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The extent to which solid‐state volume diffusion modifies rare earth element (REE) abundances in accessory minerals during high‐temperature metamorphism governs our ability to link recorded trace‐element compositions to particular thermal events. We model diffusion of REE in zircon under different temperature–time conditions and show that, for both short‐lived (e.g. 1100°C for 1–5 Ma) and more prolonged (e.g. 1050°C for 10–30 Ma or 1000°C for 200 Ma) episodes of ultra‐high‐temperature (UHT) metamorphism, REE diffusion in igneous zircon is sufficiently rapid for REE in a ~50‐μm grain to equilibrate with the new metamorphic mineral assemblage of the host rock. By contrast, unless diffusion is accelerated by recrystallization, the presence of fluids or other processes at temperatures below 900°C zircon will largely retain its original pre‐metamorphic REE abundance pattern, even when the thermal event is long lived (≥100 Ma). Where volume diffusion is dominant, for instance, in the absence of a fluid phase, the sensitivity of REE mobility to temperature can help constrain the temperature–time path of high‐grade metamorphic rocks. Modelling of well‐characterized natural samples from the regional‐scale aureole surrounding the Rogaland Igneous Complex (RIC) in SW Norway shows that variations in REE concentration patterns in zircon indicate a T–t evolution that is consistent with independent P–T–t estimates for regional metamorphism based on phase equilibrium modelling (850–950°C at 7–8 kbar for ~100 Ma). Greater modification of REE abundance patterns in zircons within 2 km of the RIC contact, however, indicates that UHT conditions persisted for ~150 Ma close to the intrusion, with a temperature of ~1100°C for 1–5 Ma at the RIC contact. Thermal modelling suggests that the inferred T–t histories of samples from different distances from the RIC contact are best explained if the complex was emplaced incrementally over 1–5 Ma. [ABSTRACT FROM AUTHOR]

Here, we present results of the first 40Ar/39Ar dating of osumilite, a high‐T mineral that occurs in some volcanic and high‐grade metamorphic rocks. The metamorphic osumilite studied here is from a metapelitic rock within the Rogaland–Vest Agder Sector, Norway, an area that experienced regional granulite facies metamorphism and subsequent contact metamorphism between 1,100 Ma and 850 Ma. The large grain size (~1 cm) of osumilite in the studied rock, which preserves a nominally anhydrous assemblage, increases the potential for large portions of individual grains to have remained essentially unaffected by the effects of diffusive argon loss, potentially preserving prograde ages. Step‐heating diffusion experiments yielded a maximum activation energy of ~461 kJ/mol and a pre‐exponential factor of ~8.34 × 108 cm2/s for Ar diffusion in osumilite. These parameters correspond to a relatively high closure temperature of ~620°C for a cooling rate of 10°C/Ma in an osumilite crystal with a 175 µm radius. Fragments of osumilite separated from the sample preserve a range of ages between c. 1,070 and 860 Ma. The oldest ages are inferred to date the growth of coarse‐grained osumilite during prograde granulite facies regional metamorphism, which pre‐date contact metamorphism that has historically been ascribed to the growth of osumilite in the region. The majority of fragments record ages between c. 920 and 860 Ma, inferred to reflect the growth of osumilite and/or diffusive argon loss during contact metamorphism. The retention of old 40Ar/39Ar dates was facilitated by the low diffusivity of Ar in osumilite (i.e. a closed system), large grain sizes, and anhydrous metamorphic conditions. The ability to date osumilite with the 40Ar/39Ar method provides a valuable new thermochronometer that may constrain the timing and duration of high‐T magmatic and metamorphic events. [ABSTRACT FROM AUTHOR]

Highlights • We study the age and metamorphic evolution of (meta)gabbros from the Albany–Fraser orogeny. • The rocks record common magmatic and peak metamorphic conditions of ∼900–950 °C and ∼7 kbar. • The gabbros crystallised at ca 1300 Ma, synchronous with high-grade metamorphism. • The Fraser Zone probably represents the deep levels of a backarc. Abstract The Fraser Zone is a major lithotectonic domain of the Albany–Fraser Orogen, Western Australia, which records Proterozoic modification of the margin of the Archean Yilgarn Craton. The Fraser Zone is volumetrically dominated by gabbroic rocks and their metamorphosed equivalents. However, little is known of the pressure–temperature–time (P–T–t) history or the geodynamic setting of these mafic rocks. When considered within the context of existing P–T constraints from spatially-associated metapelitic rocks, modelled phase equilibria suggest that both the unmetamorphosed gabbros and the granulite facies metagabbroic rocks equilibrated at 950–900 °C and ∼7 kbar, interpreted to record the conditions of magmatic crystallisation and peak metamorphism, respectively. These data support the view that mafic magmatism was the thermal driver for high- T , low- P granulite facies metamorphism. The absence of garnet from the metagabbroic rocks, and the lack of evidence for its former presence (i.e., as inclusions), argues that, during metamorphism, the rocks never reached pressures above those they attained at the thermal peak. Coronæ of zircon around ilmenite in the magmatic rocks reflect a local supply of Zr as it exsolved from ilmenite, permitting earlier growth of zircon around ilmenite than elsewhere during melt crystallisation. U–Pb dating of coronal zircon (1315 ± 5 Ma) and a discrete magmatic zircon grain isolated from ilmenite (1296 ± 5 Ma) constrain the duration of magmatic crystallisation between ca. 10 and 30 Ma. Zircon in a metamorphosed gabbro constrains the timing of granulite facies metamorphism to 1293 ± 6 Ma, synchronous with final crystallisation of the mafic magmas. Based on the implied metamorphic evolution of these rocks and that of the surrounding supracrustal package, along with existing isotopic and geochemical data, we suggest the Fraser Zone probably formed in a backarc, or perhaps an intracontinental rift setting, and records successive emplacement of gabbroic rocks into a thick, sediment-filled basin. The older gabbroic rocks record hydration and reaction with the devolatilising and/or partially molten metasedimentary rocks into which they were emplaced. Subsequent granulite facies metamorphism of these hydrated rocks was driven by the heat provided by the intrusion of younger mafic magmas. [ABSTRACT FROM AUTHOR]