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The cost‐efficient ZnMnO3 has attracted increasing attention as a prospective anode candidate for advanced lithium‐ion batteries (LIBs) owing to its resourceful abundance, large lithium storage capacity and low operating voltage. However, its practical application is still seriously limited by the modest cycling and rate performances. Herein, a facile design to scalable synthesize unique one‐dimensional (1D) mesoporous ZnMnO3 nanorods (ZMO‐NRs) composed of nanoscale particles (≈11 nm) is reported. The 1D mesoporous structure and nanoscale building blocks of the ZMO‐NRs effectively promote the transport of ions/electrons, accommodate severe volume changes, and expose more active sites for lithium storage. Benefiting from these appealing structural merits, the obtained ZMO‐NRs anode exhibits excellent rate behavior (≈454 mAh g−1 at 2 A g−1) and ultra‐long term cyclic performance (≈949.7 mAh g−1 even over 500 cycles at 0.5 A g−1) for efficient lithium storage. Additionally, the LiNi0.8Co0.1Mn0.1O2//ZMO‐NRs full cell presents a practical energy density (≈192.2 Wh kg−1) and impressive cyclability with approximately 91 % capacity retention over 110 cycles. This highlights that the ZMO‐NRs product is a highly promising high‐rate and stable electrode candidate towards advanced LIBs in electronic devices and sustainable energy storage applications. [ABSTRACT FROM AUTHOR]

In the work, a facile yet efficient self-sacrifice strategy is smartly developed to scalably fabricate hierarchical mesoporous bi-component-active ZnO/ZnFe2O4 (ZZFO) sub-microcubes (SMCs) by calcination of single-resource Prussian blue analogue of Zn3[Fe(CN)6]2 cubes. The hybrid ZZFO SCMs are homogeneously constructed from well-dispersed nanocrstalline ZnO and ZnFe2O4 (ZFO) subunites at the nanoscale. After selectively etching of ZnO nanodomains from the hybrid, porously assembled ZFO SMCs with integrate architecture are obtained accordingly. When evaluated as anodes for LIBs, both hybrid ZZFO and ZFO samples exhibit appealing electrochemical performance. However, the as-synthesized ZZFO SMCs demonstrate even better electrochemical Li-storage performance, including even larger initial discharge capacity and reversible capacity, higher rate behavior and better cycling performance, particularly at high rates, compared with the single ZFO, which should be attributed to its unique microstructure characteristics and striking synergistic effect between the bi-component-active, well-dispersed ZnO and ZFO nanophases. Of great significance, light is shed upon the insights into the correlation between the electrochemical Li-storage property and the structure/component of the hybrid ZZFO SMCs, thus, it is strongly envisioned that the elegant design concept of the hybrid holds great promise for the efficient synthesis of advanced yet low-cost anodes for next-generation rechargeable Li-ion batteries. [ABSTRACT FROM AUTHOR]

In this work, we put forward a facile yet efficient room-temperature synthetic methodology for the smart fabrication of mesoporous nanocrystalline ZnMn2O4 in macro-quality from the birnessite-type MnO2 phase. A plausible reduction/ion exchange/re-crystallization mechanism is tentatively proposed herein for the scalable synthesis of the spinel phase ZnMn2O4. When utilized as a high-performance anode for advanced Li-ion battery (LIB) application, the as-synthesized nanocrystalline ZnMn2O4 delivered an excellent discharge capacity of approximately 1288 mAh g−1 on the first cycle at a current density of 400 mA g−1, and exhibited an outstanding cycling durability, rate capability, and coulombic efficiency, benefiting from its mesoporous and nanoscale structure, which strongly highlighted its great potential in next-generation LIBs. Furthermore, the strategy developed here is very simple and of great importance for large-scale industrial production. [ABSTRACT FROM AUTHOR]

One-dimensional (1D) mesoporous ternary Co-Ni-Mn oxide nanowires (CNMO NWs) have been controllably fabricated via a facile yet scalable template-free strategy involving a green hydrothermal route coupled with the following calcination. The composition of the reaction solvent system, i.e., the volume ratio of the ethylene glycol and deionized water, plays a significant role in tuning the specific morphologies and microstructures of the final CNMO products. The as-derived lD CNMO NWs are constructed with numerous nanoparticle subunits with the size of ≈5-10 nm, and possess lots of interparticle mesopores ranged from 2 to 6 nm. The well-defined mesoporous CNMO NWs apparently have appealing structural advantages, such as fast and convenient electron and ion transport, sufficient redox electrochemical centers with multiple valences, and large electroactive surface area. As a result, the as-fabricated mesoporous CNMO NWs manifest exceptional pesudocapacitance and excellent cycling stability at high rates when evaluated as a striking low-cost electrode for next-generation electrochemical capacitors. [ABSTRACT FROM AUTHOR]

In this work, we rationally designed an efficient template-free synthetic strategy to fabricate hierarchical mesoporous hollow ZnMn2O4 sub-microspheres (HZSMs) constructed entirely from nanoparticle (NP) building blocks of size ≈15 nm. The well-known inside-out Ostwald ripening process was tentatively proposed to shed light on the formation mechanism of the mesoporous hollow nano-/microarchitecture. In favor of the intrinsic structural advantages, these resulting HZSMs exhibited superior electrochemical lithium-storage performance with high specific capacity, excellent cyclability, and good rate capability when evaluated as an anode material for advanced Li-ion batteries (LIBs). The excellent electrochemical performance should be reasonably ascribed to the porous and hollow structure of the unique HZSMs with nanoscale subunits, which reduced the diffusion length for Li+ ions, improved the kinetic process and enhanced the structural integrity with sufficient void space for tolerating the volume variation during the Li+ insertion/extraction. These results further revealed that the as-prepared mesoporous HZSMs would be a promising anode for high-performance LIBs. [ABSTRACT FROM AUTHOR]