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The eastern Qinling belt is characterized by widespread Mesozoic post-orogenic magmatism and abundant Mo–(Au–Ag) polymetallic mineralization. Most Mo deposits in this belt are genetically related to Mesozoic granitoids. The tectonic context of this close spatial and temporal relationship is still debated. This study reports U–Pb ages and Hf isotopic composition of zircons, major and trace element and Sr–Nd–Pb isotopic composition of the Donggou granite porphyry, host rock to one of the important Mesozoic Mo deposits in this orogen. Based on geochemical results, the Donggou granite porphyry is a silica-supersaturated, high-K metaluminous A-type granite showing enrichment in light REEs, depletion in middle REEs and significant negative Eu, Ba, Nb, Sr, P, and Ti anomalies. Negative initial ϵNdvalues of −17.0 to −13.2 for whole-rock and negative initial ϵHfvalues of −19.9 to −7.8 for zircon suggest that the magma was derived from a mixture of Archaean/Proterozoic crustal rocks and mantle-derived or newly added crust. Its Pb isotopic composition is similar to the lower crust of the North China block, but different from superjacent country rocks (Xiong'er and Taihua Groups). Zircon U–Pb dating yields a late Mesozoic emplacement age of 118–117 Ma, identical with the third episode of Mo mineralization in the eastern Qinling–Dabie belt. We postulate that the Donggou Mo-related porphyry granite formed by reworking of North China lower crust with significant input of juvenile material. The magmas formed in an extensional tectonic setting, induced by lithospheric thinning and asthenospheric upwelling beneath eastern China during Cretaceous time. [ABSTRACT FROM AUTHOR]

Granitic rocks forming in the syn- to post-orogenic stages can trace the compositional and structural complexity of the crust beneath an orogenic belt. The Qinling orogenic belt undertook multiple stages of tectonics and magmatism, resulting in the multifaceted evolution and compositional diversity of the crust. In the present study, the Guangtoushan and Miba plutons in South Qinling were chosen to reveal the crustal heterogeneity in study area via isotopic geochemistry and zircon geochronology. The Guangtoushan pluton was emplaced between ~215 Ma and ~202 Ma and the Miba pluton formed at ~213 Ma, as constrained by zircon U-Pb isotopic dating. Granitic rocks of the Miba pluton are characterized by amphibole bearing and homogeneous composition, with relatively depleted Sr-Nd isotopic compositions (initial 87Sr/86Sr values of 0.7060 to 0.7084 and initial εNd values of −5.4 to −9.5) and high Pb isotopic values. The Guangtoushan pluton contains muscovite and complex inherited zircon grains and has variable Sr-Nd isotopic composition (initial 87Sr/86Sr values of 0.7050 to 0.7091 and initial εNd values of −4.5 to −12.9) and low Pb isotopic values. Felsic magmas of the Guangtoushan pluton should be derived mainly from meta-sedimentary rocks beneath South Qinling, while the Miba pluton originated primarily from partial melting of meta-igneous rocks. The compositional diversity recorded in the Early Mesozoic plutons was caused by the heterogeneous crust, and partial melting was induced by heating of the up-welling asthenosphere in a post-collision setting. [ABSTRACT FROM AUTHOR]

The Qinling Orogen resulted from the collision between the North and South China blocks in the Triassic. Mesozoic granitoids, ranging from the Triassic to the Cretaceous, are widely distributed in this orogen, and they provide excellent clues for understanding the crustal evolution and geodynamic evolution of the orogenic belt. The Triassic belt is mostly located in the South Qinling, whereas the Cretaceous belt is located mostly in the North Qinling. The Taibai complex pluton is located at the conjunction of the two belts. Here we present a data set comprising zircon U-Pb dating and elemental and Sr-Nd isotopic geochemistry for Late Mesozoic granite and microgranular enclaves (MME) exposed in the Taibai complex pluton. The granite and MME yield concordant U-Pb zircon ages of 124 to 118 Ma, indicating that they were products of roughly simultaneous magmatism in the Late Mesozoic. The granite rocks are high-K, calc-alkaline, and weakly peraluminous in compositions, and they are characterized by enrichment in large ion lithophile elements (e. g., Rb, Ba), depletion in high field strength elements (e.g., Nb, Ta, Zr, Ti), and variable Sr/Y ratios of 7.64 to 63.6. Low MgO, Cr, and Ni contents imply that the magma(s) were essentially crust-derived. Both the granite and the MME show relative depletion in Sr-Nd isotopic composition (initial 87Sr/86Sr of 0.704 4 to 0.706 7, initial εNd values of −3.4 to −2.6), suggesting that the magma(s) originated from juvenile crustal rocks. These Sr-Nd isotopic characteristics are significantly different from those of other Late Mesozoic granitoids exposed elsewhere in the Qinling orogenic belt, which formed from much older and enriched sources and with negligible contributions from mantle or juvenile crust. We propose a reworking event of the juvenile crust during the Late Mesozoic that was triggered by the tectonic extension and subsequent asthenospheric upwelling that occurred in eastern China. [ABSTRACT FROM AUTHOR]

Numerous late Mesozoic (Late Jurassic to Early Cretaceous) granitic plutons are present along the southern margin of the North China Craton (s-NCC), which belongs to the northernmost tectonic unit of the eastern Qinling orogenic belt. This tectonic unit records multiple tectonothermal and metallogenic events that occurred after continental collision of the North and South China Cratons in the late Early to Middle Triassic. This study reports the zircon U-Pb ages and the whole-rock and apatite geochemical compositions of the Taishanmiao granite, one of the largest late Mesozoic plutons in eastern Qinling. Three phases of this granite, emplaced between ∼125 and ∼113 Ma, are characterized by uniformly high SiO2 and K2O but low CaO, TFe2O3, and MgO contents and enriched Nd isotopic composition with initial ε Nd values of −13.5 to −12.7. Geochemical features reveal that these are A-type granites derived from partial melting mainly of ancient crust. Temperatures obtained from Ti-in-zircon thermometry and oxygen fugacity (f O2) data indicate that the magma(s) formed at high crystallization temperatures (∼800°–840°C) and f O2 levels (fayalite–magnetite–quartz [FMQ] buffer −1.5 to +1.5). Comparison with neighboring granites, such as the ∼150–130 Ma adakitic Heyu granite and the ∼115 Ma Donggou ore-bearing granite porphyry, implies that the Heyu granite formed from thickened crust and that the Donggou granite porphyry and Taishanmiao granite likely originated from a consistent magma system during the crustal thinning that occurred ∼125–113 Ma, except the porphyry rock was more evolved. This finding implies that their uniform magma chamber could provide sufficient metals and associated materials and even energy for the Donggou Mo deposit. [ABSTRACT FROM AUTHOR]

In our previous study on petrogenesis of quartz syenite and granite porphyry, the host rocks of the Late Mesozoic Shapinggou Mo deposit in the Qinling–Dabie orogenic belt, we found that the initial Sr isotopic composition of the host rocks is strongly affected by the degree of K-alteration. Here, we provide further isotopic evidence of the host rocks and their minerals to investigate the geochemical behaviour of trace elements and isotopes during the alteration and to explain the phenomenon of decoupling of Sr–Nd isotopic composition. The quartz syenite and granite porphyry are altered by K-alteration in varying degrees and have high K2O and Rb contents and low Na2O, CaO, Sr, and Ba contents. Rock samples of both quartz syenite and granite porphyry have variable Rb/Sr ratios and initial 87Sr/86Sr values (even < 0.70) but contain quite homogeneous εNd(t) values (−12.8 to −14.8). Minerals from the rocks of moderate to intense K-alteration have very low initial 87Sr/86Sr values (even < −17), while those from the weakly altered rocks have 87Sr/86Sr(t) values of 0.7044 to 0.7084. The same phenomenon of the decoupling in Sr–Nd isotopic composition can be observed from several Mo deposits within the eastern Qinling–Dabie orogenic belt. This fact suggests similar hydrothermal features and a comparable origin for both the magmatic rocks and hydrothermal fluids in this belt. A comparison between porphyry Mo and porphyry Cu deposits shows that elements and the Rb–Sr isotope system have different behaviours during the K-alteration, implying distinct material sources and igneous rocks for porphyry Mo and porphyry Cu deposits, respectively. [ABSTRACT FROM AUTHOR]