologic time scales, the reported uncertainties are at least as important as the estimates of the numerical ages. Currently all time scales for the Devonian are based on conventional age-depth models, constructed by linear or cubic interpolation between different dated positions. Unfortunately, such models tend to produce overoptimistic confidence intervals. In this study we apply Bayesian statistics to the Devonian time scale to better incorporate stratigraphic and radioisotopic uncertainty. This approach yields a Devonian time scale characterized by increasing uncertainty with growing stratigraphic distance from a radioisotopically dated sample. This feature is absent from The Geologic Time Scale 2012 ; therefore, that time scale is overoptimistic. We further constrain the obtained time scale by incorporating astrochronological duration estimates for the Givetian and Frasnian stages. The combination of radioisotopic dating and astrochronology results in a reduction of the uncertainty on the numerical age of the stage boundaries concerned by several million years. For example, we estimate the age of the Frasnian- Famennian boundary at 373.9 ± 1.4 Ma.

Identification of Milankovitch periodicities within Magnetic Susceptibility data permitted documentation of 16.5 long 405-kyr eccentricity cycles (Fr-LECs) within the Frasnian Stage of the Upper Devonian of western Alberta and Poland. To further test the cyclostratigraphic model for the Frasnian, we conducted an integrated biostratigraphic, chemostratigraphic, and paleomagnetic investigation to develop a comparative record for the Late Frasnian of the subtropical Iowa Basin. The Late Frasnian Lime Creek Formation in Iowa was sampled in the Cerro Gordo Project Core #1 (CG-1) from northern Iowa and the H-32 core from southeastern Iowa. Conodont biostratigraphy (CG-1 and H-32) and δ13Ccarb provide Late Frasnian time control. We carried out bulk magnetic susceptibility (MS) measurementsat high sampling resolution on both cores (10 cm resolution in CG-1; 4 cm resolution in H-32). The MS series of both cores display the imprint of 100-kyr and 405 -kyr eccentricity, and suggests that the studied interval covers the last ~2.6 million years of the Frasnian. These new data indicate the base of the Lime Creek Formation corresponds to the base of Frasnian Long Eccentricity Cycle 11 (Fr-LEC 11). The shift in δ13Ccarb values from -1‰ to +2‰ in the upper Lime Creek is an expanded record of the LKE δ13Ccarb excursion that spans two short eccentricity cycles within Fr-LEC 15 (200 ky duration). The onset of sea level rise that initiated Late Frasnian Sequence 7 in Alberta begins within Fr-LEC 10. In Iowa the transgression of Devonian T-R cycle IId-1 initiated deposition across the deeply incised karst surface capping the emergent Middle Frasnian Shell Rock Platform during the earliest part of Fr-LEC 11 indicating a duration of the basal hiatus estimated at 300-400 ky. The estimated duration of the high-stand interval of T-R cycle IId-1 in Iowa spans all of Fr-LEC 11 to 14 and lower short eccentricity cycle 1 of Fr-LEC 15 . All data sets from Iowa, Canada and Poland, indicate he Lower Kellwasser δ13Ccarb excursion occurs within Fr-LEC 15, approximately 800 thousand years before the Frasnian-Famennian boundary. These results confirm that global cyclostratigraphic correlations are possible with a clear astronomical imprint, and represent the first steps towards a high-resolution chronology for the Frasnian - Famennian boundary interval.

A Devonian magnetic susceptibility (MS) record obtained on limestones ranging from the Uppermost-Eifelian to the Lower-Givetian and located on the southern border of the Dinant Synclinorium in Belgium was selected for time-series analysis. In these carbonate ramp and platform deposits, spectral analyses highlight persistent, high-frequency cycles in both the MS-signal and the microfacies curve, reflecting environmental and climate changes. These metre-scale variations in the MS-signal are interpreted as changes in the flux of magnetic minerals towards the marine system, most likely controlled by monsoon rainfall-intensity. By combining chrono- and biostratigraphic information with theoretical knowledge of sedimentation rates in different depositional environments, these cycles are interpreted as astronomically driven and dominated by precession. It is hypothesized that during precession minima (longitude of the perihelion ≈270°) the trans-equatorial pressure gradient reaches a maximum and intensifies the northeasterly monsoonal circulation. The consequent increase in moisture transport towards the continent leads to enhanced precipitation and runoff, which, in turn, induces a higher flux of detrital material – including magnetic minerals responsible for the MS-signal – towards the marine system. Moreover, this unique high-resolution climate signal reveals half-precessional cycles. These cycles suggest that during precession maxima (longitude of the perihelion ≈90°) southeasterly monsoonal circulation strengthened due to an increased inter-hemispheric pressure gradient.

Recent advances in radiometric dating result in significant improvements in the geo- logical timescale and provide better insight into the timing of various processes and evolutions within the Earth's system. However, no radiometric ages are contained within the Givetian. Con- sequently, the absolute ages of the Givetian Stage boundaries, as well as the stage's duration, remain poorly constrained. As an alternative, the analysis of sedimentary cycles allows for the esti- mation of the duration of this stage. We examined the high-resolution magnetic susceptibility signals of four Givetian outcrops in the Givet area for a possible astronomical imprint, to fully understand the rates of evolutionary and environmental change. All four sections are firmly corre- lated and wavelet analyses of the magnetic susceptibility signals reveal the imprint of astronomical eccentricity forcing. The highly stable 405 kyr cycles constrain the duration of the Givetian Stage at 4.35+ 0.45 Myr, which is in good agreement with the International Chronostratigraphic Chart (5.0 Myr). The studied sections also exhibit an imprint of obliquity, suggesting a climatic telecon- nection between low and high latitudes. The corresponding microfacies curves demonstrate similar astronomical imprint, and thereby indicate that the observed 10 5 year-scale cyclicity is the result of climatic and environmental change.

The development and behavior of million year- scaled depositional sequences recorded within Palaeozoic carbonate platform has remained poorly examined. There- fore, the understanding of palaeoenvironmental changes that occur in geological past is still limited. We herein undertake a multi-disciplinary approach (sedimentology, conodont biostratigraphy, magnetic susceptibility (MS), and geochemistry) of a long-term succession in the Carnic Alps, which offers new insights into the peculiar evolution of one of the best example of Palaeozoic carbonate platform in Europe. The Freikofel section, located in the central part of the Carnic Alps, represents an outstanding succession in a fore-reef setting, extending from the Latest Givetian (in- det.falsiovalis conodont zones) to the Early Famennian (Lower crepida conodont zone). Sedimentological analysis allowed to propose a sedimentary model dominated by distal slope and fore-reef-slope deposits. The most distal setting is characterized by an autochthonous pelagic sedi- mentation showing local occurrence of thin-bedded turbi- ditic deposits. In the fore-reef slope, in a more proximal setting, there is an accumulation of various autochthonous and allochthonous fine- to coarse-grained sediments origi- nated from the interplay of gravity-flow currents derived from the shallow-water and deepwater area. The temporal evolution of microfacies in the Freikofel section evolves in two main steps corresponding to the Freikofel (Unit 1) and the Pal (Unit 2) limestones. Distal slope to fore-reef lithologies and associate changes are from base to top of the section: (U1) thick bedded litho- and bioclastic breccia beds with local fining upward sequence and fine-grained mud- stone intercalations corresponding, in the fore-reef setting, to the dismantlement of the Eifelian-Frasnian carbonate platform during the Early to Late Frasnian time (falsiovalis to rhenana superzones) with one of the causes being the Late Givetian major rift pulse; (U2) occurrence of thin- bedded red nodular and cephalopod-bearing limestones with local lithoclastic grainstone intercalations corre- sponding to a significant deepening of the area and the progressive withdrawal of sedimentary influxes toward the basin, in relation with Late Frasnian sea-level rise. MS and geochemical analyses were also performed along the Fre- ikofel section and demonstrate the inherent parallel link existing between variation in MS values and proxy for terrestrial input. Interpretation of MS in terms of palaeo- environmental processes reflects that even though distality remains the major parameter influencing MS values, car- bonate production and water agitation also play an impor- tant role.

The Eifelian dolomites in the Zachelmie Quarry (Holy Cross Mountains, Poland) contain trackways and tracks of tetrapods 390–391 Ma old, and thus the oldest known so far. The environments of the trackway-bearing beds have been investigated using sedimentological, palaeontological, geochemical and palaeomagnetic methods. The reconstructed tetrapod habitats comprised shallow-water lagoons separated from an open marine basin by sparsely vegetated islands and spits. The lagoonal waters were well-aerated and a few metres deep at most, undergoing periodic desiccation. The dolomitic sediments, primarily of microbial origin, formed in tropical waters of slightly modified marine composition. Oxygen isotope data obtained from the dolomicrites suggest water temperatures around 30 °C. The seasonal semi-arid to sub-humid climate, deduced from paleosol characteristics, was probably of a tropical monsoonal type. The degree of restriction of the lagoonal system evolved from relatively open, evaporation-dominated towards increasingly closed, freshwater influenced. The detailed observations of the footprint-bearing beds, as well as the characteristics of the tracks, indicate that they were formed mostly under subaqueous conditions, by wading, walking on the bottom or swimming animals. Lack of tidal indicators in the restricted Zachelmie lagoons argues against previous concept that tidal flats served as a food source for the early tetrapods. Nor is a hypothesis of flooded woodlands confirmed as a habitat promoting the “fish-to-tetrapod” transition. We propose that functional limbs emerged among aqueous animals that acquired their locomotional capabilities in a shallow lagoonal water before attempting longer excursions on land.

Rhythmical alternations between limestone and shales or marls characterize the famous Kowala section, Holy Cross Mountains, Poland. Two intervals of this section were studied for evidence of orbital cyclostratigraphy. The oldest interval spans the Frasnian–Famennian boundary, deposited under one of the hottest greenhouse climates of the Phanerozoic. The youngest interval encompasses the Devonian– Carboniferous (D–C) boundary, a pivotal moment in Earth’s climatic history that saw a transition from greenhouse to icehouse. For the Frasnian–Famennian sequence, lithological variations are consistent with 405-kyr and 100-kyr eccentricity forcing and a cyclostratigraphic floating time-scale is presented. The interpretation of observed lithological rhythms as eccentricity cycles is confirmed by amplitude modulation patterns in agreement with astronomical theory and by the recognition of precession cycles in high-resolution stable isotope records. The resulting relative time-scale suggests that � 800 kyr separate the Lower and Upper Kellwasser Events (LKE and UKE, respectively), two periods of anoxia that culminated in massive biodiversity loss at the end of the Frasnian. Th/U and pyrite framboid analyses indicate that during the UKE, oxygen levels remained low for 400 kyr and d 13 C org measure

Currently, only few U-Pb isotopic dates constrain the Devonian geological time scale. For this reason, absolute age estimates of Devonian stage boundaries are characterized by very wide error bars, up to ± 3.8 Myr (Kaufmann, 2006). The uncertainty on the absolute age of stage boundaries and on the duration of different stages hampers a detailed understanding of rates of sedimentation processes, environmental changes and key-events in the evolution of life on Earth (e.g. the Late Devonian extinction, the land plant invasion, the fish-tetrapod transition, etc.). One possible way to reduce uncertainties in the Devonian geological time-scale is the recognition of astronomical cycles in its stratigraphy. Therefore, this study reports frequency analyses of high-resolution (10-20 kyr) magnetic susceptibility (MS) data of the Frasnian (Late Devonian), derived from carbonate-platform and surrounding slope and basin deposits in western Alberta, Canada. Previous studies demonstrated the generally consistent pattern of MS change across the Alberta basin and demonstrated the utility of MS stratigraphy as a refined regional correlation tool, compared to biostratigraphy. In the present study, it is shown that the MS stratigraphy of the Frasnian in western Alberta is significantly influenced by astronomical forcing. Cyclicity in the studied sections is ascribed to different Milankovi? astronomical parameters. The astronomical interpretation of observed periodicities is supported by the presence of several amplitude modulations consistent with astronomical theory, and by average sedimentation rate patterns that agree with the existing lithostratigraphy. Sixteen 405-kyr long eccentricity cycles are recognized in the Frasnian MS stratigraphy. By using these cycles as a geochronometer, a Frasnian astronomical time-scale is constructed. This time-scale indicates a duration of 6.5 ± 0.4 Myr for the Frasnian. Calibrating this duration to the Kaufmann's (2006) Devonian chronology, the absolute age of the Givetian/Frasnian boundary is recalculated to 383.6 ± 3.0 Ma and the age of the Frasnian/Famennian boundary to 376.7 ± 3.0 Ma. These new absolute ages take into account the astronomically derived duration of the Frasnian, and yield a narrowing of the error margins of the absolute ages by several hundred thousand years. Therefore, this study demonstrates that the recognition of astronomical cycles can also significantly refine the Paleozoic geological time-scale.

Low-field magnetic susceptibility (?in) measurements are quick and sensitive enabling the creation of high-resolution records; making ?in an attractive correlation tool and a proxy for paleoclimate and paleoenvironments. In geologically young material – foremost in Cenozoic sediments – ?in belongs to the geoscientist's toolkit. However, ?in is a convolved signal and may reflect other processes than the often implicitly inferred depositional conditions. Diagenesis, remagnetization and low-grade metamorphism, can potentially obscure the original, depositional, ?in signal. This aspect is particularly important when interpreting ?in records from Paleozoic rocks. Here, we review data obtained from a large sample collection of Middle to Upper Devonian sections in Belgium. Comparison of ?in trends with paleoenvironmental indicators (facies) and with detrital input proxies (Zr, Th, Ti, Al) allowed to assess the persistence of depositional trends. Furthermore, the ?in signal was deconvolved into its dominant mineralogical contributions with the help of magnetic-property analysis. The main results are pointing to a magnetic signal dominated by fine-grained magnetite, of which paleomagnetic analysis indicated a formation during Carboniferous remagnetization. This prompts a potentially strong influence of post-depositional processes and it complicates the interpretation of ?in records in terms of depositional environments. However, in most of the sections, there is a relatively good relationship between ?in trends and facies evolution and between ?in and geochemical proxies for detrital inputs. This indicates that the newly formed magnetite grains would at least partly remain where they are formed, and this allows a relative preservation of the original signal, despite the strong influence of diagenesis. Two sections show a stronger impact of diagenesis, where for about half of these sections, the primary, depositional information is lost. The Eifelian–Givetian Monts de Baileux section was selected for time-series analysis of the ?in series. The Average Spectral Misfit (ASM) method is applied to explicitly evaluate the null hypothesis of no orbital signal and in this section, there is 99.05% chance that the MS signal is reflecting an orbital imprint.

We studied a high-resolution multiproxy data set, including magnetic susceptibility (MS), CaCO3 content, and stable isotopes (δ18O and δ13C), from the stratigraphic interval covering the uppermost Maastrichtian and the lower Danian, represented by the pelagic limestones of the Scaglia Rossa Formation continuously exposed in the classic sections of the Bottaccione Gorge and the Contessa Highway near Gubbio, Italy. Variations in all the proxy series are periodic and reflect astronomically forced climate changes (i.e., Milankovitch cycles). In particular, the MS proxy reflects variations in the terrigenous dust input in this pelagic, deep-marine environment. We speculate that the dust is mainly eolian in origin and that the availability and transport of dust are influenced by variations in the vegetation cover on the Maastrichtian-Paleocene African or Asian zone, which were respectively located at tropical to subtropical latitudes to the south or far to the east of the western Tethyan Umbria-Marche Basin, and were characterized by monsoonal circulation. The dynamics of monsoonal circulation are known to be strongly dependent on precession-driven and obliquity-driven changes in insolation. We propose that a threshold mechanism in the vegetation coverage may explain eccentricity-related periodicities in the terrigenous eolian dust input. Other mechanisms, both oceanic and terrestrial, that depend on the precession amplitude modulated by eccentricity, can be evoked together with the variation of dust influx in the western Tethys to explain the detected eccentricity periodicity in the δ13C record. Our interpretations of the δ18O and MS records suggest a warming event ∼400 k.y. prior to the Cretaceous-Paleogene (K-Pg) boundary, and a period of climatic and environmental instability in the earliest Danian. Based on these multiproxy phase relationships, we propose an astronomical tuning for these sections; this leads us to an estimate of the timing and duration of several late Maastrichtian and Danian biostratigraphic and magnetostratigraphic events.