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This study presents a new approach towards the production of sol-gel silica-coated Bi2O3/Gd2O3 cement additives towards the improvement of early mechanical performance and radiation attenuation. Two types of silica coatings, which varied in synthesis method and morphology, were used to coat Bi2O3/Gd2O3 structures and evaluated as a cement filler in Portland cement pastes. Isothermal calorimetry studies and early strength evaluations confirmed that both proposed coating types can overcome retarded cement hydration process, attributed to Bi2O3 presence, resulting in improved one day compressive strength by 300% and 251% (depending on coating method) when compared to paste containing pristine Bi2O3 and Gd2O3 particles. Moreover, depending on the type of chosen coating type, various rheological performances of cement pastes can be achieved. Thanks to the proposed combination of materials, both gamma-rays and slow neutron attenuation in cement pastes can be simultaneously improved. The introduction of silica coating resulted in an increment of the gamma-ray and neutron shielding thanks to the increased probability of radiation interaction. Along with the positive early age effects of the synthesized structures, the 28 day mechanical performance of cement pastes was not suppressed, and was found to be comparable to that of the control specimen. As an outcome, silica-coated structures can be successfully used in radiation-shielding cement-based composites, e.g. with demanding early age performances. [ABSTRACT FROM AUTHOR]

Abstract This study aims to investigate the effects of carbon nanotubes and carbon nanotube-silica core-shell structures, on the behaviour of cement pastes exposed to high temperature (300, 450 and 600 ° C). Pristine multi-walled carbon nanotubes (MWCNTs) were coated with a solid nanosilica (NS) shell, to form a core-shell nanostructure (MWCNT/NS). The cement pastes were incorporated with three different nanomaterial contents equal to 0.125, 0.25 and 0.5 wt.-% of cement. The results demonstrate that incorporation of an optimum amount (0.125 wt.-%) of MWCNT/NSs, is much more beneficial than the incorporation of MWCNTs, for improving the properties of unheated and heated cement pastes. Silica shell improves the binding ability between cement matrices and nanotubes, which is reflected in specimens' compressive strength retention, as well as in decreased micro-cracking. However, exceeding the optimum amount of MWCNTs and MWCNT/NSs can lead to an agglomeration of nanomaterial, thus decreasing the thermal resistance of cement pastes. Graphical abstract Image 1 Highlights • Proposal of a green method of carbon nanotube-nanosilica (MWCNT/NS) core shell structure synthesis. • The use of MWCNT/NSs is more beneficial than the use of pristine MWCNTs, for compressive strength improvement. • MWCNT/NS structures present better mechanical and microstructural performance under elevated temperature. • Incorporation of MWNCT and MWCNT/NS decreases the cracking of specimens under elevated temperature. [ABSTRACT FROM AUTHOR]

This study investigates the effects of Fe 3 O 4 and Fe 3 O 4 /SiO 2 nanoparticle admixtures on the behavior of cement mortars exposed to elevated temperatures. Pristine nanoparticles of magnetite (Fe 3 O 4 ) were coated with a solid silica shell (via the Stöber method), to form a core-shell nanostructure (Fe 3 O 4 /SiO 2 ). The cement mortars were incorporated with an optimized ratio of 3 wt% Fe 3 O 4 and 5 wt% of Fe 3 O 4 /SiO 2 admixture. The specimens were exposed to elevated temperatures of 200, 300, 450, 600 and 800 °C. After cooling, the mass loss and flexural and compressive strengths of the specimens were determined. The results demonstrated that the presence of magnetite-silica (Fe 3 O 4 /SiO 2 ) nanostructures is much more beneficial for improving the thermal resistance of cement mortars than pristine Fe 3 O 4 nanoparticles. The silica (SiO 2 ) shell in the nanoparticles improves residual compressive strength and prevents crack extension in cement mortars exposed to elevated temperatures. The investigations undertaken in this study were supported by optical and scanning electron microscopic studies. [ABSTRACT FROM AUTHOR]

The scope of the study is to test the influence of nanocomposite silica-titania (mSiO 2 /TiO 2 ) core-shell structures on the mechanical and bactericidal properties of cement mortars. Nanocomposites are widely applied in many fields of science however, cement-based composites are mainly modified with single type of nanostructures. The goal of the presented work is to obtain a nanocomposite which exhibits the positive properties of both nanomaterials, while diminishing the negative impacts of each of the nanomaterials applied separately. The study shows that application of silica-titania (mSiO 2 /TiO 2 ) core-shell nanostructures simultaneously demonstrated the properties of nanosilica and titanium dioxide and thus the nanomaterial behaved not only as a filler to improve the microstructure and activator to promote pozzolanic reaction, but also exhibited self-cleaning and bactericidal properties when exposed to UV light. The observed improvement of compressive strength was caused by the presence of nanosilica (acting as a core) while titanium dioxide (shell) exhibits photocatalytic activity. [ABSTRACT FROM AUTHOR]

In recent years utilization of solid waste in building materials has gathered spectacular attention. One material with potential applications, especially in cement-based composites, is waste glass. The aim of this study was to evaluate the possibility of manufacturing sustainable cement mortars with the use of nanosilica (NS) and brown soda-lime waste glass (WG) fine aggregate. The mechanical and thermal properties of cement mortars containing WG aggregate and nanosilica, were analyzed in terms of waste glass and nanosilica content. Ordinary fine aggregate (river sand) was replaced with WG fine aggregate at a ratio of 100% by weight. Moreover, 0, 1 and 3 wt% of NS was incorporated to cement mortar. The experiment revealed that the presence of WG fine aggregate significantly decreased the thermal conductivity of the cement mortars and that furthermore, the sorptivity coefficient decreased. The study has shown that WG fine aggregate can be a successful substitute for natural fine sand without leading to mechanical deterioration and by significantly improving thermal properties of cement mortars. Additionally, the incorporation of nanosilica (especially in higher contents – 3 wt%) leads to a further decrement in thermal conductivity and sorptivity and improves compressive strength. [ABSTRACT FROM AUTHOR]

In this contribution the effect of nanosilica (NS) on the behavior of cement mortars containing quartz aggregate and two types of heavyweight aggregates (magnetite and barite) exposed to elevated temperature will be investigated. The cement mortars have been modified with nanosilica in quantities of 1%, 2%, 3%, 4% and 5% (by weight of cement). The samples were exposed to the elevated temperatures of 200 °C, 400 °C, 600 °C and 800 °C, respectively. The mass loss, flexural and compressive strength of the cooled specimens were determined. Additionally, by means of scanning electron microscopy (SEM) and optical microscopy the structure defects have been determined. The results clearly demonstrate that there is an optimal nanosilica content, in the cement mortar containing quartz and magnetite aggregate, improving the thermal resistance and preventing the crack extension (especially in the range of 200–400 °C). However, the study has also shown that cement mortars containing barite aggregate tend to crack and exhibit spalling as a result of low thermal resistance of the aggregate. [ABSTRACT FROM AUTHOR]

The recycling of waste glass is a major problem for municipalities worldwide. The problem concerns especially colored waste glass which, due to its low recycling rate as result of high level of impurity, has mostly been dumped into landfills. In recent years, a new use was found for it: instead of creating waste, it can be recycled as an additive in building materials. The aim of the study was to evaluate the possibility of manufacturing sustainable and self-cleaning cement mortars with use of commercially available nanomaterials and brown soda-lime waste glass. Mechanical and bactericidal properties of cement mortars containing brown soda-lime waste glass and commercially available nanomaterials (amorphous nanosilica and cement containing nanocrystalline titanium dioxide) were analyzed in terms of waste glass content and the effectiveness of nanomaterials. Quartz sand is replaced with brown waste glass at ratios of 25%, 50%, 75% and 100% by weight. Study has shown that waste glass can act as a successful replacement for sand (up to 100%) to produce cement mortars while nanosilica is incorporated. Additionally, a positive effect of waste glass aggregate for bactericidal properties of cement mortars was observed. [ABSTRACT FROM AUTHOR]

The recycling of waste glass is a major problem for municipalities worldwide due to high disposal costs and environmental concerns. Recycling glass from the municipal solid waste stream in order to manufacture new glass products is limited due to high costs, impurities, and mixed color. Although colorless waste glass has been recycled effectively, colored waste glass with its low recycling rate, has mostly been dumped into landfills. Due to its high level of impurity, colored glass cannot be processed easily. A new use was found for it, instead of creating waste: an additive in building materials. In this study, the self-cleaning properties and strength development characteristics of mortar containing waste glass and nanomaterials (nanosilica – nSiO 2 and titanium dioxide – TiO 2 ) are analyzed in terms of waste glass content and the effectiveness of commercially available nanomaterials. Quartz sand is replaced with brown waste glass at ratios of 25%, 50% and 100% by weight. The photodegradation of the rhodamine B test has been conducted to analyze the effect of titanium dioxide, nanosilica and waste glass presence in the cement mortar for its potential application in self-cleaning façades. Studies have shown that waste glass can act as a successful replacement for sand, especially when mixed partially with sand. Additionally, a positive influence of nanomaterials on the self-cleaning and mechanical properties was noted. [ABSTRACT FROM AUTHOR]

The use of lightweight concrete (LWC) for structural and non-structural applications has attracted great interest in recent years. The main benefits include reduced deadload of structural elements and generally lower production and transportation costs. However, a decrease in concrete density often leads to a decrease in strength and durability. Typically, concretes are mostly modified with mineral additives such as silica fume or fly ash. Because of the recent developments in nanotechnology, research attention has turned to the possibility of improving concrete properties with nanomaterials, i.e., nano-SiO2. However, there are still certain issues with the dosage and efficiency of nanomaterials. Therefore, in order to establish the current state of knowledge in this field, this review gathers most recent results about the performance of LWC modified with nanomaterials. The review is divided into sections about the influence of nanoparticles on the fresh properties of concrete and their influence on the mechanical and durability characteristics. The paper studies in depth the most common approach to nanomaterials in concrete technology and proposes areas for further development. [ABSTRACT FROM AUTHOR]

• 3D printable mortars containing different dosages of nanosilica (NS) were developed and evaluated. • NS accelerates significantly the setting and hardening of printable mortar, while reducing its open time. • Increment of yield stress, together with an increment in NS dosage, was found to have occurred. • Optimal NS dosage results in improvement of the compressive strength and pore structure. • Incorporation of NS in the mixture resulted in improved buildability and decrement in pore anisotropy. This study presents the experimental results of an investigation on the effects of nanosilica (NS) on the material characteristics of printable mortars used for additive manufacturing. Printable cement mortars based on Ordinary Portland Cement, limestone filler and silica sand were modified with different dosages of nanosilica (from 2% to 6% by weight of binder) and its influence on their hydration, rheological, mechanical and transport properties was assessed. The study showed that NS accelerates significantly the setting and hardening of printable mortar, while reducing its open time. Moreover, an increment of yield stress, together with an increment in NS dosage, was found to have occurred. The incorporation of an optimal NS dosage results in a noticeable increase in the compressive strength and alteration of the pore structure as determined by the MIP measurements. Moreover, transport properties of the produced mortar are significantly improved due to incorporation of NS. In addition to the microstructure refinement, Micro-CT and scanning electron microscopy (SEM) studies revealed that 3D printed mortars exhibit pore anisotropy in accordance with the printing direction. However, incorporation of NS in the mixture resulted in improved buildability, thus decreasing pore anisotropy. [ABSTRACT FROM AUTHOR]

• Lightweight aggregate concretes (LWACs) with a targeted density of 850 kg/m3, and 450 kg/m3 were developed. • Cement was replaced with 1, 2, 5 and 10% nanosilica (by mass of cement). • Shrinkage, transport, mechanical and microstructural (2D and 3D) properties of concretes were evaluated. • Nanosilica has a beneficial effect in improving the mechanical and transport properties of concretes. • Nanosilica significantly improves the pore characteristics of lightweight concretes. This work is aimed at characterizing the effects of nanosilica (NS) on the properties of lightweight aggregate concretes with different densities. Lightweight aggregate concrete (LWAC) and ultra-lightweight aggregate concrete (ULWAC) with targeted oven-dry densities of 850 kg/m3 and 450 kg/m3, respectively, were produced. The mixtures were modified by replacing cement with nanosilica, in concentrations of 1, 2, 5 and 10 wt-%. For comparison purposes, control specimens containing either cement alone or cement with silica fume (SF) were also produced. Their mechanical properties, including flexural and compressive strengths and transport characteristics, were evaluated by measuring the water accessible porosity and water absorption coefficients of the concretes. In addition, the thermal conductivity and drying shrinkage, being important parameters of lightweight concrete, were characterized. The pore structure characteristics of the concretes were assessed using 2D and 3D image analysis techniques; namely, using an automated air void analyser and micro-computed tomography (micro-CT), respectively. The experimental results show that NS has a significant effect on improving the mechanical and transport properties of lightweight concretes and that the efficiency of NS is much higher than that of SF. Moreover, depending on dosage, NS was found to have a negligible or decreasing influence on the drying shrinkage of concrete, after 28 days of curing. Microstructural studies confirmed that NS significantly affects the pore characteristics of concretes, thus resulting in concretes with denser and stronger microstructures. [ABSTRACT FROM AUTHOR]

This investigation studies the effects of hot water and hot air curing on the strength development, transport properties, and freeze-thaw resistance of mortars incorporating low-heat blast furnace slag cement and nanosilica (NS). Mortar samples were prepared and stored in ambient conditions for 24 h. After demolding, mortar samples were subjected to two different hot curing methods: Hot water and hot air curing (40 °C and 60 °C) for 24 h. For comparison purposes, mortar reference mixes were prepared and cured in water and air at ambient conditions. Strength development (from 1 to 180 days), capillary water porosity, water sorptivity, and freeze-thaw resistance were tested after 180 days of curing. The experimental results showed that both curing regimes accelerate the strength development of mortars, especially in the first seven days of hydration. The highest early strengths were reported for mortars subjected to a temperature of 60 °C, followed by those cured at 40 °C. The hot water curing regime was found to be more suitable, as a result of more stable strength development. Similar findings were observed in regard to durability-related properties. It is worth noting that thermal curing can more efficiently increase strength in the presence of nanosilica, suggesting that NS is more effective in enhancing strength under thermal curing. [ABSTRACT FROM AUTHOR]

This study presents the results of an experimental investigation of the effects of nanosilica (NS) on the strength development, transport properties, thermal conductivity, air-void, and pore characteristics of lightweight aggregate concrete (LWAC), with an oven-dry density <1000 kg/m3. Four types of concrete mixtures, containing 0 wt.%, 1 wt.%, 2 wt.%, and 4 wt.% of NS were prepared. The development of flexural and compressive strengths was determined for up to 90 days of curing. In addition, transport properties and microstructural properties were determined, with the use of RapidAir, mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM) techniques. The experimental results showed that NS has remarkable effects on the mechanical and transport properties of LWACs, even in small dosages. A significant improvement in strength and a reduction of transport properties, in specimens with an increased NS content, was observed. However, the positive effects of NS were more pronounced when a higher amount was incorporated into the mixtures (>1 wt.%). NS contributed to compaction of the LWAC matrix and a modification of the air-void system, by increasing the amount of solid content and refining the fine pore structure, which translated to a noticeable improvement in mechanical and transport properties. On the other hand, NS decreased the consistency, while increasing the viscosity of the fresh mixture. An increment of superplasticizer (SP), along with a decrement of stabilizer (ST) dosages, are thus required. [ABSTRACT FROM AUTHOR]