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Zhundong (ZD) coalfield has a large number of coal reserves. However, the severe fouling and slagging problems that occurred in ZD coal-fired utility boilers have seriously hindered the large-scale utilization of ZD coal. Deep understanding of the mineral transformation of ZD coal during combustion and its impact on fouling and slagging can provide technical support for fouling and slagging prevention in utility boilers. In this paper, a novel temperature and atmosphere controlling method was proposed to study ash deposition. Wucaiwan (WCW) coal ash samples in different atmospheres and temperatures were collected efficiently by the established single thermocouple high-temperature online microscope observation test rig. The influence of rapid heating and cooling on the mineral transformation of WCW coal ash samples was systematically investigated using XRD and SEM-EDS, respectively. The effects of SO2 in the flue gas on the mineral transformation and the sulphates generation of the coal ash were analysed by comparing the experimental results in oxidizing atmosphere and simulated flue gas atmosphere. The experimental results showed that the microscopic morphology, mineral and element conversion of coal ash samples during heating and cooling were quite different. Compared with oxidizing atmosphere, SO2 in the flue gas significantly increase the S content of ash at 600 °C−1200 °C and the amount of molten minerals on the quenched ash sample surface during cooling. These results indicate that SO2 can promote the sulfation reactions of alkali/alkaline earth metal (AAEM) on the quenched ash sample surface and restrain the decomposition of S-containing minerals in ash cooling. The investigation also reveals that the molten AAEM sulphate on the ash surface is mainly generated at 800 °C−900 °C. The present study not only provides the fundamental understandings of mineral transformation but also guides industrial applications to reduce the risk of ash deposition.

Reinforcement efficiency of different types of carbon nanotubes (CNT) have been compared in polyacrylonitrile (PAN) films at nanotube loadings of 5, 10, and 20 wt %. The films are characterized for mechanical, dynamic-mechanical, and thermomechanical properties, electrical conductivity, as well as structural analysis. PAN/CNT composite films exhibit electrical conductivities up to 5500 S/m. Based on X-ray diffraction, PAN crystallinity was shown to increase with the presence of CNT. PAN-CNT interactions in the various composites were compared using conventional activation energy analysis. The strongest physical interaction between PAN and CNT was found in samples containing single-wall carbon nanotubes (SWNT). CNT surface area was also measured using nitrogen gas adsorption and correlated with PAN-CNT composite film mechanical properties, in an effort to better understand PAN-CNT interactions for different CNT morphologies. Solvent behavior of various composite films has also been investigated. The presence of CNT was found to improve PAN solvent resistance.

An LCE with a p-pentaphenyl transverse rod in the main chain was synthesized, in which the rod can be oriented parallel or normal to the main chain under uniaxial tension. DSC and WAXD studies indicate a highly ordered lamellar structure typical of a smectic A phase. Stress-strain curves showed a large Young modulus at small strains, followed by a yield point, at which necking occurred and the specimen became transparent. An interesting rigid-soft-rigid phenomenon was observed in the yield section, which is likely to indicate a self-assembly-driven reconstruction process. Two possible arrangements of transverse rods and chain extenders are proposed for the network structure.

Polyacrylonitrile (PAN)/single wall carbon nanotube (SWNT) composite films have been processed with unique combination of tensile strength (103 MPa), modulus (10.9 GPa), electrical conductivity (1.5×10 4 S/m), dimensional stability (coefficient of thermal expansion 1.7×10 −6 /°C), low density (1.08 g/cm 3 ), solvent resistance, and thermal stability. PAN molecular motion above the glass transition temperature ( T g ) in the composite film is significantly suppressed, resulting in high PAN/SWNT storage modulus above T g (40 times the PAN storage modulus). Rope diameter in the SWNT powder was 26 nm, while in 60/40 PAN/SWNT film, the rope diameter was 40 nm. PAN crystallite size from (110) plane in PAN and PAN/SWNT films was 5.3 and 2.9 nm, respectively. This study suggests good interaction between PAN and SWNT.