1. Phase transition and heterogeneous strengthening mechanism in CoCrFeNiMn high-entropy alloy fabricated by laser-engineered net shaping via annealing at intermediate-temperature
- Author
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Yunjian Bai, Maohui Li, Kun Zhang, Bingchen Wei, Yanpeng Wei, Kuo Yan, and Heng Jiang
- Subjects
Equiaxed crystals ,Materials science ,Polymers and Plastics ,Mechanical Engineering ,High entropy alloys ,Metals and Alloys ,02 engineering and technology ,Plasticity ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Mechanics of Materials ,Materials Chemistry ,Ceramics and Composites ,Laser engineered net shaping ,Grain boundary ,Deformation (engineering) ,Composite material ,Dislocation ,0210 nano-technology ,Ductility - Abstract
High-entropy alloys (HEAs) have attracted tremendous attention owing to their controllable mechanical properties, whereas additive manufacturing (AM) is an efficient and flexible processing route for novel materials design. However, a profound appraisal of the fundamental material physics behind the strengthening of AM-printed HEAs upon low/intermediate-temperature annealing is essential. In this work, CoCrFeNiMn HEAs have been prepared using laser-engineered net shaping (LENS) and subsequently annealed at different temperatures. The CoCrFeNiMn HEA annealed at intermediate-temperature (873 K) exhibits a strong strain hardening capability, resulting in ultimate strength of 725 MPa and plasticity of 22%. A ternary heterogeneous strengthening mechanism is proposed to explain this phenomenon, in which equiaxed grains, columnar grains, and σ precipitates play different roles during tensile deformation. The resultant excellent strength and ductility can be ascribed to the heterostructure-induced mismatch. The equiaxed grains provide adequate grain boundaries (GBs), which induce dislocation plugging-up and entanglement; the columnar grains induce the onset and arrest of the dislocations for plastic deformation; and the σ precipitates hinder the movement of slip dislocations. The results provide new insights into overcoming the strength-ductility trade-off of LENS-printed HEAs with complex geometries.
- Published
- 2021
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