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Herein, the oxidation properties, i.e., oxidation processes in air, oxidation-product composition, and oxide-film growth, of tungsten–rhenium thermocouple wires were investigated via differential scanning calorimetry (DSC), thermogravimetry (TG), X-ray diffraction (XRD), and scanning electron microscopy (SEM). A tungsten–rhenium thermocouple was protected against oxidation using solidification technology, and the cross sections of the thermocouple wires were observed via SEM. The results showed that the oxidation-initiation temperatures for the W–26% Re and W–5% Re thermocouple wires were ≤681 and ≤873°C, respectively, in air. Moreover, the major oxidization product at high temperature was WO3. The oxide layers were unable to form protective films owing to the generation of stress-induced cracks that grew in radiating lines. The protected tungsten–rhenium thermocouple wires remained intact during oxidation, and oxide layers were not detected. [ABSTRACT FROM AUTHOR]