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Lithium fluoride (LiF) crystals and thin films are utilized as radiation detectors for energy diagnostics of proton beams. This is achieved by analyzing the Bragg curves in LiF obtained by imaging the radiophotoluminescence of color centers created by protons. In LiF crystals, the Bragg peak depth increases superlinearly with the particle energy. A previous study has shown that, when 35 MeV protons impinge at grazing incidence onto LiF films deposited on Si(100) substrates, the Bragg peak in the films is located at the depth where it would be found in Si rather than in LiF due to multiple Coulomb scattering. In this paper, Monte Carlo simulations of proton irradiations in the 1–8 MeV energy range are performed and compared to experimental Bragg curves in optically transparent LiF films on Si(100) substrates. Our study focuses on this energy range because, as energy increases, the Bragg peak gradually shifts from the depth in LiF to that in Si. The impact of grazing incidence angle, LiF packing density, and film thickness on shaping the Bragg curve in the film is examined. At energies higher than 8 MeV, all these quantities must be considered, although the effect of packing density plays a minor role. [ABSTRACT FROM AUTHOR]

Radiation-induced color centers locally produced in lithium fluoride (LiF) are successfully used for radiation detectors. LiF detectors for extreme ultraviolet radiation, soft and hard X-rays, based on photoluminescence from aggregate electronic defects, are currently under development for imaging applications with laboratory radiation sources, as well as large-scale facilities. Among the peculiarities of LiF-based detectors, noteworthy ones are their very high intrinsic spatial resolution across a large field of view, wide dynamic range, and versatility. LiF crystals irradiated with a monochromatic 8 keV X-ray beam at KIT synchrotron light source (Karlsruhe, Germany) and with the broadband white beam spectrum of the synchrotron bending magnet have been investigated by optical spectroscopy, laser scanning confocal microscopy in fluorescence mode, and confocal Raman micro-spectroscopy. The 3D reconstruction of the distributions of the color centers induced by the X-rays has been performed with both confocal techniques. The combination of the LiF crystal capability to register volumetric X-ray mapping with the optical sectioning operations of the confocal techniques has allowed performing 3D reconstructions of the X-ray colored volumes and it could provide advanced tools for 3D X-ray detection. [ABSTRACT FROM AUTHOR]

In recent years, lithium fluoride (LiF) detectors based on the optical reading of photoluminescence emitted by radiation-induced F 2 and F 3 + colour centres have been successfully used for advanced diagnostics of proton beams. In this work, the visible photoluminescence response of LiF film-based radiation detectors of three different thicknesses, grown by thermal evaporation on glass and Si(100) substrates and irradiated with 27 MeV proton beams at doses in the range between 4.2 × 103 and 1.7 × 105 Gy, was carefully investigated by fluorescence optical microscopy. Before irradiation, the structural and morphological properties of LiF films were investigated by atomic force microscopy and X-ray diffraction techniques. Substrate-enhanced photoluminescence response up to 48% was observed in LiF film-based detectors grown on Si(100) substrates with respect to those deposited on glass in the same deposition run and irradiated in the same conditions. This photoluminescence enhancement can be mainly ascribed to the reflective properties of the Si substrate in the visible spectral range, where the emission bands of F 2 and F 3 + colour centres are located, combined with the proper choice of the film thickness. Other complex effects related to the polycrystalline nature of the LiF films cannot be excluded. • LiF thin films thermally-evaporated on glass and silicon as proton beam detectors. • Morphological and structural analysis performed by AFM and X-ray diffraction. • Radiophotoluminescence of colour centres investigated by fluorescence optical microscopy. • Substrate-enhanced photoluminescence response measured in LiF detectors grown on Si. • Enhanced photoluminescence response up to 48% depending on the LiF film thickness. [ABSTRACT FROM AUTHOR]

Irradiation of lithium fluoride with protons causes the formation of electronic defects, known as colour centres, in the crystal lattice. Two stable defects among them, the F 2 and F 3 + aggregate ones, under blue light simultaneous excitation show broad photoluminescence in the red and green visible spectral ranges, respectively, their peculiar characteristics being well known for applications in optically-pumped tuneable lasers, broad-band miniaturized light-emitting photonic devices and passive radiation imaging detectors. Recently, exploitation of their radiophotoluminescence has been successfully proposed for proton-beam advanced diagnostics and dosimetry, even at low dose values typical of radiotherapy. In the present study, lithium fluoride crystals were irradiated with 2.3 MeV protons in the dose range from ∼104 to ∼107 Gy and their dynamic range, that is the capability of detecting the widest possible range of radiophotoluminescence intensity emitted by the colour centres, was found to be 114 dB at the F 2 peak emission wavelength of 675 nm under continuous-wave laser excitation at 445 nm. Moreover, after including in the analysis a set of lithium fluoride crystals irradiated with 26.1 MeV protons in the dose range from 0.5 to 48 Gy at a much lower dose-rate, it was found that the radiophotoluminescence intensity of the F 2 colour centres shows a linear dependence with dose from 0.5 to ∼2 × 105 Gy. • Laser-excited photoluminescence spectra of proton-irradiated LiF crystals. • LiF F 2 colour centres radiophotoluminescence dynamic range is 114 dB at 675 nm. • F 2 radiophotoluminescence peak intensity vs dose is linear up to 2 × 105 Gy. • The dynamic range is higher than 100 dB in the wavelength range from 530 to 720 nm. [ABSTRACT FROM AUTHOR]

Thin films of poly(N-isopropylacrylamide) (PNIPAM) microgels have recently attracted significant attention as promising candidates for creating switchable interfaces in biomedical and biotechnological applications. In this study, microgel films are proposed as smart coatings for photoluminescent solid-state radiation detectors based on lithium fluoride (LiF). Understanding the impact of the solid substrate is crucial for customising and refining microgel coatings for specific applications. To investigate the effects of surface quality, microgel size, and particle concentration on the properties of microgel films, PNIPAM microgels were spin-coated onto LiF crystal surfaces and characterised through wettability measurements, UV-Vis-NIR spectrophotometry, and Atomic Force Microscopy. This approach enabled effective control over the optical and morphological properties of the films, paving the way for the development of hybrid and potentially biocompatible radiation detectors using PNIPAM microgel films. [Display omitted] [ABSTRACT FROM AUTHOR]