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In this work, the structural phase state and physical properties of YbMn1-xFexO3 (hereinafter YbMF) ceramics in the range of x = 0.0–1.0 with a concentration step Δx = 0.1 were studied by complex methods. X-ray diffraction revealed that the YbMF compositions in the range of x = 0.1–0.5 were hexagonal (H) phase solid solutions. In the concentration range of x = 0.6–0.8, the hexagonal and orthorhombic (O) systems coexist, and the unit cell parameters of these phases rise with increasing x. The study of the lattice parameters, bond lengths, bond angles and the main parameters of the magnetic hysteresis loop of the H-phase revealed the presence of a singular point x = 0.5 in the concentration range, where extrema of the corresponding parameters were observed. By analyzing the Cole–Cole plots for the electric modulus M*(ω), a conclusion was drawn about the thermally activated nature of the dielectric relaxation for each composition with a single relaxation time τ. The magnetodielectric MD(ω) and magnetoresistive MR(ω) coefficients measured in crossed and parallel fields E and H show high values, which reach 1.6% and 50%, respectively, depending on the frequency of the measuring field. [ABSTRACT FROM AUTHOR]