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Abstract: Patterns of uranium–molybdenum covariation in marine sediments have the potential to provide insights regarding depositional conditions and processes in paleoceanographic systems. Specifically, such patterns can be used to assess bottom water redox conditions, the operation of metal-oxyhydroxide particulate shuttles in the water column, and the degree of water mass restriction. The utility of this paleoenvironmental proxy is due to the differential geochemical behavior of U and Mo: (1) uptake of authigenic U by marine sediments begins at the Fe(II)–Fe(III) redox boundary (i.e., suboxic conditions), whereas authigenic Mo enrichment requires the presence of H2S (i.e., euxinic conditions), and (2) transfer of aqueous Mo to the sediment may be enhanced through particulate shuttles, whereas aqueous U is unaffected by this process. In the present study, we examine U–Mo covariation in organic-rich sediments deposited mostly in the western Tethyan region during oceanic anoxic events (OAEs) of Early Jurassic to Late Cretaceous age. Our analysis generally confirms existing interpretations of redox conditions in these formations but provides significant new insights regarding water mass restriction and the operation of particulate shuttles in depositional systems. These insights will help to address contentious issues pertaining to the character and origin of Mesozoic OAEs, such as the degree to which regional paleoceanographic factors controlled the development of the OAEs. [Copyright &y& Elsevier]

The Bächental bituminous marls (Bächentaler Bitumenmergel) belonging to the Sachrang Member of the Lower Jurassic Middle Allgäu Formation were investigated using a multidisciplinary approach to determine environmental controls on the formation of organic-rich deposits in a semi-restricted basin of the NW Tethys during the Early Jurassic. The marls are subdivided into three units on the basis of mineralogical composition, source-rock parameters, redox conditions, salinity variations, and diagenetic processes. Redox proxies (e.g., pristane/phytane ratio; aryl isoprenoids; bioturbation; ternary plot of iron, total organic carbon, and sulphur) indicate varying suboxic to euxinic conditions during deposition of the Bächental section. Redox variations were mainly controlled by sea-level fluctuations with the tectonically complex bathymetry of the Bächental basin determining watermass exchange with the Tethys Ocean. Accordingly, strongest anoxia and highest total organic carbon content (up to 13%) occur in the middle part of the profile (upper tenuicostatum and lower falciferum zones), coincident with an increase in surface-water productivity during a period of relative sea-level lowstand that induced salinity stratification in a stagnant basin setting. This level corresponds to the time interval of the lower Toarcian oceanic anoxic event (T-OAE). However, the absence of the widely observed lower Toarcian negative carbon isotope excursion in the study section questions its unrestricted use as a global chemostratigraphic marker. Stratigraphic correlation of the thermally immature Bächental bituminous marls with the Posidonia Shale of SW Germany on the basis of C 27 /C 29 sterane ratio profiles and ammonite data suggests that deposition of organic matter-rich sediments in isolated basins in the Alpine realm commenced earlier (late Pliensbachian margaritatus Zone) than in regionally proximal epicontinental seas (early Toarcian tenuicostatum Zone). The late Pliensbachian onset of reducing conditions in the Bächental basin coincided with an influx of volcaniclastic detritus that was possibly connected to complex rifting processes of the Alpine Tethys and with a globally observed eruption-induced extinction event. The level of maximum organic matter accumulation in the Bächental basin corresponds to the main eruptive phase of the Karoo-Ferrar large igneous province (LIP), confirming its massive impact on global climate and oceanic conditions during the Early Jurassic. The Bächental marl succession is thus a record of the complex interaction of global (i.e., LIP) and local (e.g., redox and salinity variations, basin morphology) factors that caused reducing conditions and organic matter enrichment in the Bächental basin. These developments resulted in highly inhomogeneous environmental conditions in semi-restricted basins of the NW Tethyan domain during late Pliensbachian and early Toarcian time. [ABSTRACT FROM AUTHOR]