1. Nanoscale strain mapping in battery nanostructures.
- Author
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Ulvestad, A., Cho, H. M., Harder, R., Kim, J. W., Dietze, S. H., Fohtung, E., Meng, Y. S., and Shpyrko, O. G.
- Subjects
X-ray diffraction ,NANOPARTICLES ,LITHIATION ,CATHODES ,NANOSTRUCTURES - Abstract
Coherent x-ray diffraction imaging is used to map the local three dimensional strain inhomogeneity and electron density distribution of two individual LiNi
0.5 Mn1.5 O4-δ cathode nanoparticles in both ex-situ and in-situ environments. Our reconstructed images revealed a maximum strain of 0.4%. We observed different variations in strain inhomogeneity due to multiple competing effects. The compressive/tensile component of the strain is connected to the local lithium content and, on the surface, interpreted in terms of a local Jahn-Teller distortion of Mn3+ . Finally, the measured strain distributions are discussed in terms of their impact on competing theoretical models of the lithiation process. [ABSTRACT FROM AUTHOR]- Published
- 2014
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