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The present study has aimed to quantify the role of pore blocking and cake layer in a laboratory scale hollow fibre membrane module in submerged configuration. The membrane reactor (MBR) was fed with raw wastewater, only screened with a 2-mm sieve, collected from the Palermo WWTP. The MBR was characterised by an operating volume of 190 L and equipped with an aeration system located on the bottom of the reactor. The MBR operated for 65 days. The permeate was extracted by imposing a constant flux through the membrane (21 Lh-1m-2). The results confirm the importance of pore blocking control during start-up. In particular, it provides a rapid irreversible fouling that takes place at the beginning of the filtration process, before the deposition mechanism. Therefore, low suspended solids concentration in the initial phase causes a fast irreversible fouling. This circumstance creates the need for more frequent chemical cleaning after start-up without inoculum. Finally, the results underline that the cake has a mainly reversible feature. [ABSTRACT FROM AUTHOR]

• Biological and photocatalysis treatments in-series enabled high TOC removal (ca. 95%). • High photocatalysis performance was achieved because of the MBR pre-treatment. • The addition of K 2 S 2 O 8 reduced the necessity of cumulative impinging energy (60 E). • Membrane fouling mechanisms were the "cake layer deposition" and the "pore blocking". This study investigated the treatment of a shipboard slop containing commercial gasoline in a pilot plant scale consisting of a membrane biological reactor (MBR) and photocatalytic reactor (PCR) acting in series. The MBR contributed for approximately 70% to the overall slop purification. More precisely, the biological process was able to remove approximately 40%, on average, of the organic pollution in the slop. Nevertheless, the membrane was capable to retain a large amount of organic molecules within the system, amounting for a further 30% of the influent total organic content removal. However, this affected the membrane fouling, thus resulting in the increase of the pore blocking mechanism that accounted for approximately 20% to the total resistance to filtration (2.85∙1013 m−1), even if a significant restoration of the original membrane permeability was obtained after chemical cleanings. On the other hand, the biological treatment produced a clear solution for the photocatalytic system, thereby optimizing the light penetration and generation of highly oxidizing active oxygen species that enabled the degradation of bio-recalcitrant compounds. Indeed, low total organic carbon (TOC) values (<10 mg L−1) were achieved in the output of the photocatalytic reactor by means of only 60 Einstein (E) of cumulative impinging energy after the addition of K 2 S 2 O 8. Overall, coupling the two processes enabled very high TOC removal (ca. 95%). [ABSTRACT FROM AUTHOR]