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Using ozonesonde measurements from 2015 to 2018 at the Jang Bogo station located in the southeastern Antarctic region, we evaluate ozone profiles retrieved from the three satellite measurements that are widely used: Ozone Monitoring Instrument (OMI), Microwave Limb Sounder (MLS), and Ozone Mapping Profiler Suite (OMPS) data. For the fair validation, ozonesonde profiles are smoothed using the weighting function of each satellite retrieval algorithm (i.e., convolution process). Compared with limb-viewing MLS and OMPS ozone profiles, the OMI ozone profiles are relatively less qualified: coarser vertical resolution and larger inter-annual variation. Nevertheless, our validation reveals that the quality of all three satellite ozone profiles looks comparable; In general, difference from ozonesonde profile is ∼1 ppm absolutely, and -20 to 30% relatively at maximum. This quantitative range well corresponds to previous work, meaning that our new validation confirms the reliability of satellite ozone profiles in the southeastern Antarctic region where the measurement data for the validation were not enough. Another interesting feature is the role of a priori ozone profile; Nadir-viewing OMI satellite can have qualified ozone profiles by a proper assumption of a priori ozone profile. Since the performance of limb-viewing ozone profiles is better, however, the careful usage of nadir-viewing ozone profile is still required. We think that the simultaneous usage of multiple satellite ozone profiles can contribute to better understanding of Antarctic ozone characteristics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Inc. All rights reserved.)

Observations of March 2024 Arctic (63°N–90°N) total column ozone set a record high of 477 Dobson Units (DU) against the 1979–2023 satellite era time series. It was about 60 DU higher than average and 6 DU higher than the previous March 1979 471 DU record. Daily Arctic ozone was above average for every day in March 2024, and set record highs from 11–26 March 2024. Microwave Limb Sounder data show this record ozone anomaly was concentrated in the lower stratosphere (10–30 km). These record values developed over the 2023–2024 winter and can be associated with vertically propagating planetary‐scale wave events that caused significant stratospheric warmings. These wave events forced poleward and downward ozone advection into the lower stratosphere, leading to record column ozone levels. The above average levels persisted through August 2024 and across the northern hemisphere. Plain Language Summary: Man‐made chlorofluorocarbons (CFCs) depleted the Earth ozone layer. The 1987 Montreal Protocol curbed CFC growth, but because CFCs have multi‐decadal lifetimes, Arctic ozone is not expected to recover back to 1980 levels until ∼2045. Current high CFC levels combined with persistent and cold polar vortices led to severe Arctic ozone spring depletion in 1997, 2011, and 2020. Contrary to expectations, March 2024 Arctic ozone showed a record high level, dramatically contrasting against the severe depletion events. Meteorological and ozone profile information show that the exceptional 2024 ozone was mainly found in the lowermost Arctic stratosphere, in association with record high lowermost stratospheric temperatures. The ozone levels incrementally increased during the 2023–2024 winter because of large‐scale weather systems that propagated from the troposphere into the stratosphere. Collectively, these weather systems also were at a record level, moving higher ozone concentrations from the mid‐latitudes and upper stratospheric into the Arctic region. This record high ozone would likely have not occurred if CFC levels had not begun slowly declining in response to the Montreal Protocol. Given the absence of high Arctic ozone since the 1970s, the March 2024 record high should be considered a positive harbinger of the future Arctic ozone layer. Key Points: Arctic total column ozone in March 2024 set a record high for the 1979‐present periodPolar lower stratosphere temperatures also set a record high in March 2024 in the MERRA‐2 reanalysis dataA record amount of Rossby waves propagating upward from the troposphere caused the record total ozone and lower stratospheric temperature [ABSTRACT FROM AUTHOR]

We present a new tropospheric ozone dataset based on TROPOspheric Monitoring Instrument (TROPOMI)/Sentinel-5 Precursor (S5P) total ozone measurements combined with stratospheric ozone data from the Belgian Assimilation System for Chemical ObsErvations (BASCOE) constrained by assimilating ozone observations from the Microwave Limb Sounder (MLS). The BASCOE stratospheric data are interpolated to the S5P observations and subtracted from the TROPOMI total ozone data. The difference is equal to the tropospheric ozone residual column from the surface up to the tropopause. The tropospheric ozone columns are retrieved at the full spatial resolution of the TROPOMI sensor (5.5×3.5 km 2) with daily global coverage. Compared to the Ozone Mapping and Profiler Suite Modern-Era Retrospective analysis for Research and Applications 2 (OMPS-MERRA-2) data, a global mean positive bias of 3.3 DU is found for the analysed period April 2018 to June 2020. A small negative bias of about -0.91 DU is observed in the tropics relative to the operational TROPOMI tropical tropospheric data based on the convective cloud differential (CCD) algorithm throughout the same period. The new tropospheric ozone data (S5P-BASCOE) are compared to a set of globally distributed ozonesonde data integrated up to the tropopause level. We found 2254 comparisons with cloud-free TROPOMI observations within 25 km of the stations. In the global mean, S5P-BASCOE deviates by 2.6 DU from the integrated ozonesondes. Depending on the latitude the S5P-BASCOE deviate from the sondes and between -4.8 and 7.9 DU , indicating a good agreement. However, some exceptional larger positive deviations up to 12 DU are found, especially in the northern polar regions (north of 70 ∘). The monthly mean tropospheric column and time series for selected areas showed the expected spatial and temporal pattern, such as the wave one structure in the tropics or the seasonal cycle, including a summer maximum, in the mid-latitudes. [ABSTRACT FROM AUTHOR]

A new atmospheric ozone profile climatology has been constructed by combining daytime ozone profiles from the Aura Microwave Limb Sounder (MLS) and Modern-Era Retrospective Analysis for Research Applications version 2 (MERRA-2) Global Modeling Initiative (GMI) model simulation (M2GMI). The MLS and M2GMI ozone profiles are merged between 13 and 17 km (∼159 and 88 hPa), with MLS used for stratospheric and GMI for primarily tropospheric levels. The time record for profiles from MLS and GMI is August 2004–December 2016. The derived seasonal climatology consists of monthly zonal-mean ozone profiles in 5 ∘ latitude bands from 90 ∘ S to 90 ∘ N covering altitudes (in Z* log-pressure altitude) from zero to 80 km in 1 km increments. This climatology can be used as a priori information in satellite ozone retrievals, in atmospheric radiative transfer studies, and as a baseline to compare with other measured or model-simulated ozone. The MLS/GMI seasonal climatology shows a number of improvements compared with previous ozone profile climatologies based on MLS and ozonesonde measurements. These improvements are attributed mostly to continuous daily global coverage of GMI tropospheric ozone compared with sparse regional measurements from sondes. In addition to the seasonal climatology, we also derive an additive climatology to account for interannual variability in stratospheric zonal-mean ozone profiles which is based on a rotated empirical orthogonal function (REOF) analysis of Aura MLS ozone profiles. This REOF climatology starts in 1970 and captures most of the interannual variability in global stratospheric ozone including quasi-biennial oscillation (QBO) signatures. [ABSTRACT FROM AUTHOR]

Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, and continues to be, uniquely important for studies of long-term changes in Antarctic ozone. However, a crack in the ice shelf on which it resides forced the station to abruptly close in February of 2017, leading to a gap of two ozone hole seasons in its historic record. We develop and test a method for filling in the record of Halley total ozone by combining and adjusting overpass data from a range of different satellite instruments. Comparisons to the Dobson suggest that our method reproduces monthly ground-based total ozone values with an average difference of 1.1 ± 6.2 DU for the satellites used to fill in the 2017–2018 gap. We show that our approach more closely reproduces the Dobson measurements than simply using the raw satellite average or data from a single satellite instrument. The method also provides a check on the consistency of the provisional data from the automated Dobson used at Halley after 2018 with earlier manual Dobson data and suggests that there were likely inconsistencies between the two. The filled Halley dataset provides further support that the Antarctic ozone hole is healing, not only during September but also in January. [ABSTRACT FROM AUTHOR]

Seasonal ozone depletion in the polar regions (during late winter and early spring) depends on the presence and distribution of polar stratospheric clouds (PSCs). In this paper, we present new satellite observations of PSCs by the Ozone Mapping and Profiler Suite (OMPS) Limb Profiler (LP) instrument. LP cloud detections are identified as PSCs based on location, altitude, and background atmosphere temperature. The hyperspectral capabilities of OMPS LP enable PSC detection to occur concurrent with stratospheric ozone measurements from the same instrument. We present PSC results from the Northern Hemisphere 2019–2010 winter/spring season to illustrate the exceptional nature of this season. Future OMPS LP instruments flying on Joint Polar Satellite System (JPSS) satellites will continue PSC observations into the 2030s. Plain Language Summary: The presence of polar stratospheric clouds is an important factor in determining whether polar ozone depletion occurs during the spring. We present new observations of PSCs from the OMPS Limb Profiler (LP), collected in parallel with ozone profile measurements by the same instrument. LP observations show that the Arctic 2019–2020 winter/spring season was exceptional in terms of PSC geographic coverage and duration. LP measurements of PSCs will continue with future satellite instruments. Key Points: Polar stratospheric clouds are a precursor to seasonal ozone depletionThe OMPS Limb Profiler can create vertically resolved daily maps of PSC distributionThe Arctic 2019–2020 winter/spring season had high PSC occurrence rates more typically observed in the Antarctic [ABSTRACT FROM AUTHOR]

Past studies have suggested that ozone in the troposphere has increased globally throughout much of the 20th century due to increases in anthropogenic emissions and transport. We show, by combining satellite measurements with a chemical transport model, that during the last four decades tropospheric ozone does indeed indicate increases that are global in nature, yet still highly regional. Satellite ozone measurements from Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) are merged with ozone measurements from the Aura Ozone Monitoring Instrument/Microwave Limb Sounder (OMI/MLS) to determine trends in tropospheric ozone for 1979–2016. Both TOMS (1979–2005) and OMI/MLS (2005–2016) depict large increases in tropospheric ozone from the Near East to India and East Asia and further eastward over the Pacific Ocean. The 38-year merged satellite record shows total net change over this region of about +6 to +7 Dobson units (DU) (i.e., ∼15 %–20 % of average background ozone), with the largest increase (∼4 DU) occurring during the 2005–2016 Aura period. The Global Modeling Initiative (GMI) chemical transport model with time-varying emissions is used to aid in the interpretation of tropospheric ozone trends for 1980–2016. The GMI simulation for the combined record also depicts the greatest increases of +6 to +7 DU over India and East Asia, very similar to the satellite measurements. In regions of significant increases in tropospheric column ozone (TCO) the trends are a factor of 2–2.5 larger for the Aura record when compared to the earlier TOMS record; for India and East Asia the trends in TCO for both GMI and satellite measurements are ∼+3 DU decade -1 or greater during 2005–2016 compared to about +1.2 to +1.4 DU decade -1 for 1979–2005. The GMI simulation and satellite data also reveal a tropospheric ozone increases in ∼+4 to +5 DU for the 38-year record over central Africa and the tropical Atlantic Ocean. Both the GMI simulation and satellite-measured tropospheric ozone during the latter Aura time period show increases of ∼+3 DU decade -1 over the N Atlantic and NE Pacific. [ABSTRACT FROM AUTHOR]

A version 2 processing of data from two ozone monitoring instruments on Suomi NPP, the OMPS nadir ozone mapper and the OMPS nadir ozone profiler, has now been completed. The previously released data were useful for many purposes but were not suitable for use in ozone trend analysis. In this processing, instrument artifacts have been identified and corrected, an improved scattered light correction and wavelength registration have been applied, and soft calibration techniques were implemented to produce a calibration consistent with data from the series of SBUV/2 instruments. The result is a high-quality ozone time series suitable for trend analysis. Total column ozone data from the OMPS nadir mapper now agree with data from the SBUV/2 instrument on NOAA 19 with a zonal average bias of -0.2 % over the 60 ∘ S to 60 ∘ N latitude zone. Differences are somewhat larger between OMPS nadir profiler and N19 total column ozone, with an average difference of -1.1 % over the 60 ∘ S to 60 ∘ N latitude zone and a residual seasonal variation of about 2 % at latitudes higher than about 50 ∘. For the profile retrieval, zonal average ozone in the upper stratosphere (between 2.5 and 4 hPa) agrees with that from NOAA 19 within ±3 % and an average bias of -1.1 %. In the lower stratosphere (between 25 and 40 hPa) agreement is within ±3 % with an average bias of +1.1 %. Tropospheric ozone produced by subtracting stratospheric ozone measured by the OMPS limb profiler from total column ozone measured by the nadir mapper is consistent with tropospheric ozone produced by subtracting stratospheric ozone from MLS from total ozone from the OMI instrument on Aura. The agreement of tropospheric ozone is within 10 % in most locations. [ABSTRACT FROM AUTHOR]

One of the largest constraints to the retrieval of accurate ozone profiles from UV backscatter limb sounding sensors is altitude registration. Two methods, the Rayleigh scattering attitude sensing (RSAS) and absolute radiance residual method (ARRM), are able to determine altitude registration to the accuracy necessary for long-term ozone monitoring. The methods compare model calculations of radiances to measured radiances and are independent of onboard tracking devices. RSAS determines absolute altitude errors, but, because the method is susceptible to aerosol interference, it is limited to latitudes and time periods with minimal aerosol contamination. ARRM, a new technique introduced in this paper, can be applied across all seasons and altitudes. However, it is only appropriate for relative altitude error estimates. The application of RSAS to Limb Profiler (LP) measurements from the Ozone Mapping and Profiler Suite (OMPS) on board the Suomi NPP (SNPP) satellite indicates tangent height (TH) errors greater than 1 km with an absolute accuracy of ±200 m. Results using ARRM indicate a ~300 to 400m intra-orbital TH change varying seasonally ±100 m, likely due to either errors in the spacecraft pointing or in the geopotential height (GPH) data that we use in our analysis. ARRM shows a change of ~200m over ~5 years with a relative accuracy (a long-term accuracy) of ±100m outside the polar regions. [ABSTRACT FROM AUTHOR]

Sentinel 5 Precursor (S5P) satellite was launched into a polar orbit in October 2017, carrying the TROPOMI instrument. S5P has sun synchronous orbit with an equator crossing time of 13:30 LT. TROPOMI achieves an almost daily coverage, due to the wide swath width of 2600 km. The near-real-time (NRT) ozone total column is based on the two step DOAS approach, consisting of a slant column retrieval and an iterative AMF-calculation. In this study we present tropospheric ozone columns based on total column from S5P and stratospheric column based on 4D-Var assimilation of Aura MLS ozone profiles. MLS profiles are assimilated by the Belgian Assimilation System for Chemical ObsErvations (BASCOE, Lefever et al., 2015, ACP) and are delivered with a time frequency of 3 hours. BASCOE stratospheric columns are interpolated linearly in time and space to TROPOMI total column locations before subtraction. To avoid potential errors we used only cloud free TROPOMI data.After a brief introduction of the method the data will be compared to other tropospheric ozone data e.g OMPS or sondes. The study will focus be on the first year highlighting some tropospheric ozone hotspots like megacities. [ABSTRACT FROM AUTHOR]