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Context. Barium (Ba) stars are characterised by an abundance of heavy elements made by the slow neutron capture process (s-process). This peculiar observed signature is due to the mass transfer from a stellar companion, bound in a binary stellar system, to the Ba star observed today. The signature is created when the stellar companion is an asymptotic giant branch (AGB) star. Aims. We aim to analyse the abundance pattern of 169 Ba stars using machine learning techniques and the AGB final surface abundances predicted by the FRUITY and Monash stellar models. Methods. We developed machine learning algorithms that use the abundance pattern of Ba stars as input to classify the initial mass and metallicity of each Ba star's companion star using stellar model predictions. We used two algorithms. The first exploits neural networks to recognise patterns, and the second is a nearest-neighbour algorithm that focuses on finding the AGB model that predicts the final surface abundances closest to the observed Ba star values. In the second algorithm, we included the error bars and observational uncertainties in order to find the best-fit model. The classification process was based on the abundances of Fe, Rb, Sr, Zr, Ru, Nd, Ce, Sm, and Eu. We selected these elements by systematically removing s-process elements from our AGB model abundance distributions and identifying the elements whose removal had the biggest positive effect on the classification. We excluded Nb, Y, Mo, and La. Our final classification combined the output of both algorithms to identify an initial mass and metallicity range for each Ba star companion. Results. With our analysis tools, we identified the main properties for 166 of the 169 Ba stars in the stellar sample. The classifications based on both stellar sets of AGB final abundances show similar distributions, with an average initial mass of M = 2.23 Mand 2.34 M and an average [Fe/H] = -0.21 and -0.11, respectively. We investigated why the removal of Nb, Y, Mo, and La improves our classification and identified 43 stars for which the exclusion had the biggest effect. We found that these stars have statistically significant and different abundances for these elements compared to the other Ba stars in our sample. We discuss the possible reasons for these differences in the abundance patterns. [ABSTRACT FROM AUTHOR]

We present detailed chemical compositions of four stars on the first-ascent red giant branch that are classified as chemically peculiar, but lack comprehensive analyses at high spectral resolution. For BD+03°2688, HE 0457−1805, HE 1255−2324, and HE 2207−1746, we derived metallicities [Fe/H] = −1.21, −0.19, −0.31, and −0.55, respectively, indicating a range in Galactic population membership. In addition to atmospheric parameters, we extracted elemental abundances for 28 elements, including the evolutionary-sensitive CNO group and 12C/13C ratios. Novel results are also presented for the heavy elements tungsten and thallium. All four stars have very large enhancements of neutron-capture elements, with high [La/Eu] ratios indicating enrichments from the slow neutron capture (s -process). To interpret these abundances, all indicative of [ s /Fe] >1.0, we compared our results with data from literature, as well as with predictions from the Monash and fruity   s -process nucleosynthesis models. BD+03°2688, HE 1255−2324, and HE 2207−1746 show C/O >1, while HE 0457−1805 has C/O <1. Since HE 0457−1805 and HE 1255−2324 are binary stars, their peculiarities are attributable to mass transfer. We identified HE 0457−1805 as a new barium giant star, and HE 1255−2324 as a new CH star, in fact a higher metallicity analogue CEMP- r / s star; the single object reported in literature so far with similar characteristics is the barium star HD 100503 ([Fe/H] = −0.72). A systematic monitoring is needed to confirm the binary nature of BD+03°2688 and HE 2207−1746, which are probably CH stars. [ABSTRACT FROM AUTHOR]

New elemental abundances for the neutron-capture elements Sr, Nb, Mo, Ru, La, Sm, and Eu are presented for a large sample of 180 barium (Ba) giant stars, a class of chemically peculiar objects that exhibit in their spectra enhancements of the elements created by the s -process, as a consequence of mass transfer between the components of a binary system. The content of heavy elements in these stars, in fact, points to nucleosynthesis mechanisms that took place within a former asymptotic giant branch (AGB) companion, now an invisible white dwarf. From high-resolution (⁠|$R=48\, 000$|⁠) spectra in the optical, we derived the abundances either by equivalent width measurements or synthetic spectra computations, and compared them with available data for field giant and dwarf stars in the same range of metallicity. A re-determination of La abundances resulted in [La/Fe] ratios up to 1.2 dex lower than values previously reported in literature. The programme Ba stars show overabundance of neutron-capture elements, except for Eu, for which the observational data set behave similarly to field stars. Comparison to model predictions are satisfactory for second-to-first s -process peak ratios (e.g. [La/Sr]) and the ratios of the predominantly r -process element Eu to La. However, the observed [Nb, Mo, Ru/Sr] and [Ce, Nd, Sm/La] ratios show median values higher or at the upper limits of the ranges of the model predictions. This unexplained feature calls for new neutron capture models to be investigated. [ABSTRACT FROM AUTHOR]