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In our present work, TiN suspension was sprayed onto the 316 stainless steel substrate using the suspension high velocity oxy fuel thermal spray. An in-situ reaction between TiN and O 2 occurred during the spray process to form TiO 2 and TiN/TiO 2 composite coatings were fabricated. The phase evolution, microstructures and tribological properties of TiN/TiO 2 composite coatings were studied. Results showed that the interface between the coating and the substrate was well bonded, which was mainly owing to the in-situ reaction heat and the sufficient deformation of particles. The structure of molten particles, small grain size and low porosity could contribute to improving the mechanical and tribological properties of the in-situ coating. A schematic exfoliation process of TiN/TiO 2 composite coating was proposed to analyze the failure of coatings. The antiwear mechanisms of the TiN/TiO 2 composite coatings were discussed. The good cohesive bonding strength and high hardness of the TiN/TiO 2 composite coating, the pinning role of TiN in crack propagation, and the newly formed TiO 2 in the friction layer during the sliding test contributed to the improvement of tribological properties for the TiN/TiO 2 composite coating. This work could provide a reference for the application of TiN/TiO 2 composite coating in the field of friction and wear. [ABSTRACT FROM AUTHOR]

This paper aims to experimentally investigate the effect of graphene nanoplatelets (GNPs) doped Al2O3 coating deposited on the surface of cemented carbide substrate using suspension high velocity oxy fuel (SHVOF) thermal spraying technique. Scanning electron microscopy was applied to characterize GNPs doped Al2O3 feedstock, the surface morphologies of cemented carbide before and after spraying, and the wear track morphology of cemented carbide after wear tests. The phases of GNPs doped Al2O3 feedstock, uncoated and coated cemented carbide were analyzed by X‐ray diffraction. The existence of GNPs was analyzed by Raman spectroscopy. A mixture of un‐molten and molten splats formed on the surface of cemented carbide substrate after SHVOF thermal spray. The average coefficient of friction (CoF) of coated samples was slightly lower than that of uncoated samples, which might be due to the friction‐reduction effect of GNPs. The wear rate of the samples was one order of magnitude higher than that of the alumina ball, showing that the wear of samples was the main wear between the friction couples. The wear mechanism of uncoated sample was mainly fatigue spalling, and that of cemented carbide substrate coated with GNPs doped Al2O3 coating was mainly plowing and abrasive wear. [ABSTRACT FROM AUTHOR]

In our present work, alumina/BNNTs and alumina/MoS 2 coatings were deposited onto stainless steel substrates by solution precursor high velocity oxy-fuel thermal spraying. The phase evolution, microstructure and tribological properties of the two kinds of coatings were studied. Investigation of the phased content showed that Al 2 O 3 , BN and MoS 2 survived in the coatings after being sprayed with SHVOF technology. Cross-section images of the coatings showed that the interface between the coating and the substrate was well bonded, and there were no obvious particle inclusions and defects at the interface. The top morphology of the coatings exhibited certain degree of particle deformation, which was conducive to the formation of a more compact coating with less porous and better bonding strength with the substrate. Dry sliding tests showed that alumina/BNNTs and alumina/MoS 2 coating improved the tribological properties of the samples and they were suitable for low load friction conditions (5 and 10 N). A crack evolution model was proposed to analyze the failure of coatings. This work could provide a reference for the application of the two coatings in the field of friction and wear. • Alumina/BNNTs and alumina/MoS 2 were deposited onto a stainless steel substrate using SHVOF thermal spraying. • The top morphology of the coatings exhibited a certain degree deformation of the particles. • The wear mechanisms of the coatings were dominated by coating peeling off, adhesion and abrasive wear. • A crack evolution model was proposed to analyze the failure of coatings. [ABSTRACT FROM AUTHOR]