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This paper investigates how nano-SiO 2 interacts with NBR to affect the tribological properties of water-lubricated NBR-based composites using the Rtec friction and wear tester and the molecular dynamics simulation method. The surface-modified nano-SiO 2 (SiO 2(TESPT)) particles were prepared by modifying the hydroxyl groups on the surface of nano-SiO 2 with Silicon 69 (TESPT), and cast copper alloy (ZCuSn10Zn2) was used as the counterface material in the friction test and wear test. The results showed that different interfacial interplay between nano-SiO 2 and NBR makes for distinct wear mechanisms of NBR-based composites. With weak interface bonding between nano-SiO 2 and NBR, NBR/SiO 2 can easily get worn as nano-SiO 2 particles detach from the matrix during the wear process, leaving pits and cracks on the worn surface. Instead, SiO 2(TESPT) has stronger interface bonding with the matrix, which can prevent the detachment of SiO 2(TESPT) , restrict the movement of molecular chains in NBR, and reduce the temperature peak of the friction pair. SiO 2(TESPT) exerts a dual influence on the tribological properties of NBR: while significantly improving the wear resistance of NBR, it can also notably increase the friction coefficient of the composite. • TESPT was used to modify the surface of nano-SiO 2 to enhance its interfacial bonding with NBR-based composites. • Strong interfacial bonding has dual effects on tribological properties of NBR-based composites. • Strong interfacial bonding can improve the wear property of NBR-based composites. • The study reveals the tribological mechanism of NBR enhanced by stronger interfacial interaction between nano-SiO 2 and NBR. [ABSTRACT FROM AUTHOR]

The friction and wear of water-lubricated bearings has always been an engineering problem that we need to solve urgently. To investigate the influence of SiO 2 particle size and dispersion on the friction and wear properties of nitrile rubber. The friction and wear performance of rubber compounds (SiO 2 (nano) /NBR, SiO 2 (micr) /NBR and SiO 2 (TESP) /NBR) was tested by American Rtec multifunctional friction and wear test machine under the conditions of water lubrication and constant temperature. The results showed that the particle size of SiO 2 has a great impact on its dispersion in nitrile rubber, and the surface modification of SiO 2 can significantly improve its dispersion. SiO 2 (TESPT) /NBR showed a good friction coefficient under low-speed and high-load conditions. The wear of SiO 2 (nano) /NBR and SiO 2 (micr) /NBR, which was mainly the fatigue wear, was relatively serious. In contrast, the modified SiO 2 had a smaller particle size, better dispersion and stronger interfacial bonding with the nitrile rubber matrix. This significantly reduced the wear of SiO 2 (TESPT) /NBR, which was mainly the abrasive wear, and improved its wear resistance. • TESPT was used to modify the hydroxyl groups on the surface of nano-silica. • The escape and disintegration of SiO 2 (micr) and SiO 2 (nano) agglomerates during the wear process were characterized. • The effect of particle size and dispersion of SiO 2 on tribological properties of nitrile rubber was revealed. [ABSTRACT FROM AUTHOR]

Nitrile Butadiene Rubber (NBR) is widely used in ship water-lubricated stern tube bearings. Sediments in the water would cause a serious effect on friction and wear properties of the water-lubricated bearings. In this study, the tribological performance of water-lubricated rubber bearings under different sediment particle sizes and sand types were analyzed. Two sediment sand types are involved in the research, (i) SiO 2 particles with sizes of 0–25 μm, 48–60 μm, 75–90 μm and 150–200 μm, respectively; (ii) Sediment particles collected from the Yangtze River with sizes of 48–60 μm, 75–90 μm and 120–150 μm, respectively. The friction coefficients and wear volumes as well as surface morphology were measured. It was found that NBR worn by SiO 2 particles was worse than that by the sediment within a certain particle size range. On the other hand, the particle sizes exhibited significant effects on the tribological properties. As the particle size increased, the largest wear volume of NBR occurred at particle size of 75–90 μm, While the friction coefficient grew firstly and then fell down, and reached its maximum at particle size of 48–60 μm. Additionally, the friction coefficient demonstrated a negative correlation with sliding speed regardless of the sediment type and particle size. The particle sizes were prevented from flowing into the friction pair as applied load increased. In conclusion, this research offers a great insight for designing water-lubricated bearings. [ABSTRACT FROM AUTHOR]