51. Some Effects of Textural Properties of Carbon Fibers from Phenolic Resins on Double-Layer Capacitance in Aprotic Electrolyte
- Author
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Yu-Sheng Yang, Wen-Sheng Dong, Lang Liu, Jing-Ren Song, Gao-Ping Cao, Quangui Guo, and Chun-Ling Liu
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,Inorganic chemistry ,Double-layer capacitance ,Electrolyte ,Condensed Matter Physics ,Electrochemistry ,Capacitance ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,Electrical resistivity and conductivity ,Propylene carbonate ,Materials Chemistry ,medicine ,Current density ,Activated carbon ,medicine.drug - Abstract
Phenolic-based activated carbon fibers (ACFs) were prepared by catalytic activation using Zr(acac) 4 and ferrocene in CO 2 , respectively. The presence of the metal catalysts can promote the formation of mesopores and enhance the electric conductivity, particularly in the presence of Zr(acac) 4 . The electrochemical performance of the ACFs as electrodes of electric double-layer capacitors in 1 mol L -1 LiClO 4 /propylene carbonate (PC) was studied using galvanostatic charge/discharge and ac impedance techniques. The number of ions participating in the double layers per surface area unit increases with increasing the pore size above 11 A, and from 25 to 81 A it is nearly constant. The capacitance per unit mesopore surface area (8.08 μF cm -2 ) is higher than that per unit micropore surface area (4.29 μF m -2 ) at a current density of 50 mA g -1 . The organic ions could enter the larger pore easily and quickly. But if the pore size is larger than 26.5 A, the ac impedance increases due to the poor electric conductivity of the ACFs. The optimal pore size seems to be around 25 A in LiClO 4 /PC solution.
- Published
- 2008