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Green single crystal-based light-emitting devices based on 1,4-bis(5-phenylthiophen-2-yl)benzene (AC5) crystals have been realized by template stripping method. And double-layered structure with a molybdenum oxide (MoO 3 ) layer is employed as anodic buffer layer to lower the carrier injection barrier. On the basis of this structure, the AC5 crystal-based OLEDs exhibit a significantly lower turn-on voltage of 5 V and higher luminance reaching 28.96 cd/m 2 , which open a realistic route towards their practical application in optoelectronic devices. [ABSTRACT FROM AUTHOR]

Organic single crystals with much higher carrier mobility and stability compared to the amorphous organic materials have shown great potential in electronic and optoelectronic devices. However, their applications in white organic light‐emitting devices (WOLEDs), especially the three‐color‐strategy WOLEDs, have been hindered by the difficulties in fabricating complicated device structures. Here, double‐doped white‐emission organic single crystals are used as the active layers for the first time in the three‐color‐strategy WOLEDs by co‐doping the red and green dopants into blue host crystals. Precise control of the dopant concentration in the double‐doped crystals results in moderately partial energy transfer from the blue donor to the green and red dopants, and thereafter, simultaneous RGB emissions with balanced emission intensity. The highest color‐rendering index (CRI) and efficiency, to the best of the authors' knowledge, are obtained for the crystal‐based WOLEDs. The CRI of the WOLEDs varies between 80 and 89 with the increase of the driving current, and the luminance and current efficiency reach up to 793 cd m−2 and 0.89 cd A−1, respectively. The demonstration of the present three‐color organic single‐crystal‐based WOLED promotes the development of the single crystals in optoelectronics. High‐color‐rendering and high‐efficiency three‐color‐strategy white organic light‐emitting devices (WOLEDs) are realized using double‐doped white‐emission organic single crystals, which are grown by co‐doping red and green dopants into the blue host. The crystal‐based WOLEDs exhibit the maximum luminance, current efficiency, and external quantum efficiency of 793 cd m−2, 0.89 cd A−1, and 0.48%, respectively, which promote the development of the organic single crystals in optoelectronics. [ABSTRACT FROM AUTHOR]