29 results on '"Yijin Zhang"'
Search Results
2. Enhancing the absorption of a thin germanium slab with periodical patterning
- Author
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Aimin Wu, Ziyang Han, Wenfei Li, Yi Jin, Xiyuan Cao, and Yijin Zhang
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010302 applied physics ,Coupling ,Materials science ,business.industry ,Physics::Optics ,chemistry.chemical_element ,Germanium ,Photodetection ,Condensed Matter Physics ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,Responsivity ,Planar ,chemistry ,0103 physical sciences ,Slab ,Optoelectronics ,Electrical and Electronic Engineering ,business ,Absorption (electromagnetic radiation) ,Photonic crystal - Abstract
We propose a germanium (Ge) photonic crystal thin slab to achieve perfect absorption efficiency in telecom band. The maximum absorption is increased 14-fold compared to a planar cell with the same thickness at normal incidence. The absorption enhancement is attributed to the critical coupling with guided resonances by introducing an airhole photonic crystal on the thin slab. This novel design constitutes an important step towards high responsivity and high-speed photodetection with strong energy harvesting.
- Published
- 2019
3. Perfect near-infrared absorption of graphene with hybrid dielectric nanostructures
- Author
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Aimin Wu, Xiyuan Cao, Yijin Zhang, Zhongying Xue, Yi Jin, Ziyang Han, Wenfei Li, and Guanyu Liu
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010302 applied physics ,Materials science ,Silicon photonics ,Silicon ,business.industry ,Graphene ,chemistry.chemical_element ,Photodetection ,Dielectric ,Condensed Matter Physics ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials ,law.invention ,Responsivity ,chemistry ,law ,0103 physical sciences ,Optoelectronics ,Electrical and Electronic Engineering ,business ,Silicon oxide ,Absorption (electromagnetic radiation) - Abstract
Near-infrared perfect wave harvesting of graphene is theoretically and numerically obtained in a hybrid dielectric configuration without assistance of a reflecting mirror. The absorption is increased 43-fold compared to a suspended graphene layer at normal incidence. The mechanism of perfect absorption is based on critical coupling with a guided resonance introduced by a silicon bar array and Fabry–Perot (FP) effect of a silicon oxide layer. This lossless design is expected to find applications to allow the active area with effective generation and fast transport of photocarriers, paving a new way for on-chip small-footprint ultrahigh responsivity and ultrahigh-speed photodetection in silicon photonics.
- Published
- 2019
4. Design optimization for A Cabin-Skeleton Coupling Structure of Blended-wing-body Underwater Glider
- Author
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Peng Wang, Huachao Dong, Xinkai Yu, and Yijin Zhang
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Coupling ,Wing ,Materials science ,business.industry ,Underwater glider ,Structure (category theory) ,Stiffness ,Structural engineering ,Stability (probability) ,Finite element method ,medicine ,medicine.symptom ,business ,Parametric statistics - Abstract
According to the special shape of a blended-wing-body underwater glider (BWBUG), the cabin-skeleton coupling structure including a pressure cabin structure and a skeleton structure is designed in its internal space, which plays a role of support and pressure resistance. Based on fixed BWB shape parameters, firstly, the pressure cabin structure and skeleton structure were parametrically modeled. Next, finite element analysis (FEA) was conducted for the coupling structure in the hanging before entering the water and deepwater pressure conditions respectively, mainly analyzing the strength, stiffness, and stability. Then, the maximum buoyancy-weight ratio is used as the target, besides, the specific indicators for the obtained strength, stiffness, and stability are used as constraints. Finally, a surrogate-based constrained global optimization algorithm (SCGOSR) is adopted to optimize the coupling structure. After the optimization, the buoyancy-weight ratio is increased by about 43%, and a satisfactory cabin-skeleton coupling structure is obtained.
- Published
- 2020
5. Potential Profile of Stabilized Field-Induced Lateral p–n Junction in Transition-Metal Dichalcogenides
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Ryuji Suzuki, Yijin Zhang, and Yoshihiro Iwasa
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Materials science ,Electrical junction ,General Physics and Astronomy ,Nanotechnology ,02 engineering and technology ,Electroluminescence ,010402 general chemistry ,01 natural sciences ,law.invention ,law ,Condensed Matter::Superconductivity ,General Materials Science ,Diode ,business.industry ,Doping ,General Engineering ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Organic semiconductor ,Semiconductor ,Optoelectronics ,0210 nano-technology ,business ,p–n junction ,Light-emitting diode - Abstract
Electric field-induced p-n junctions are often used to realize peculiar functionalities in various materials. This method can be applied not only to conventional semiconductors but also to carbon nanotubes, graphene, and organic semiconductors to which the conventional chemical doping method is difficult to apply. Transition-metal dichalcogenides (TMDs) are one of such materials where the field-induced p-n junctions play crucial roles in realizing solar cell and light-emitting diode operations as well as circularly polarized electroluminescence. Although the field-induced p-n junction is a well-established technique, many of its physical properties are left to be understood because their doping mechanism is distinct from that of conventional p-n junctions. Here we report a direct electrical measurement of the potential variation along the field-induced p-n junction using multiple pairs of voltage probes. We detected the position of the junction, estimated the built-in potential, and monitored the effect of the bias voltage. We found that the built-in potential becomes negative under a forward bias voltage range where field-induced TMD p-n junctions have been operated as light-emitting diodes. This feature well reproduced the circularly polarized electroluminescence from the WSe
- Published
- 2017
6. Extended Polymorphism of Two-Dimensional Material
- Author
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Norio Kobayashi, Yijin Zhang, Terukazu Nishizaki, Yasuhiko Imai, Yoshihiro Iwasa, Masaki Nakano, Shigeru Kimura, Masaro Yoshida, Jianting Ye, Akihiko Fujiwara, and Device Physics of Complex Materials
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Diffraction ,Phase transition ,two-dimensional material ,TRANSITION-METAL DICHALCOGENIDES ,Materials science ,4HB-TAS2 ,Tantalum ,chemistry.chemical_element ,charge-density-wave (CDW) ,Bioengineering ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,01 natural sciences ,Transition metal ,electric double layer transistor (EDLT) ,1T-TAS2 ,General Materials Science ,Polymorphism ,MOS2 ,microbeam X-ray diffraction ,2H-NBSE2 ,Superconductivity ,Mechanical Engineering ,SUPERCONDUCTIVITY ,General Chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Crystallography ,Polymorphism (materials science) ,chemistry ,Chemical physics ,PHASE-TRANSITION ,0210 nano-technology ,Single crystal ,POLYTYPISM - Abstract
When controlling electronic properties of bulk materials, we usually assume that the basic crystal structure is fixed. However, in two-dimensional (2D) materials, atomic structure or to functionalize their properties. Various polymorphs can exist in transition metal dichalcogenides (TMDCs) from which 2D materials are generated, and polymorphism has drastic on the electronic states. Here we report the discovery of an polymorph is attracting growing interest as a controlling parameter unprecedented polymorph of a TMDC 2D material. By mechanical exfoliation, we made thin flakes from a single crystal of 2Ha-type tantalum disulfide (TaS2), a metallic TMDC with a charge-density-wave (CDW) phase. Microbeam X-ray diffraction measurements and electrical transport measurements indicate that thin flakes possess a polymorph different from any one known in TaS2 bulk crystals. Moreover, the flakes with the unique polymorph displayed the dramatically enhanced CDW ordering temperature. The present results suggest the potential existence of diverse structural and electronic phases accessible only in 2D materials.
- Published
- 2017
7. Near Infrared Absorption Enhancement of Graphene for High-Responsivity Photodetection
- Author
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Yijin Zhang, Yi Jin, Xiyuan Cao, and Aimin Wu
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Materials science ,Silicon ,Graphene ,business.industry ,chemistry.chemical_element ,Photodetector ,02 engineering and technology ,Photodetection ,021001 nanoscience & nanotechnology ,01 natural sciences ,law.invention ,010309 optics ,Responsivity ,Interference (communication) ,chemistry ,law ,0103 physical sciences ,Optoelectronics ,Photonics ,0210 nano-technology ,Absorption (electromagnetic radiation) ,business - Abstract
Near-infrared strong light harvesting of graphene is obtained based on multipole resonance interference of silicon nanodisks. The ultrathin design allows the active area with effective generation of photo carriers, paving a new way for small footprint high-speed and high-responsivity photon detection.
- Published
- 2019
8. Enhanced intrinsic photovoltaic effect in tungsten disulfide nanotubes
- Author
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Yijin Zhang, Jurgen H. Smet, Reshef Tenne, Yoshihiro Iwasa, Ryo Suzuki, Feng Qin, Toshiya Ideue, Masaru Onga, and Alla Zak
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Photocurrent ,Nanotube ,Multidisciplinary ,Materials science ,business.industry ,Tungsten disulfide ,02 engineering and technology ,Photovoltaic effect ,Anomalous photovoltaic effect ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,7. Clean energy ,0104 chemical sciences ,Nanomaterials ,chemistry.chemical_compound ,Semiconductor ,chemistry ,Monolayer ,Optoelectronics ,0210 nano-technology ,business - Abstract
The photovoltaic effect in traditional p–n junctions—where a p-type material (with an excess of holes) abuts an n-type material (with an excess of electrons)—involves the light-induced creation of electron–hole pairs and their subsequent separation, generating a current. This photovoltaic effect is particularly important for environmentally benign energy harvesting, and its efficiency has been increased dramatically, almost reaching the theoretical limit1. Further progress is anticipated by making use of the bulk photovoltaic effect (BPVE)2, which does not require a junction and occurs only in crystals with broken inversion symmetry3. However, the practical implementation of the BPVE is hampered by its low efficiency in existing materials4–10. Semiconductors with reduced dimensionality2 or a smaller bandgap4,5 have been suggested to be more efficient. Transition-metal dichalcogenides (TMDs) are exemplary small-bandgap, two-dimensional semiconductors11,12 in which various effects have been observed by breaking the inversion symmetry inherent in their bulk crystals13–15, but the BPVE has not been investigated. Here we report the discovery of the BPVE in devices based on tungsten disulfide, a member of the TMD family. We find that systematically reducing the crystal symmetry beyond mere broken inversion symmetry—moving from a two-dimensional monolayer to a nanotube with polar properties—greatly enhances the BPVE. The photocurrent density thus generated is orders of magnitude larger than that of other BPVE materials. Our findings highlight not only the potential of TMD-based nanomaterials, but also more generally the importance of crystal symmetry reduction in enhancing the efficiency of converting solar to electric power. A bulk photovoltaic effect is observed in devices based on tungsten disulfide, and is enhanced if the devices take the form of polar nanotubes, showing the importance of reducing crystal symmetry to a polar structure in achieving higher efficiencies.
- Published
- 2019
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9. Hierarchical porous structures in cellulose: NMR relaxometry approach
- Author
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Yijin Zhang, Fei Lu, Ruigang Liu, Hongliang Kang, Pingping Li, Yong Huang, Weiwei Li, Junfeng Xiang, and Chao Zhang
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Relaxometry ,Materials science ,Polymers and Plastics ,Organic Chemistry ,technology, industry, and agriculture ,02 engineering and technology ,equipment and supplies ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Dimethylacetamide ,0104 chemical sciences ,Amorphous solid ,Solvent ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Materials Chemistry ,Organic chemistry ,Sample preparation ,Cellulose ,0210 nano-technology ,Porosity ,Dissolution - Abstract
Hierarchical porous structures in cellulose materials are important for the dissolution, properties and applications of cellulose materials. Methods for characterizing the hierarchical porous structures in cellulose materials without changing its original state are still limited. In this work, we introduced nuclear magnetic resonance (NMR) relaxometry for characterizing the hierarchical porous structures in cotton fibers without modifying their structure during sample preparation. By this method, the changes of the porous structures in cotton samples were characterized. It was found that soaking cellulose in water and stewing cellulose in N,N -dimethylacetamide at high temperature could efficiently improve the accessibility of cellulose samples to the solvent molecules and expand the Amorphous Region in cellulose. The method provided in this work can be used for the evaluation of the hierarchical porous structures of cellulose materials without additional modified information, which is helpful to the utilization of cellulose in various fields.
- Published
- 2016
10. Publisher Correction: Ambipolar device simulation based on the drift-diffusion model in ion-gated transition metal dichalcogenide transistors
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Nobuyuki Sano, Yijin Zhang, Akiko Ueda, Hiroshi Imamura, and Yoshihiro Iwasa
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lcsh:Computer software ,Materials science ,Ambipolar diffusion ,business.industry ,Transistor ,Computer Science Applications ,Ion ,law.invention ,lcsh:QA76.75-76.765 ,Transition metal ,Mechanics of Materials ,law ,Modeling and Simulation ,lcsh:TA401-492 ,Optoelectronics ,General Materials Science ,lcsh:Materials of engineering and construction. Mechanics of materials ,Device simulation ,business - Abstract
An amendment to this paper has been published and can be accessed via a link at the top of the paper.
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- 2020
11. Electric-field Control of Electronic States in WS2 Nanodevices by Electrolyte Gating
- Author
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Feng Qin, Masaro Yoshida, Yu Saito, Toshiya Ideue, Yoshihiro Iwasa, Yijin Zhang, Wu Shi, and Ryuji Suzuki
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Superconductivity ,Materials science ,General Immunology and Microbiology ,business.industry ,Ambipolar diffusion ,General Chemical Engineering ,General Neuroscience ,Doping ,Electrolyte ,Electrochemistry ,General Biochemistry, Genetics and Molecular Biology ,Condensed Matter::Materials Science ,Electric field ,Optoelectronics ,Electric potential ,business ,Electron-beam lithography - Abstract
A method of carrier number control by electrolyte gating is demonstrated. We have obtained WS2 thin flakes with atomically flat surface via scotch tape method or individual WS2 nanotubes by dispersing the suspension of WS2 nanotubes. The selected samples have been fabricated into devices by the use of the electron beam lithography and electrolyte is put on the devices. We have characterized the electronic properties of the devices under applying the gate voltage. In the small gate voltage region, ions in the electrolyte are accumulated on the surface of the samples which leads to the large electric potential drop and resultant electrostatic carrier doping at the interface. Ambipolar transfer curve has been observed in this electrostatic doping region. When the gate voltage is further increased, we met another drastic increase of source-drain current which implies that ions are intercalated into layers of WS2 and electrochemical carrier doping is realized. In such electrochemical doping region, superconductivity has been observed. The focused technique provides a powerful strategy for achieving the electric-filed-induced quantum phase transition.
- Published
- 2018
12. Superconductivity in Pristine 2Ha−MoS2 at Ultrahigh Pressure
- Author
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Zhaorong Yang, Xuliang Chen, Xiao-Di Liu, Shengqi Chu, Yijin Zhang, Yanming Ma, Fei Yen, Yonghui Zhou, Jinlong Zhu, Yanchun Li, Zhenhua Chi, Chuanlong Lin, Jinggeng Zhao, Feng Peng, and Tomoko Kagayama
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Superconductivity ,Diffraction ,Range (particle radiation) ,Materials science ,Condensed matter physics ,Intercalation (chemistry) ,General Physics and Astronomy ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,01 natural sciences ,Synchrotron ,law.invention ,Pressure range ,law ,0103 physical sciences ,010306 general physics ,0210 nano-technology ,Fermi Gamma-ray Space Telescope - Abstract
As a follow-up of our previous work on pressure-induced metallization of the 2H_{c}-MoS_{2} [Chi et al., Phys. Rev. Lett. 113, 036802 (2014)PRLTAO0031-900710.1103/PhysRevLett.113.036802], here we extend pressure beyond the megabar range to seek after superconductivity via electrical transport measurements. We found that superconductivity emerges in the 2H_{a}-MoS_{2} with an onset critical temperature T_{c} of ca. 3 K at ca. 90 GPa. Upon further increasing the pressure, T_{c} is rapidly enhanced beyond 10 K and stabilized at ca. 12 K over a wide pressure range up to 220 GPa. Synchrotron x-ray diffraction measurements evidenced no further structural phase transition, decomposition, and amorphization up to 155 GPa, implying an intrinsic superconductivity in the 2H_{a}-MoS_{2}. DFT calculations suggest that the emergence of pressure-induced superconductivity is intimately linked to the emergence of a new flat Fermi pocket in the electronic structure. Our finding represents an alternative strategy for achieving superconductivity in 2H-MoS_{2} in addition to chemical intercalation and electrostatic gating.
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- 2018
13. Application of transition-metal dichalcogenides beyond general electronics
- Author
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Yijin Zhang
- Subjects
Materials science ,Transition metal ,Electronics ,Engineering physics - Published
- 2017
14. Electrically Switchable Chiral Light-Emitting Transistor
- Author
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Yoshihiro Iwasa, Takashi Oka, Justin Ye, Yijin Zhang, R. Suzuki, and Device Physics of Complex Materials
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Multidisciplinary ,Materials science ,VALLEY POLARIZATION ,INSULATOR ,business.industry ,Ambipolar diffusion ,Transistor ,WSE2 ,Electroluminescence ,Polarization (waves) ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,Electric field ,ELECTROLUMINESCENCE ,Optoelectronics ,Tungsten diselenide ,DIODES ,FIELD ,business ,Circular polarization ,Diode ,MONOLAYER MOS2 - Abstract
Controlling Chiral Light Emission Circularly polarized light plays important roles in a number of applications such as displays, communication, and sensing. Thus, the ability to produce compact and readily controllable polarized light sources is important, and dichalcogenide materials such as tungsten diselenide may provide a route to such sources. Zhang et al. (p. 725 , published online 17 April; see the Perspective by Zaumseil ) formed an electric-double-layer transistor structure with WSe2 and used a gated ionic liquid to control the carrier density. Electrical control of the output light was achieved with the polarization being switched by reversing the polarity of the applied field and injected charge.
- Published
- 2014
15. Interface transport properties in ion-gated nano-sheets
- Author
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Justin Ye, Yuichi Kasahara, Yijin Zhang, and Yoshihiro Iwasa
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Quantum phase transition ,GRAPHENE ,TRANSITION-METAL DICHALCOGENIDES ,Materials science ,Spin states ,INSULATOR ,Graphene ,HGTE QUANTUM-WELLS ,General Physics and Astronomy ,Nanotechnology ,INDUCED SUPERCONDUCTIVITY ,STATE ,law.invention ,ELECTRONIC-PROPERTIES ,law ,Electric field ,Topological insulator ,DENSITY ,General Materials Science ,Field-effect transistor ,Physical and Theoretical Chemistry ,FIELD-EFFECT TRANSISTORS ,Transport phenomena ,Single crystal ,TEMPERATURE - Abstract
Recent advances in atomic-scale preparation of ultrathin nano-sheets and efficient field-effect gating mediated by movement of ions have provided a prolific paradigm for creating exotic states at interfaces of a new-type of device called electric-double layer transistors (EDLTs). We present a short review on these liquid/solid interfaces formed on nano-sheets prepared by micro cleaving a bulk layered single crystal, which can be electrostatically doped to a high carrier density of ∼1014 cm−2. Atomically flat surfaces prepared on various layered materials allowed ideal transport when they acted as transistor channels after accumulating dense carriers. The unique system combining these two advantages enabled observations of novel transport phenomena showing quantum phase transition of charge and spin states controlled by electric field. Examples include gate-induced metal-insulator transition, opening of new transport channels, and field-induced interface superconductivity, which present a rapidly growing field with emerging opportunities for science and technology.
- Published
- 2013
16. Ambipolar transport in MoS2 based electric double layer transistors
- Author
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Yoshihiro Iwasa, Jianting Ye, and Yijin Zhang
- Subjects
Materials science ,Fabrication ,Band gap ,Graphene ,business.industry ,Ambipolar diffusion ,Transistor ,Nanotechnology ,Electron ,law.invention ,law ,Hardware_INTEGRATEDCIRCUITS ,Optoelectronics ,Field-effect transistor ,business ,Single crystal - Abstract
Making field effect transistors (FETs) on thin flake of single crystal isolated from layered materials was pioneered by the success of graphene. To overcome the difficulties of the zero band gap in graphene electronics, we report the fabrication of an electric double layer (EDL) transistor, a variant of FET, based on another layered material, MoS2. Using strong carrier tunability found in EDL coupled by ion movement, MoS2 transistor displayed an unambiguously ambipolar operation in addition to its commonly observed n-type transport. A high on/off ratio >104, large “ON” state conductivity of ∼mS, and a high reachable n2D ∼ 1×1014 cm-2 confirmed the high performance transistor operation being important for application. The high-density carriers of both holes and electrons can drive the MoS2 channel to metallic states indicating that new electronic phases could be accessed using the protocol established in making EDL gated transistors on layered materials.
- Published
- 2013
17. Field-induced superconductivity in MoS2
- Author
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Yoshihiro Iwasa, Yijin Zhang, and Jianting Ye
- Subjects
Superconductivity ,Materials science ,Semiconductor ,Condensed matter physics ,Ambipolar diffusion ,business.industry ,Phase (matter) ,Doping ,Gate dielectric ,Metal–insulator transition ,business ,Phase diagram - Abstract
We fabricated MoS2 transistor adopting electric double layer (EDL) as gate dielectric. So far, EDL has realized p-type conducting MoS2 in addition to well-known n-type conduction showing ambipolar operation. In our study, field-effect superconducting transition of MoS2 was realized with maximum TC around 10 K. This TC is the highest not only within MoS2 compounds but also among whole TMDs. The highest TC discovered in this study lies in the carrier density region much smaller than chemically investigated region. Such compounds with small doping level have never been successfully synthesized by chemical method. Furthermore, by combining HfO2 (typical high-k material for FETs) gating with EDL gating, continuous control of carrier density, and thus quantum phase, was demonstrated. As a result, we successfully obtained the phase diagram of MoS2. Interestingly, the TC exhibits strong carrier density dependence, showing dome-shaped superconducting phase. Superconducting dome in other materials than cuprates has been reported only a few times in doped 2D semiconductors. Since FET charge accumulation is basically two dimensional, our result implies the existence of common mechanism for superconducting dome in 2D band insulators.
- Published
- 2013
18. Gate-Optimized Thermoelectric Power Factor in Ultrathin WSe2 Single Crystals
- Author
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Yoshihiro Iwasa, Ryuji Suzuki, Masaru Onga, Yu Saito, Masaro Yoshida, Takahiko Iizuka, Sunao Shimizu, and Yijin Zhang
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Range (particle radiation) ,Materials science ,business.industry ,Mechanical Engineering ,Doping ,Bioengineering ,02 engineering and technology ,General Chemistry ,Electron ,Power factor ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Condensed Matter::Materials Science ,Condensed Matter::Superconductivity ,Electric field ,Seebeck coefficient ,0103 physical sciences ,Optoelectronics ,General Materials Science ,010306 general physics ,0210 nano-technology ,business ,Chemical composition ,Thermoelectric power factor - Abstract
We report an electric field tuning of the thermopower in ultrathin WSe2 single crystals over a wide range of carrier concentration by using electric double-layer (EDL) technique. We succeeded in the optimization of power factor not only in the hole but also in the electron side, which has never been chemically accessed. The maximized values of power factor are one-order larger than that obtained by changing chemical composition, reflecting the clean nature of electrostatic doping.
- Published
- 2016
19. Optoelectronic response of a WS 2 tubular p - n junction
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Yoshihiro Iwasa, Jurgen H. Smet, Feng Qin, Masaru Onga, Alla Zak, Yijin Zhang, Reshef Tenne, and Wu Shi
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Materials science ,Fabrication ,Spintronics ,business.industry ,Mechanical Engineering ,Photovoltaic system ,02 engineering and technology ,General Chemistry ,Photovoltaic effect ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Mechanics of Materials ,0103 physical sciences ,Valleytronics ,Optoelectronics ,General Materials Science ,Quantum efficiency ,010306 general physics ,0210 nano-technology ,business ,p–n junction ,Diode - Abstract
Due to their favourable and rich electronic and optical properties, group-VI-B transition-metal dichalcogenides (TMDs) have attracted considerable interest. They have earned their position in the materials portfolio of the spintronics and valleytronics communities. The electrical performance of TMDs is enhanced by rolling up the two-dimensional (2D) sheets to form quasi-one-dimensional (1D) tubular structures. The fabrication of p-n junctions out of these tubular TMDs would boost their potential for optoelectronic devices as such junctions represent a fundamental building block. Here, we report the realization of a p-n junction out of a single, isolated WS2-nanotube (WS2-NT). Light-emitting diode operation and photovoltaic behaviour were observed based on such p-n junctions. The emitted light as well as the photovoltaic effect exhibit strong linear polarization characteristics due to the quasi-1D nature. The external quantum efficiency for the photovoltaic effect reaches a value as high as 4.8%, exceeding by far that of 2D TMDs and even approaching the internal quantum efficiency of the 2D TMDs. This efficiency improvement indicates that TMD nanotubes are superior candidates over 2D TMDs for optoelectronic applications.
- Published
- 2018
20. Memristive phase switching in two-dimensional 1T-TaS 2 crystals
- Author
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Yoshihiro Iwasa, Masaro Yoshida, Ryuji Suzuki, Masaki Nakano, and Yijin Zhang
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Phase transition ,Materials science ,nonvolatile memory ,Materials Science ,Tantalum ,chemistry.chemical_element ,Nanotechnology ,Tantalum disulfide (TaS2) ,electrical phase switching ,law.invention ,Crystal ,law ,Electric field ,Metastability ,metastable states ,Physics::Atomic Physics ,two-dimensional materials ,memristor ,Research Articles ,Multidisciplinary ,Electronic correlation ,Graphene ,SciAdv r-articles ,first-order phase transition ,Non-volatile memory ,chemistry ,Chemical physics ,Research Article - Abstract
Electrical switching to multiple novel metastable states in a correlated two-dimensional crystal., Scaling down materials to an atomic-layer level produces rich physical and chemical properties as exemplified in various two-dimensional (2D) crystals including graphene, transition metal dichalcogenides, and black phosphorus. This is caused by the dramatic modification of electronic band structures. In such reduced dimensions, the electron correlation effects are also expected to be significantly changed from bulk systems. However, there are few attempts to realize novel phenomena in correlated 2D crystals. We report memristive phase switching in nano-thick crystals of 1T-type tantalum disulfide (1T-TaS2), a first-order phase transition system. The ordering kinetics of the phase transition were found to become extremely slow as the thickness is reduced, resulting in an emergence of metastable states. Furthermore, we realized unprecedented memristive switching to multistep nonvolatile states by applying an in-plane electric field. The reduction of thickness is essential to achieve such nonvolatile electrical switching behavior. The thinning-induced slow kinetics possibly make the various metastable states robust and consequently realize the nonvolatile memory operation. The present result indicates that a 2D crystal with correlated electrons is a novel nano-system to explore and functionalize multiple metastable states that are inaccessible in its bulk form.
- Published
- 2015
21. Superconductivity Series in Transition Metal Dichalcogenides by Ionic Gating
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Jianting Ye, Masaro Yoshida, Yu Saito, Ryuji Suzuki, Jun Miyazaki, Yijin Zhang, Naoko Inoue, Yoshihiro Iwasa, Wu Shi, and Device Physics of Complex Materials
- Subjects
Superconductivity ,Multidisciplinary ,Materials science ,VALLEY POLARIZATION ,INSULATOR ,GATED TRANSISTORS ,Band gap ,MOLYBDENUM TRIOXIDE ,BAND-GAP ,Doping ,Ionic bonding ,Gating ,ELECTRIC-FIELD ,Article ,TRANSPORT ,CRYSTALS ,chemistry.chemical_compound ,chemistry ,Transition metal ,Chemical physics ,DENSITY ,Condensed Matter::Superconductivity ,Ionic liquid ,Field-effect transistor ,MONOLAYER MOS2 - Abstract
Functionalities of two-dimensional (2D) crystals based on semiconducting transition metal dichalcogenides (TMDs) have now stemmed from simple field effect transistors (FETs) to a variety of electronic and opto-valleytronic devices and even to superconductivity. Among them, superconductivity is the least studied property in TMDs due to methodological difficulty accessing it in different TMD species. Here, we report the systematic study of superconductivity in MoSe2, MoTe2 and WS2 by ionic gating in different regimes. Electrostatic gating using ionic liquid was able to induce superconductivity in MoSe2 but not in MoTe2 because of inefficient electron accumulation limited by electronic band alignment. Alternative gating using KClO4/polyethylene glycol enabled a crossover from surface doping to bulk doping, which induced superconductivities in MoTe2 and WS2 electrochemically. These new varieties greatly enriched the TMD superconductor families and unveiled critical methodology to expand the capability of ionic gating to other materials.
- Published
- 2015
22. Controlling charge-density-wave states in nano-thick crystals of 1T-TaS2
- Author
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Masaro Yoshida, Yasuhiko Imai, Akihiko Fujiwara, Shigeru Kimura, Ryuji Suzuki, Yoshihiro Iwasa, Yijin Zhang, Jianting Ye, and Device Physics of Complex Materials
- Subjects
Superconductivity ,Phase transition ,TRANSITION-METAL DICHALCOGENIDES ,Multidisciplinary ,Materials science ,Condensed matter physics ,INSULATOR ,Graphene ,SUPERCONDUCTIVITY ,PHASE ,Tantalum ,chemistry.chemical_element ,LOCALIZATION ,Electron ,Article ,law.invention ,Transition metal ,chemistry ,law ,Nano ,Charge density wave ,MONOLAYER MOS2 - Abstract
Two-dimensional crystals, especially graphene and transition metal dichalcogenides (TMDs), are attracting growing interests because they provide an ideal platform for novel and unconventional electronic band structures derived by thinning. The thinning may also affect collective phenomena of electrons in interacting electron systems and can lead to exotic states beyond the simple band picture. Here, we report the systematic control of charge-density-wave (CDW) transitions by changing thickness, cooling rate and gate voltage in nano-thick crystals of 1T-type tantalum disulfide (1T-TaS2). Particularly the clear cooling rate dependence, which has never been observed in bulk crystals, revealed the nearly-commensurate CDW state in nano-thick crystals is a super-cooled state. The present results demonstrate that, in the two-dimensional crystals with nanometer thickness, the first-order phase transitions are susceptible to various perturbations, suggestive of potential functions of electronic phase control.
- Published
- 2014
23. Single-Walled Carbon-Nanotube P-N Junction Diode for Optoelectronics
- Author
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Taishi Takenobu, Yoshihiro Iwasa, Jiang Pu, Yijin Zhang, T. Fujimoto, R. Shimizu, and Kazuhiro Yanagi
- Subjects
Materials science ,business.industry ,law ,Optoelectronics ,Carbon nanotube ,business ,p–n junction ,Diode ,law.invention - Published
- 2013
24. Formation of a stable p-n junction in a liquid-gated MoS2 ambipolar transistor
- Author
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Taishi Takenobu, Yoshihiro Iwasa, Jianting Ye, Yijin Zhang, Yohei Yomogida, and Device Physics of Complex Materials
- Subjects
Molybdenum disulfide ,Circular dichroism ,electric double-layer transistor ,Materials science ,VALLEY POLARIZATION ,Electrical junction ,Bioengineering ,law.invention ,chemistry.chemical_compound ,law ,General Materials Science ,MONOLAYER MOS2 ,Diode ,p-n junction ,business.industry ,Ambipolar diffusion ,Mechanical Engineering ,Transistor ,General Chemistry ,Condensed Matter Physics ,ambipolar ,SINGLE-CRYSTAL ,chemistry ,Thin-film transistor ,THIN-FILM TRANSISTORS ,Optoelectronics ,EMISSION ,p–n junction ,business ,LIGHT-EMITTING TRANSISTORS - Abstract
Molybdenum disulfide (MoS2) has gained attention because of its high mobility and circular dichroism. As a crucial step to merge these advantages into a single device, we present a method that electronically controls and locates p-n junctions in liquid-gated ambipolar MoS2 transistors. A bias-independent p-n junction was formed, and it displayed rectifying I-V characteristics. This p-n diode could perform a crucial role in the development of optoelectronic valleytronic devices.
- Published
- 2013
25. High circular polarization in electroluminescence from MoSe2
- Author
-
Masaru Onga, Yoshihiro Iwasa, Yijin Zhang, and Ryuji Suzuki
- Subjects
Materials science ,Photoluminescence ,Physics and Astronomy (miscellaneous) ,Condensed matter physics ,Scattering ,business.industry ,Transistor ,02 engineering and technology ,Electroluminescence ,021001 nanoscience & nanotechnology ,Polarization (waves) ,01 natural sciences ,Helicity ,law.invention ,Transition metal ,law ,0103 physical sciences ,Optoelectronics ,010306 general physics ,0210 nano-technology ,business ,Circular polarization - Abstract
The coupling between the valley degree of freedom and the optical helicity is one of the unique phenomena in transition metal dichalcogenides. The significant valley polarization evaluated from circularly polarized photoluminescence (PL) has been reported in many transition metal dichalcogenides, except in MoSe2. This compound is an anomalous material showing ultra-fast relaxation of the valley polarized states, which causes negligible polarization in the PL. Meanwhile, circularly polarized electroluminescence (EL) has been recently reported in a WSe2 light-emitting transistor, providing another method for using the valley degree of freedom. Here, we report the EL properties of MoSe2, demonstrating electrical switching of the optical helicity. Importantly, we observed high circular polarization reaching 66%. The results imply that the dominant mechanism of circularly polarized EL is robust against intervalley scattering, in marked contrast to the PL.
- Published
- 2016
26. Ambipolar MoS2 Thin Flake Transistors
- Author
-
Yoshihiro Iwasa, Jianting Ye, Yijin Zhang, Yusuke Matsuhashi, and Device Physics of Complex Materials
- Subjects
GRAPHENE ,Electron mobility ,TRANSITION-METAL DICHALCOGENIDES ,Materials science ,Transistors, Electronic ,Bioengineering ,Nanotechnology ,Dielectric ,Sulfides ,law.invention ,law ,Hall effect ,Transition metal chalcogenide ,General Materials Science ,Particle Size ,Electrodes ,Molybdenum ,business.industry ,Graphene ,Ambipolar diffusion ,Mechanical Engineering ,SUPERCONDUCTIVITY ,Transistor ,electric double layer ,FET ,Equipment Design ,General Chemistry ,Condensed Matter Physics ,Nanostructures ,Equipment Failure Analysis ,Semiconductor ,DENSITY ,Optoelectronics ,Field-effect transistor ,Crystallization ,business - Abstract
Field effect transistors (FETs) made of thin flake single crystals isolated from layered materials have attracted growing interest since the success of graphene. Here, we report the fabrication of an electric double layer transistor (EDLT, a FET gated by ionic liquids) using a thin flake of MoS2, a member of the transition metal dichalcogenides, an archetypal layered material. The EDLT of the thin flake MoS2 unambiguously displayed ambipolar operation, in contrast to its commonly known bulk property as an n-type semiconductor. High-performance transistor operation characterized by a large "ON" state conductivity in the order of similar to mS and a high on/off ratio >10(2) was realized for both hole and electron transport. Hall effect measurements revealed mobility of 44 and 86 cm(2) V-1 s(-1) for electron and hole, respectively. The hole mobility is twice the value of the electron mobility, and the density of accumulated carrier reached 1 x 10(14) cm(-2), which is 1 order of magnitude larger than conventional FETs with solid dielectrics. The high-density carriers of both holes and electrons can create metallic transport in the MoS2 channel. The present result is not only important for device applications with new functionalities, but the method itself would also act as a protocol to study this class of material for a broader scope of possibilities in accessing their unexplored properties.
- Published
- 2012
27. 2D crystals of transition metal dichalcogenide and their iontronic functionalities
- Author
-
Masaro Yoshida, Yoshihiro Iwasa, Ryuji Suzuki, and Yijin Zhang
- Subjects
Phase transition ,Materials science ,Spintronics ,business.industry ,Mechanical Engineering ,Transistor ,Nanotechnology ,Fermi energy ,General Chemistry ,Condensed Matter Physics ,law.invention ,Semiconductor ,Mechanics of Materials ,law ,Valleytronics ,Monolayer ,General Materials Science ,Field-effect transistor ,business - Abstract
2D crystals based on transition metal dichalcogenides (TMDs) provide a unique platform of novel physical properties and functionalities, including photoluminescence, laser, valleytronics, spintronics, piezoelectric devices, field effect transistors (FETs), and superconductivity. Among them, FET devices are extremely useful because of voltage-tunable carrier density and Fermi energy. In particular, high density charge accumulation in electric double layer transistor (EDLT), which is a FET device driven by ionic motions, is playing key roles for expanding the functionalities of TMD based 2D crystals. Here, we report several device concepts which were realized by introducing EDLTs in TMDs, taking the advantage of their extremely unique band structures and phase transition phenomena realized simply by thinning to the monolayer level. We address two kinds of TMDs based on group VI and group V transition metals, which basically yield semiconductors and metals, respectively. For each system, we first introduce peculiar characteristics of TMDs achieved by thinning the crystals, followed by the related FET functionalities.
- Published
- 2015
28. Fabrication of stretchable MoS2 thin-film transistors using elastic ion-gel gate dielectrics
- Author
-
Yoshifumi Wada, Taishi Takenobu, Yoshihiro Iwasa, Jiang Pu, Yijin Zhang, Lain-Jong Li, and Jacob Tse-Wei Wang
- Subjects
Electron mobility ,Materials science ,Fabrication ,Physics and Astronomy (miscellaneous) ,business.industry ,Transistor ,Stretchable electronics ,Dielectric ,law.invention ,Threshold voltage ,chemistry.chemical_compound ,chemistry ,law ,Thin-film transistor ,Optoelectronics ,business ,Molybdenum disulfide - Abstract
We fabricated stretchable molybdenum disulfide thin-film transistors (MoS2 TFTs) on poly(dimethylsiloxane) substrates using ion gels as elastic gate dielectrics. The TFTs exhibited an electron mobility of 1.40 cm2/(V·s) and an on/off current ratio of 104 with a notably low threshold voltage (∼1 V). Furthermore, our MoS2 TFTs operated at a mechanical strain of 5% without significant degradation of their electrical properties. These results demonstrate the potential for using MoS2 films for stretchable electronics.
- Published
- 2013
29. Gate-Induced Superconductivity in Layered-Material-Based Electric Double Layer Transistors
- Author
-
Justin Ye, Yoshihiro Iwasa, Alberto F. Morpurgo, Saverio Russo, Monica F. Craciun, Yijin Zhang, Yuichi Kasahara, and Yusuke Matsuhashi
- Subjects
Superconductivity ,History ,Materials science ,business.industry ,Doping ,Transistor ,Nanotechnology ,Computer Science Applications ,Education ,law.invention ,Condensed Matter::Materials Science ,Charge-carrier density ,law ,Optoelectronics ,Field-effect transistor ,business - Abstract
High carrier density part of many materials could be accessed by a variation of the field effect transistor technique: electric double layer transistor. Carrier density regime of n~1014 cm−2 can be easily accessed electrostatically realizing effective doping without chemical modification. In this study, we utilized micro-cleavage on a number of interesting layered materials. And realized high carrier density state and high performance transport on atomically flat surfaces.
- Published
- 2012
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