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A better understanding of background tropospheric ozone delivers multiple benefits. Robust estimates of regional background ozone are required to understand the limits of anthropogenic emissions controlling ozone reduction. Long-term estimates of background ozone assist in characterising changes in atmospheric composition and can help quantify the influence of human activity on the atmosphere. Background tropospheric ozone measurements representative of continental air masses are scarce in Australia. Here, we use k-means clustering to identify a cluster of measurements from the long-term air quality monitoring station at Oakdale, NSW, which are likely to be representative of background air. The cluster is associated with NOx-limited air masses of continental origin. From this analysis, we estimate background ozone representative of Eastern Australia. We find recent (2017–2022) mean ozone mixing ratios of 28.5 ppb and identify a statistically significant (α = 0.05) trend in the mean of +1.8 (1.0–2.8) ppb/decade. Our methods demonstrate that some long-term monitoring stations within or near urban areas can provide suitable conditions and datasets for regional Global Atmosphere Watch monitoring. [ABSTRACT FROM AUTHOR]

It has been recognized that the background ozone concentration in urban areas is changing over the years. This article aims to determine the background ozone level (BOL) using ambient air quality data measurements collected at some monitoring stations in the Sydney basin, Australia. A definition of background ozone in the context of the Sydney region is proposed. With this definition, it is possible to estimate the background ozone using ambient measurements of ozone and its precursors. The trend of the BOL is also estimated from the temporal ambient monitoring records as of early 1998-2005. These ozone level changes at different monitoring stations are assessed using the linear regression method. The results are shown to vary between different monitoring sites. This demonstrates that the local conditions at each site are important in determining as to whether an air quality management plan for reducing the ozone level to below the exceedance level is effective and achievable or not. Furthermore, the results obtained are compared with those obtained by the Clapp-Jenkin method, which is based on the relationship between oxidant and nitrogen oxides, assuming a stationary state of photochemical smog function. [ABSTRACT FROM AUTHOR]