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Multiphase nanocomposites based on epoxy resin loaded with 1 wt% of multiwalled carbon nanotubes (MWCNTs) and different amounts of hydrotalcite clay (HT) are experimentally characterized in order to investigate their possible usage as temperature sensors and/or heating elements. In particular, the effects of clay content on the temperature dependence of the electrical and thermal properties of the samples are investigated. Moderate clay content (0.7% or 1% by weight) induces an improvement of the electrical and thermal conductivities, thus allowing to achieve fixed heating power levels with applied voltages lower than those required for MWCNT filled epoxy systems. The operating temperatures can be designed to be lower than that the glass transition reducing the risk of material degradation. Furthermore, the presence of clay increases the sensitivity compared to the (binary) MWCNT-based composites. The proposed multiphase nanocomposites could be used for the deicing of aircraft structural parts, in small boilers, floor pipes, and so on. [ABSTRACT FROM PUBLISHER]

A structure aimed at modeling a polymeric nanocomposite loaded with carbon nanotubes (CNTs) is simulated by considering, in a three-dimensional space, a random distribution of impenetrable conducting cylinders inside an insulating cubic matrix. The variation of the electrical conductivity of the structure for different volume loadings of the conducting phase is estimated through a 3D resistor network. The tunneling effect between conducting clusters which is deemed responsible of the global conductivity is taken into account. By using a Monte Carlo method, the electrical conductivity and the percolation thresholds of the obtained structures are analyzed as a function of geometrical and physical influencing parameters. [ABSTRACT FROM AUTHOR]

The limitation of poor mechanical stability and difficulties in printing electrically conductive components can be overcome owing to the recent introduction of nanotechnology into the field of additive manufacturing (AM) and the consequent development of nonconventional polymer nanocomposites suitable for 3D printing. In the present work, different weight percentages (up to 6 wt % in total) of carbon-based nanostructures—multiwalled carbon nanotubes (MWCNTs), graphene nanoplatelets (GNPs), and a combination of both fillers (MWCNTs/GNPs)—were incorporated into poly(lactic) acid (PLA, Ingeo™) in an attempt to overcome several limitations of conventional 3D manufacturing based on insulating materials. Solution blending and melt mixing were the two fabrication methods adopted for preparation of the samples under test. A comparison of the morphological, rheological, and electrical properties of the resulting nanocomposites was carried out. Moreover, for the same weight concentrations, the influence of physical and geometrical features (i.e., functionalization and aspect ratio) of the embedded fillers was also investigated. Rheological methods were applied to control the quality of fillers dispersion in PLA matrix. The rheological percolation threshold was considered as reference in order to evaluate the internal structure of nanodispersions. TEM visualization, combined with rheological characterizations, was used for efficient control of the nanofiller dispersion. DC characterization revealed that lower electrical percolation thresholds and higher values of electrical conductivity were achieved using fillers with a larger aspect ratio and melt mixing, respectively. Moreover, given the possibility of obtaining complex and appropriate shapes for electromagnetic compatibility (EC) applications, electromagnetic (EM) response of the nanocomposites at the highest filler concentration was investigated in GHz and THz regions. It was found that the electromagnetic shielding efficiency (EMI) of nanocomposites strongly depended on the aspect ratio of the nanofillers, whereas the type of processing technique did not have a significant effect. Therefore, a careful choice of methods and materials must be made to address the final application for which these materials and further 3D printed architectures are designed. [ABSTRACT FROM AUTHOR]

Abstract This paper aims to address current limitations of 3D printed conductive materials through the development of a novel formulation of a thermoplastic composite. In particular, a conductive filament suitable for three-dimensional printing is obtained on the basis of Polylactic acid (PLA) filled with two types of highly conductive nano-carbon materials, i.e. multi-walled carbon nanotubes (MWCNTs), graphene nanoplates (GNPs) and a combination of both fillers (MWCNT/GNP). A systematic rheological and electrical characterization of the resulting nanocomposites is presented. Viscoelastic properties and rheological percolation threshold are determined for the binary and ternary composites and related to the size of nanoparticles. Comparable values for the percolation threshold are found by means of rheological and electrical studies. Low electrical percolation thresholds and high values of the electrical conductivity of the order of S/m are achieved for the investigated formulations. At the highest filler loading (i.e. 12 wt%) the electrical conductivity reaches the value of 4.54 S/m, 6.27 S/m and 0.95 S/m for the composites based on MWCNTs, GNPs and multiphase system, respectively. These results, together with the good stability shown by the nano-reinforced PLA in the frequency range [100 Hz-1MHz] make these composites promising candidates for 3D printed conductive devices for electromagnetic (EM) applications. [ABSTRACT FROM AUTHOR]