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In this study, Mg-13.2Gd-4.3Ni alloys containing continuous bulk-shaped long-period stacking ordered (LPSO), lamellar LPSO, and a small amount of eutectic phase were prepared, and the evolution of microstructure at different extrusion temperatures and its influence on mechanical and degradation properties as well as corrosion mechanism were investigated. Preheating before extrusion can effectively promote the precipitation of lamellar LPSO in matrix. EX400 with higher volume fraction of non-DRXed grains exhibited higher strength, which was mainly due to strong texture, high dislocation density, and high volume fraction of lamellar LPSO. The EX420 with higher volume fraction of DRXed grains showed higher degradation rate, which was mainly due to the higher density of grain boundary. The EX400 exhibited excellent comprehensive properties with tensile yield strength (TYS) of 334 MPa, ultimate tensile strength (UTS) of 484 MPa and elongation (EL) of 7.4%, ultimate compressive strength (UCS) of 638 MPa and compressive yield strength (CYS) of 443 MPa, degradation rate of 86.1 mg/cm2/h at 93 °C in 3 wt.% KCl solution. [ABSTRACT FROM AUTHOR]

The fabrication of high-performance cement-based materials has benefited greatly from the extensive use of graphene and its derivatives. This paper studies the effects of graphene sulfonate nanosheets (GSNSs) on sacrificial cement paste and mortar (the tested materials) and other siliceous sacrificial materials, especially their ablation behaviors and mechanical properties. Decomposition temperatures and differential scanning calorimetry were used to examine how different contents of GSNSs determines the corresponding decomposition enthalpy of the tested materials and their ablation behaviors. Molecular dynamics was also used to clarify the mechanism how the GSNSs work in the CSH (calcium silicate hydrated)/GSNSs composite to increase the resistance to high temperature. The experimental results show that: (1) the contents of GSNSs at 0.03 wt.%, 0.1 wt.%, and 0.3 wt.% brought an increase of 10.97%, 22.21%, and 17.56%, respectively, in the flexural strength of siliceous sacrificial mortar, and an increase of 1.92%, 9.16%, and 6.70% in its compressive strength; (2) the porosity of siliceous sacrificial mortar was decreased by 5.04%, 9.91%, and 7.13%, respectively, and the threshold pore diameter of siliceous sacrificial mortar was decreased by 13.06%, 35.39%, and 24.02%, when the contents of GSNSs were 0.03 wt.%, 0.1 wt.%, and 0.3 wt.%, respectively; (3) a decline of 11.16%, 28.50%, and 61.01% was found in the ablation velocity of siliceous sacrificial mortar, when the contents of GSNSs were 0.03 wt.%, 0.1 wt.%, and 0.3 wt.%, respectively; (4) when considering the ablation velocities and mechanical properties of siliceous sacrificial materials, 0.1 wt.% GSNSs was considered to be the optimal amount; (5) the GSNSs contribute to the reinforced effect of GSNSs on CSH gel through the grab of dissociated calcium and water molecules, and the chemical reaction with silicate tetrahedron to produce S–O–Si bonds. These results are expected to promoting the development of new kinds of siliceous sacrificial materials that contain GSNSs. [ABSTRACT FROM AUTHOR]

Ultra-high-performance concrete (UHPC) has been used as an advanced construction material in civil engineering because of its excellent mechanical properties and durability. However, with the depletion of the raw material (river sand) used for preparing UHPC, it is imperative to find a replacement material. Recycled sand is an alternative raw material for preparing UHPC, but it degrades the performance. In this study, we investigated the use of graphene oxide (GO) as an additive for enhancing the properties of UHPC prepared from recycled sand. The primary objective was to investigate the effects of GO on the mechanical properties and durability of the UHPC at different concentrations. Additionally, the impact of the GO additive on the microstructure of the UHPC prepared from recycled sand was analysed at different mixing concentrations. The addition of GO resulted in the following: (1) The porosity of the UHPC prepared from recycled sand was reduced by 4.45–11.35%; (2) the compressive strength, flexural strength, splitting tensile strength, and elastic modulus of the UHPC prepared from recycled sand were enhanced by 8.24–16.83%, 11.26–26.62%, 15.63–29.54%, and 5.84–12.25%, respectively; (3) the resistance of the UHPC to penetration of chloride ions increased, and the freeze–thaw resistance improved; (4) the optimum mixing concentration of GO in the UHPC was determined to be 0.05 wt.%, according to a comprehensive analysis of its effects on the microstructure, mechanical properties, and durability of the UHPC. The findings of this study provide important guidance for the utilisation of recycled sand resources. [ABSTRACT FROM AUTHOR]

Ultra-high-performance concrete (UHPC) has received increasing attention in recent years due to its remarkable ductility, durability, and mechanical properties. However, the manufacture of UHPC can cause serious environmental issues. This work addresses the feasibility of using aeolian sand to produce UHPC, and the mix design, environmental impact, and mechanical characterization of UHPC are investigated. We designed the mix proportions of the UHPC according to the modified Andreasen and Andersen particle packing model. We studied the workability, microstructure, porosity, mechanical performance, and environmental impact of UHPC with three different water/binder ratios. The following findings were noted: (1) the compressive strength, flexural strength, and Young's modulus of the designed UHPC samples were in the ranges of 163.9–207.0 MPa, 18.0–32.2 MPa, and 49.3–58.9 GPa, respectively; (2) the compressive strength, flexural strength, and Young's modulus of the UHPC increased with a decrease in water/binder ratio and an increase in the steel fibre content; (3) the compressive strength–Young's modulus correlation of the UHPC could be described by an exponential formula; (4) the environmental impact of UHPC can be improved by decreasing its water/binder ratio. These findings suggest that it is possible to use aeolian sand to manufacture UHPC, and this study promotes the application of aeolian sand for this purpose. [ABSTRACT FROM AUTHOR]

• UHPC with high elastic modulus was design by MAA particle packing model. • Workability, microstructure, and mechanical strength of HEMUHPC were studied. • Elastic modulus of HEMUHPC ranged from 40.50 GPa to 47.13 GPa. • Relationship between elastic modulus and compressive strength was a power function. • Optimal content of alumina micro-powder in HEMUHPC was 10%. Elastic modulus is an important parameter in engineering structural design for evaluating the stiffness of concrete members. Ultra-high-performance concrete (UHPC) has excellent mechanical properties and durability, but the relatively low elastic modulus prohibits the widespread use of the UHPC. In this study, high elastic modulus UHPC (HEMUHPC) was designed according to Modified Andreasen and Andersen particle packing model proposed by Funk and Dinger. Effects of alumina micro-powder (the content of alumina is higher than 99%, and the particle size is lower than 100 μ m) on the workability, microstructure, and mechanical properties of HEMUHPC were systematically investigated. The reason for the improvement of elastic modulus of HEMUHPC was revealed by nano indentation test. It was found that, 1) the porosity and threshold pore diameter of HEMUHPC were reduced because of the addition of alumina micro-powder; 2) the flexural strength, compressive strength, and elastic modulus of HEMUHPC were increased by 3.54–11.23%, 8.89–22.83%, and 6.19–16.37%, respectively, due to the addition of alumina micro-powder; 3) the optimal content of alumina micro-powder was 10%, considering its effects on the workability, mechanical properties, and microstructure of HEMUHPC; 4) Nano indentation experiments showed that the elastic modulus of the alumina micro-powder was 90–135 GPa, which is much higher than the elastic modulus of hydration products of HEMUHPC, and thus the elastic modulus of the HEMUHPC matrix could be improved, due to the addition of alumina micro-powder. [ABSTRACT FROM AUTHOR]

• Producing cement-based sacrificial materials with strontium ferrite is feasible. • Adding strontium ferrite decreases the mechanical properties of cement mortar. • Adding strontium ferrite reduces the drying shrinkage of cement mortar. • Strontium ferrite does not participate in the hydration reaction of cement mortar. • A model between the damage of cement mortar and the temperature is proposed. The safety of nuclear power plant can be improved via core catcher, and cement-based sacrificial materials are widely used in most core catchers because of their simple construction process and the low manufacturing cost. This paper carried out a preliminary investigation to explore the feasibility of using strontium ferrite to prepare cement-based sacrificial materials. The effects of strontium ferrite on the room temperature and high temperature properties of cement mortar were systematically studied in the work. In addition, the damage evolution of cement mortar containing strontium ferrite subjected to elevated temperatures was also identified according to the damage mechanics theory. It was found that, (1) the addition of strontium ferrite led to the deterioration of the mechanical properties, microstructure and pore structure of cement mortar; (2) it was feasible to prepare cement-based sacrificial materials containing strontium ferrite that met the requirements on basic properties like mechanical properties, free water content, volume stability, and the high temperature integrity by controlling the content of strontium ferrite; (3) the correlation between the internal damage of cement mortar and the temperature could be described by Weibull Distribution Model, which provided a basis for the identification and evaluation of serious nuclear power accidents. [ABSTRACT FROM AUTHOR]