1. Preparation of thin-film composite membranes supported with electrospun nanofibers for desalination by forward osmosis.
- Author
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Al-Furaiji, Mustafa, Kadhom, Mohammed, Kalash, Khairi, Waisi, Basma, and Albayati, Noor
- Subjects
COMPOSITE membranes (Chemistry) ,POLYACRYLONITRILES ,OSMOSIS ,REVERSE osmosis ,CONTACT angle ,NANOFIBERS ,ELECTRODE reactions - Abstract
The forward osmosis (FO) process has been considered to be a viable option for water desalination in comparison to the traditional processes like reverse osmosis, regarding energy consumption and economical operation. In this work, a polyacrylonitrile (PAN) nanofiber support layer was prepared using the electrospinning process as a modern method. Then, an interfacial polymerization reaction between m -phenylenediamine (MPD) and trimesoyl chloride (TMC) was carried out to generate a polyamide selective thin-film composite (TFC) membrane on the support layer. The TFC membrane was tested in FO mode (feed solution facing the active layer) using the standard methodology and compared to a commercially available cellulose triacetate membrane (CTA). The synthesized membrane showed a high performance in terms of water flux (16 Lm -2 h -1) but traded the salt rejection (4 gm -2 h -1) compared with the commercial CTA membrane (water flux = 13 Lm -2 h -1 and salt rejection = 3 gm -2 h -1) at no applied pressure and room temperature. Scanning electron microscopy (SEM), contact angle, mechanical properties, porosity, and performance characterizations were conducted to examine the membrane. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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