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This research is devoted to the microstructure evolution and deformation behavior of the Al-1.2Mg-0.7Si-1.0Cu-0.1Sc-0.2Zr alloy during the isothermal multidirectional forging (MDF) in a large cumulative strain and temperature range. The structure investigation of the studied alloy revealed several phases precipitated during solidification, among which θ(Al2Cu), Q(Al5Cu2Mg8Si6), Mg2Si, Sc-bearing W(AlScCu) and V(AlSi2Sc2) phases were observed. The MDF at 150–350 °C and a maximum cumulative strain of 14.4 significantly refined grain structure providing a mean grain size of 1.2–2.1 µm. The L12 structured Al3(Sc,Zr) dispersoids with a mean size of 10 ± 1 nm were formed during two-step homogenization annealing. Due to Zener pinning of the nanoscale dispersoids and fine-grained structure, the alloy exhibited near-superplastic behavior in a temperature range of 460–500 °C and strain rate range of 2 × 10−3–1 × 10−2 s−1 with the maximum elongation to failure of ~300%. After a strengthening heat treatment, the forged alloy exhibited the yield strength of 326 ± 5 MPa, ultimate tensile strength of 366 ± 5 MPa, and elongation of 10 ± 3%. The hot deformation behavior was described using the Arrhenius type model. The developed model demonstrated high predictability accuracy with a maximum average absolute relative error of 6.6%. [ABSTRACT FROM AUTHOR]

In the present study, AA7075 and AA2024 aluminum alloys were reinforced with ZrC, and the particles of WC were joined using the friction stir welding (FSW) method. The microstructural and mechanical properties of the welds were investigated using SEM, EDS, and tensile tests. The FSW process resulted in high-quality welds with fine grain structure; the stirred zone has 666% smaller grain size than AA7075 and AA2024 aluminum alloys. The tensile test showed strong and ductile welds. The fracture test showed ductile and less brittle composite joints of AA2024 and AA7075 alloys reinforced with WC and ZrC. The processing parameters in the FSW process significantly affect tensile strength (UTS); therefore, the improvement of UTS with tool speed is much greater than with welding speed. Increasing the tool speed from 400 to 560 rpm increased UTS by 7.1%, and from 560 to 700 rpm by 5.4%. The tensile test results showed that the welds exhibited considerable strength and ductility. Fracture analysis showed that the composite joints made of different AA2024 and AA7075 alloys and reinforced with WC and ZrC were ductile and less brittle. This study showed that FSW can efficiently fuse different aluminum alloys reinforced with ceramic particles. [ABSTRACT FROM AUTHOR]

The ceramic particle reinforcement process is one of the most utilized techniques to enhance the metal surface. The current investigation uses vanadium and niobium carbides to reinforce the AA6061 alloy using the friction stir process (FSP). The mechanical properties are evaluated using ultrasound and conventional compressive tests; furthermore, the microstructure and physical properties are carried out to show the effect of single and hybrid additives of ceramic particles on the surface composites of aluminum alloy. Scanning electron microscopy (SEM) is utilized to examine the presence and distribution of the reinforcement VC and NbC particles inside the composite matrix. The microstructure examination revealed a good dispersion and homogenized distribution of the reinforcement particles. The results indicated that reinforcement particles significantly enhanced the mechanical and physical properties. The VC and NbC particles play an important role in improving the surface hardening behavior and grain refinement by restricting grain growth during the dynamic recrystallization process in the FSP action. The hybrid composited AA6061/NbC + VC recorded an increase in the compressive stress, yield stress, and hardness of 25%, 20%, and 50%, respectively, relative to the base metal, in addition to a 55% decrease in the coefficient of the thermal expansion (CTE) was reported. Moreover, the hybrid composite AA6061/NbC + VC significantly affected the corrosion rate with a reduction of 45%. [ABSTRACT FROM AUTHOR]

Due to the engine's start/stop system and a sudden increase in speed or load, the development of alloys suitable for engine bearings requires excellent tribological properties and high mechanical properties. Including additional elements in the Al-rich matrix of these anti-friction alloys should strengthen their tribological properties. The novelty of this work is in constructing a suitable artificial neural network (ANN) architecture for highly accurate modeling and prediction of the mechanical properties of the bearing aluminum-based alloys and thus optimizing the chemical composition for high mechanical properties. In addition, the study points out the impact of soft and more solid phases on the mechanical properties of these alloys. For this purpose, a huge number of alloys (198 alloys) with different chemical compositions combined from Sn, Pb, Cu, Mg, Zn, Si, Ni, Bi, Ti, Mn, Fe, and Al) were cast, annealed, and tested for determining their mechanical properties. The annealed sample microstructure analysis revealed the formation of soft structural inclusions (Sn-rich, Sn-Pb, and Pb-Sn phases) and solid phase inclusions (strengthened phase, Al2Cu). The mechanical properties of ultimate tensile strength (σu), Brinell hardness (HB), and elongation to failure (δ) were used as control responses for constructing the ANN network. The constructed network was optimized by attempting different network architecture designs to reach minimal errors. Besides the excellent tribological characteristics of the designed set of alloys, soft inclusions based on Sn and Pb and solid-phase Cu inclusions fulfilled the necessary level of mechanical properties for anti-friction alloys; the maximum mechanical properties reached were: σu = 197 ± 7 MPa, HB = 77 ± 4, and δ = 20.3 ± 1.0%. The optimal ANN architecture with the lowest errors (correlation coefficient (R) = 0.94, root mean square error (RMSE) = 3.5, and average actual relative error (AARE) = 1.0%) had two hidden layers with 20 neurons. The model was validated by additional experiments, and the characteristics of the new alloys were accurately predicted with a low level of errors: R ≥ 0.97, RMSE = 1–2.65, and AARE ˂ 10%. [ABSTRACT FROM AUTHOR]

The paper studies the influence of 0.5–1.8 wt.% Ni alloying on the superplasticity, microstructural evolution, and dynamic grain growth effect in a temperature range of 625–775 °C and room temperature mechanical properties of two-phase Ti-Al-Mo-V alloys. Due to a decrease in β transus and an enhancement in the alloy diffusivity, an increase in Ni content significantly improved superplasticity. The Ni-modified alloys exhibited 1.5–3-fold lower flow stress, a 2.5–3-fold greater elongation to failure, and 1.4–1.7-fold higher strain rate sensitivity m coefficient compared to the Ni-free alloy. An intermetallic Ti2Ni compound precipitated in the 1.8 wt.% Ni-modified alloy during low-temperature deformation at 700 °C and decreased superplastic properties. The Ti-4Al-3Mo-1V-0.1B alloy with 0.9 wt.% Ni exhibited a good combination of the superplastic behavior and room-temperature mechanical properties: an elongation to failure of 500–900% at a low-temperature range of 625–775 °C and constant strain rate of 1 × 10−3 s−1 and a yield strength of 885 MPa and ultimate tensile strength of 1020 MPa after pre-straining for 100% in a superplastic regime and strengthening heat treatment. [ABSTRACT FROM AUTHOR]

The superplasticity of Ti-based alloys is improved due to grain refinement, an increase in grain size stability, and an increase in the β -phase fraction up to ∼0.5. Alloying with β -stabilizers reduces the β -transus temperature and increases the β -phase fraction at low forming temperatures, thus improving the superplasticity and lowering its temperature. Both grain growth and superplastic deformation mechanisms are diffusion-controlled phenomena, and, therefore, the diffusivity of the alloying elements should have a significant effect on superplasticity. This work deals with the influence of the high-diffusive elements Fe, Co, and Ni on the grain structure and superplasticity of titanium alloys. For this purpose, the Ti-Al-Mo-V alloy, and alloys with proportional replacement of low-diffusive Mo by Fe, Co, or Ni, exhibiting an interstitial diffusion mechanism, were studied. The alloying elements content was selected to ensure the same β -phase fraction at a deformation temperature of ∼875 °C. The microstructure evolution after thermomechanical processing, annealing, and superplastic deformation, as well as post-deformation room-temperature mechanical properties of the studied alloys, were compared. The actual phase ratio was reconstructed by comparing scanning electron microscopy images in backscattered electrons and electron backscatter diffraction data for the same fragments. It was found that Mo replacement for highly diffusive elements accelerated dynamic grain growth during superplastic deformation at an elevated temperature of 875 °C but improved superplasticity at a lower temperature of 775 °C. The results confirmed that alloying with high-diffusive elements is a promising strategy for the design of low-temperature superplastic forming alloys. [Display omitted] • Ti-Al-V-Mo and alloys with proportional replacement of Mo by Fe/Co/Ni were studied. • High diffusive elements accelerated dynamic grain growth for the Mo-free alloys. • Fe/Co promote excellent superplasticity with a stable flow at low temperatures. • Fe/Co/Ni significantly accelerate recrystallization/globularization and GBS. • Ti 2 Ni precipitates significantly influence the grain structure formation. [ABSTRACT FROM AUTHOR]

The mechanical properties and microstructure of as-cast and homogenized AA7075 were investigated. This alloy was modified by adding transition elements 0.3%Sc + 0.5%Zr, 1%Ti + 0.2%B, and 1%Fe + 1%Ni for use in additive manufacturing applications. After adding Ti + B and Sc + Zr, the structure became uniform and finer with the formation of the Al3(Sc, Zr) and TiB2 phases. Coarse structures were obtained with the formation of an extremely unfavorable morphology, close to a needle-like structure when Fe + Ni was added. The mechanical properties of the modified alloys were increased compared to those of the standard alloy, where the best ultimate tensile strength (UTS) and yield strength (YS) were obtained in the AA7075-TiB alloy compared to the standard alloy in as-cast and homogenized conditions, and the highest hardness value was provided by Fe + Ni additives. The effect of the laser melting process on the microstructure and mechanical properties was investigated. Single laser melts were performed on these alloys using 330 V and a scanning speed of 8 mm/s. During the laser melting, the liquation of the alloying elements occurred due to non-equilibrium solidification. A change in the microstructures was observed within the melt zone and heat-affected zone (HAZ). The hardness of the laser-melted zone (LMZ) after adding the modification elements was increased in comparison with that of the standard alloy. Corrosion testing was performed using a solution of 100 mL distilled water, 3.1 g NaCl, and 1 mL HCl over 5, 10, and 30 min and 1 and 2 h. The corrosion resistance of the alloy modified with FeNi was low because of the non-uniform elemental distribution along the LMZ, but in the case of modification with ScZr and TiB, the corrosion resistance was better compared to that of the standard alloy. [ABSTRACT FROM AUTHOR]

The effect of isothermal multidirectional forging (IMF) on the microstructure evolution of a conventional Al–Mg-based alloy was studied in the strain range of 1.5 to 6.0, and in the temperature range of 200 to 500 °C. A mean grain size in the near-surface layer decreased with increasing cumulative strain after IMF at 400 °C and 500 °C; the grain structure was inhomogeneous, and consisted of coarse and fine recrystallized grains. There was no evidence of recrystallization when the micro-shear bands were observed after IMF at 200 and 300 °C. Thermomechanical treatment, including IMF followed by 50% cold rolling and annealing at 450 °C for 30 min, produced a homogeneous equiaxed grain structure with a mean grain size of 5 µm. As a result, the fine-grained sheets exhibited a yield strength and an elongation to failure 30% higher than that of the sheets processed with simple thermomechanical treatment. The IMF technique can be successfully used to produce fine-grained materials with improved mechanical properties. [ABSTRACT FROM AUTHOR]

Novel titanium-based alloys are required to increase the efficiency of superplastic forming technology and decrease energy consumption. For this purpose, the superplastic deformation behavior, strain-induced microstructure evolution in a temperature range of 625–775 °C, and post-deformation mechanical properties of Ti–4Al–1V–1Fe–1Ni-0.1B- x Mo alloys (x = 1, 2.5, or 5 wt%) were investigated. The studied alloys demonstrated a stable flow with a high strain rate sensitivity coefficient m of 0.50–0.65 and an elongation-to-failure δ of 700–1000% at temperatures of 700–775 °C. Molybdenum insignificantly influenced superplastic deformation behavior at high temperatures due to a high fraction of the β phase of 22–62%. The Mo effect was significant at a low deformation temperature of 625 °C. At this temperature, an increase in Mo content from 1 to 5% provided the β -phase fraction above the critical value of ∼20% and increased the m- value from 0.4 to 0.5 and δ from ∼200 to ∼700%. Increasing Mo from 1 to 5% enhanced the post-deformation yield strength at room temperature by 180 MPa, the ultimate tensile strength by 170 MPa, and the ductility by 2.5%. Consequently, alloying Ti–4Al–1V–1Fe–1Ni-0.1B with 5% Mo provided an excellent combination of superplasticity at a low temperature of 625 °C and post-forming tensile mechanical properties. • Increase in Mo content from 1 to 5 wt% improved low temperature superplasticity. • 5Mo and 20% of the β phase are required for low-temperature superplasticity at 625 °C. • Alloys exhibit a stable fine-grained structure during deformation at 625–700 °C. • Increase in Mo content improved the post-forming mechanical properties. • 5 wt%Mo provided a good combination of the superplastic and mechanical properties. [ABSTRACT FROM AUTHOR]

Decreasing the superplastic forming temperature of Ti alloys is currently an important issue. This study investigated the impact of modifying the Ti–Al–Mo–V alloy with different percentages of Fe (0–2 wt.%) on the microstructure, superplasticity and post-forming mechanical properties. The results revealed that during superplastic deformation, the increase in Fe content facilitated the recrystallisation and fragmentation of the phases and grain boundary sliding due to the accelerating diffusivity by Fe. In contrast, the presence of Fe increased the susceptibility to grain growth. A high strain rate sensitivity coefficient m (0.45–0.5) and maximum elongation to failure (500–1000%) were achieved for these alloys at a constant strain rate of 1 × 10−3 s−1 and in a low temperature range (625–775 °C). Alloying the investigated alloy with Fe increased the post-forming room-temperature tensile strength by 90–220 MPa and decreased the ductility by 1–2%. Alloying with 0.5% Fe provided a good combination of the superplastic and room-temperature mechanical properties for the studied alloys. • 0.5-2 wt%Fe addition substantially improved the superplasticity of Ti-based alloy. • Fe facilitated the recrystallisation/fragmentation. • Alloying with Fe accelerated grain growth in Ti-based alloy. • Fe alloying increased the post-forming room-temperature tensile strength. • 0.5%Fe provided a good combination of the superplastic and mechanical properties. [ABSTRACT FROM AUTHOR]