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Start Over Author "Gosens, Ronald" Topic molecular association
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1. Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes.

Author

Berrocal, José Augusto, Di Meo, Florent, García-Iglesias, Miguel, Gosens, Ronald P. J., Meijer, E. W., Linares, Mathieu, and Palmans, Anja R. A.

Subjects
HYDROGEN bonding, MOLECULAR association, SOLVENTS, ENANTIOSELECTIVE catalysis, HETEROGENEOUS catalysis, ALKANES
Abstract

We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2 : 1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes. [ABSTRACT FROM AUTHOR]

Published
2016
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