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Start Over Author "Jiang, Yu-Bo" Topic microwave
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1. Pd-catalyzed ligand-free C(5)–H arylation of 1,4-disubstituted 1,2,3-triazoles promoted by microwaves.

Author

Zhao, Fen, Tian, Wen-Hai, Luo, Fang, Cheng, Hui-Ling, Jiang, Yu-Bo, and Chen, Zhen

Subjects
PALLADIUM, CATALYTIC activity, MICROWAVES, REGIOSELECTIVITY (Chemistry), LIGAND binding (Biochemistry)
Abstract

Pd(OAc)2-catalyzed regioselective C(5)–H arylation of 1,4-disubstituted 1,2,3-triazoles was achieved without ligand under microwave conditions in 1 h, generating 1,4,5-trisubstituted 1,2,3-triazoles with good to excellent yields. The obtained molecules can be easily converted into 4,5-disubstituted 1,2,3-triazoles through the debenzylation process with one-pot manipulation. [ABSTRACT FROM PUBLISHER]

Published
2016
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