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17 results on '"Daniel Alves, Dalla Corte"'

1. First Example of Protonation of Ruddlesden–Popper Sr2IrO4: A Route to Enhanced Water Oxidation Catalysts

Author

Alexis Grimaud, Paul E. Pearce, Daniel Alves Dalla Corte, Domitille Giaume, Ronghuang Zhang, Gwenaëlle Rousse, Heifang Li, Artem M. Abakumov, Michaël Deschamps, Vanessa Pimenta, Jordi Cabana, Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université d'Orléans (UO), Université d'Orléans (UO), Chimie du solide et de l'énergie (CSE), and Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Chemical transformation, Materials science, Hydrogen, Electrolysis of water, business.industry, General Chemical Engineering, Inorganic chemistry, chemistry.chemical_element, Protonation, [CHIM.MATE]Chemical Sciences/Material chemistry, 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 7. Clean energy, 0104 chemical sciences, Catalysis, Renewable energy, chemistry, Value (economics), Materials Chemistry, 0210 nano-technology, business
Abstract

International audience; Water electrolysis is considered as a promising way to store and convert excess renewable energies into hydrogen, which is of high value for many chemical transformation processes such as the Haber-Bosch process. However, to allow for the widespread of the polymer electrolyte membrane water electrolysis (PEMWE) technology, the main challenge lies in the design of robust catalysts for oxygen evolution reaction (OER) under acidic conditions since most of transition metal-based oxides undergo structural degradation under these harsh acidic conditions. To broaden the variety of candidate materials as OER catalysts, a cation-exchange synthetic route was recently explored to reach crystalline pronated iridates with unique structural properties and stability. In this work, a new protonated phase H 3.6 IrO 4 •3.7H 2 O, prepared via Sr 2+ /H + cation exchange at room temperature starting from the parent Ruddlesden-Popper Sr 2 IrO 4 phase, is described. This is the first discovery of crystalline protonated iridate forming from a perovskite-like phase, adopting a layered structure with apex-linked IrO 6 octahedra. Furthermore, H 3.6 IrO 4 •3.7H 2 O is found to possess not only an enhanced specific catalytic activity, superior to that of other perovskite-based iridates, but also a mass activity comparable to that of nanosized IrO x particles, while showing an improved catalytic stability owing to its ability to reversibly exchange protons in acid.

Published
2020

2. A Dissolution/Precipitation Equilibrium on the Surface of Iridium‐Based Perovskites Controls Their Activity as Oxygen Evolution Reaction Catalysts in Acidic Media

Author

Moulay Tahar Sougrati, Alexis Grimaud, Wei Yin, Manel Ben Osman, Ronghuan Zhang, Nicolas Dubouis, Daniel Alves Dalla Corte, Domitille Giaume, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Institut de Recherche de Chimie Paris (IRCP), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Ministère de la Culture (MC), ANR-17-CE05-0008,MIDWAY,Contrôle des Interfaces Electrochimiques pour de meilleurs electrocatalyseurs pour l'oxydation de l'eau(2017), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), and Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Ministère de la Culture (MC)

Subjects
iridium dissolution, Materials science, oxygene volution reaction, 010405 organic chemistry, Precipitation (chemistry), Inorganic chemistry, perovskites, Oxygen evolution, chemistry.chemical_element, [CHIM.CATA]Chemical Sciences/Catalysis, General Medicine, General Chemistry, Pourbaix diagram, 010402 general chemistry, Electrochemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, chemistry, Pourbaix diagrams, Iridium, Deposition (chemistry), Dissolution
Abstract

International audience; Recently, Ir (V)-based perovskite-like materials were proposed as oxygen evolution reaction (OER) catalysts in acidic media with promising performance. However, iridium dissolution and surface reconstruction were observed, questioning the real active sites on the surface of these catalysts. In this work, Sr2MIr (V) O6 (M = Fe, Co) and Sr2Fe0.5Ir0.5 (V) O4 were explored as OER catalysts in acidic media. Their activities were observed to be roughly equal to that previously reported for La2LiIrO6 or Ba2PrIrO6. Coupling electrochemical measurements with iridium dissolution studies under chemical or electrochemical conditions, we show that the deposition of an IrOx layer on the surface of these perovskites is responsible for their OER activity. Furthermore, we experimentally reconstruct the iridium Pourbaix diagram which will help guide future research in controlling the dissolution/precipitation equilibrium of iridium species for the design of better Ir-based OER catalysts.

Published
2019

3. Operando decoding of chemical and thermal events in commercial Na(Li)-ion cells via optical sensors

Author

Steven T. Boles, Hwa Yaw Tam, Jiaqiang Huang, Betar M. Gallant, E. R. Logan, Julien Bonefacino, Charles Delacourt, Laura Albero Blanquer, Daniel Alves Dalla Corte, Jean-Marie Tarascon, J. R. Dahn, Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Laboratoire réactivité et chimie des solides - UMR CNRS 7314 (LRCS), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), and Université de Picardie Jules Verne (UPJV)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)

Subjects
Isothermal microcalorimetry, Battery (electricity), Optical fiber, Materials science, Energy Engineering and Power Technology, 02 engineering and technology, Electrolyte, 010402 general chemistry, 7. Clean energy, 01 natural sciences, Heat capacity, law.invention, [SPI.MAT]Engineering Sciences [physics]/Materials, Reliability (semiconductor), [CHIM.GENI]Chemical Sciences/Chemical engineering, Fiber Bragg grating, law, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, Thermal, ComputingMilieux_MISCELLANEOUS, Renewable Energy, Sustainability and the Environment, business.industry, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Electronic, Optical and Magnetic Materials, Fuel Technology, Optoelectronics, 0210 nano-technology, business
Abstract

Monitoring the dynamic chemical and thermal state of a cell during operation is crucial to making meaningful advancements in battery technology as safety and reliability cannot be compromised. Here we demonstrate the feasibility of incorporating optical fibre Bragg grating sensors into commercial 18650 cells. By adjusting fibre morphologies, wavelength changes associated with both temperature and pressure are decoupled with high accuracy, which allows tracking of chemical events such as solid electrolyte interphase formation and structural evolution. We also demonstrate how multiple sensors are used to determine the heat generated by the cell without resorting to microcalorimetry. Unlike with conventional isothermal calorimetry, the cell’s heat capacity contribution is readily assessed, allowing for full parametrization of the thermal model. Collectively, these findings offer a scalable solution for screening electrolyte additives, rapidly identifying the best formation processes of commercial cells and designing battery thermal management systems with enhanced safety. Tracking a battery’s chemical and thermal states during operation offers important information on its reliability and lifetime. Here the authors develop optical fibre sensors and decouple temperature and pressure variations in the measurements inside of batteries, allowing chemical and thermal events to be monitored with high accuracy.

Published
2020

4. Elucidating the Origin of the Electrochemical Capacity in a Proton-Based Battery H x IrO 4 via Advanced Electrogravimetry

Author

Antonella Iadecola, Jean-Marie Tarascon, Pierre Lemaire, Hubert Perrot, Daniel Alves Dalla Corte, Ozlem Sel, Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Centre for Social Evolution (CSE), Department of Plant and Environmental Sciences [Copenhagen], Faculty of Science [Copenhagen], University of Copenhagen = Københavns Universitet (UCPH)-University of Copenhagen = Københavns Universitet (UCPH)-Faculty of Science [Copenhagen], University of Copenhagen = Københavns Universitet (UCPH)-University of Copenhagen = Københavns Universitet (UCPH)-Department of Biology [Copenhagen], University of Copenhagen = Københavns Universitet (UCPH)-University of Copenhagen = Københavns Universitet (UCPH), Laboratoire Interfaces et Systèmes Electrochimiques (LISE), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Collège de France - Chaire Chimie du solide et énergie, Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU)-Faculty of Science [Copenhagen], University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU)-Department of Biology [Copenhagen], University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU), and Chaire Chimie du solide et énergie

Subjects
Battery (electricity), aqueous battery, Materials science, Proton, [SPI.NRJ]Engineering Sciences [physics]/Electric power, Nanotechnology, 02 engineering and technology, proton insertion, 010402 general chemistry, 021001 nanoscience & nanotechnology, Electrochemistry, 01 natural sciences, EQCM, 0104 chemical sciences, protonic phase H x IrO 4, [SPI]Engineering Sciences [physics], Electrogravimetry, electrode-electrolyte interface, [CHIM]Chemical Sciences, General Materials Science, 0210 nano-technology
Abstract

International audience; Recently, because of sustainability issues dictated by societal demands, more importance has been given to aqueous systems and especially to proton-based battery. However, the mechanisms behind the processes leading to energy storage in such systems are still not elucidated. Under this scope, our study is structured on the selection of a model electrode material, the protonic phase H x IrO 4 and the scrutiny of the interfacial processes through suitable analytical tools. Herein, we employed operando Electrochemical Quartz Crystal Microbalance (EQCM) combined with Electrochemical Impedance Spectroscopy (EIS) to provide new insights into the mechanism intervening at the Electrode-Electrolyte Interface. Firstly, we demonstrated that not only the surface or near surface but the whole particle participates in the cationic redox process. Secondly, we proved the contribution of the proton on the overall potential window together with the incorporation of water at low potentials solely. This is explained by the fact that water molecules permit a further insertion of protons in the material by shielding the proton charge but at the expense of the proton kinetic properties. These findings shed new light on the importance of water molecules in the ion-insertion mechanisms taking place at the Electrode-Electrolyte Interface of aqueous proton-based batteries. Overall, the present results further highlight the richness of the EQCM based methods for the battery field in offering mechanistic insights that are crucial for the understanding of interfaces and charge storage in insertion compounds.

Published
2020

5. Li-Rich Layered Sulfide as Cathode Active Materials in All-Solid-State Li–Metal Batteries

Author

Daniel Alves Dalla Corte, Sujoy Saha, Florencia Marchini, Jean-Marie Tarascon, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Chaire Chimie du solide et énergie, Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), and Collège de France - Chaire Chimie du solide et énergie

Subjects
Materials science, Sulfide, Oxide, 02 engineering and technology, Electrolyte, 010402 general chemistry, 01 natural sciences, 7. Clean energy, law.invention, Metal, chemistry.chemical_compound, law, General Materials Science, Polarization (electrochemistry), chemistry.chemical_classification, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Cathode, 0104 chemical sciences, Anode, chemistry, Chemical engineering, visual_art, Electrode, visual_art.visual_art_medium, 0210 nano-technology, [CHIM.OTHE]Chemical Sciences/Other
Abstract

International audience; Great hopes are placed on all-solid state Li-metal batteries (ASSB's) to boost the energy density of the current Li-ion technology. Though, these devices still present a number of unresolved issues that keep them far from commercialization such as interfacial instability, lithium dendrite formation and lack of mechanical integrity during cycling. To mitigate these limiting aspects, the most advanced ASSB systems presently combine a sulfide or oxide-based solid electrolyte (SE) with a coated Li-based oxide as positive electrode and a lithium anode. Through this work we propose a different twist by switching from layered oxides to layered sulfides as active cathode materials. Herein we present the performance of a Li-rich layered sulfide of formula Li 1.13 Ti 0.57 Fe 0.3 S 2 (LTFS) in room temperature operating all-solid state batteries, using β-Li 3 PS 4 as a solid electrolyte and both InLi and Li anode materials. These batteries exhibit good cyclability, small polarization and, in the case of Li anode, no irreversible capacity. Taking advantage of the stable LTFS/β-Li 3 PS 4 interface, we also propose the use of LTFS mixed with an 2 oxide-based cathode material in the positive electrode of an ASSB. Our proof of concept using LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC 622) showed that the addition of a small amount of LTFS had a direct positive impact in the battery performance, ascribed to the improvement of the oxide cathode/sulfide SE interface.

Published
2020

6. Polymorphism in Li4Zn(PO4)2 and Stabilization of its Structural Disorder to Improve Ionic Conductivity

Author

Jean-Marie Tarascon, Gwenaëlle Rousse, Sujoy Saha, Daniel Alves Dalla Corte, Matthieu Courty, Ignacio Blazquez Alcover, Université Pierre et Marie Curie - Paris 6 (UPMC), Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Laboratoire réactivité et chimie des solides - UMR CNRS 7314 (LRCS), Université de Picardie Jules Verne (UPJV)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Collège de France - Chaire Chimie du solide et énergie, Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), and Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Materials science, Crystal chemistry, General Chemical Engineering, 02 engineering and technology, General Chemistry, Crystal structure, Conductivity, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, Crystallography, Polymorphism (materials science), Materials Chemistry, Fast ion conductor, [CHIM]Chemical Sciences, Ionic conductivity, Orthorhombic crystal system, 0210 nano-technology, Monoclinic crystal system
Abstract

International audience; Realization of the vulnerability of current rechargeable battery systems drives the research of solid electrolytes. In the search for a new Li ion conductor, we explore the rich crystal chemistry of Li 4 Zn(PO 4) 2 which presents a low temperature monoclinic (α-) and a high temperature orthorhombic (β-) polymorph. We solved the crystal structure of the β-phase and found that it has a disordered Li/Zn-sublattice while showing the largest conductivity; however it could not be stabilized at room temperature by quenching. We discovered that the partial substitution of Zn 2+ with Ga 3+ in Li 4-x Zn 1-x Ga x (PO 4) 2 first leads to an intermediate β' phase. Increasing the Ga content to 0.5 mol pfu. enables to stabilize the pure β-phase at room temperature, which exhibits a conductivity by several orders of magnitudes higher than the pristine sample. The crystal structures of the new β'/β-phases have been solved to elucidate the conduction mechanism, which confirms the high sensitivity of ionic conductivity on disorder.

Published
2018

7. Low-cost high-efficiency system for solar-driven conversion of CO 2 to hydrocarbons

Author

Lukas Lutz, Anders Hagfeldt, Sarah Lamaison, Nicolas Menguy, Tran Ngoc Huan, Marc Fontecave, Daniel Alves Dalla Corte, Silver-Hamill Turren-Cruz, Dilan Karapinar, Victor Mougel, Martin Foldyna, Federico Bella, Collège de France - Chaire Chimie des processus biologiques, Laboratoire de Chimie des Processus Biologiques (LCPB), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de physique des interfaces et des couches minces [Palaiseau] (LPICM), École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), Laboratory of Photomolecular Science (LSPM), Ecole Polytechnique Fédérale de Lausanne (EPFL), and Chaire Chimie des processus biologiques

Subjects
Electrocatalysis, PV–EC, CO2 reduction, Electrolyzer, Copper dendrites, Materials science, copper dendrites, electrocatalysis, electrolyzer, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, 7. Clean energy, Electrochemical cell, law.invention, pv-ec, law, evolution, ethylene, [CHIM]Chemical Sciences, Process engineering, Multidisciplinary, copper-oxide electrocatalyst, catalysis, business.industry, Photovoltaic system, 021001 nanoscience & nanotechnology, Solar energy, electroreduction, Cathode, 0104 chemical sciences, Renewable energy, Anode, Chemical energy, water oxidation, 13. Climate action, cells, 0210 nano-technology, business, Efficient energy use
Abstract

Conversion of carbon dioxide into hydrocarbons using solar energy is an attractive strategy for storing such a renewable source of energy into the form of chemical energy (a fuel). This can be achieved in a system coupling a photovoltaic (PV) cell to an electrochemical cell (EC) for CO2 reduction. To be beneficial and applicable, such a system should use low-cost and easily processable photovoltaic cells and display minimal energy losses associated with the catalysts at the anode and cathode and with the electrolyzer device. In this work, we have considered all of these parameters altogether to set up a reference PV–EC system for CO2 reduction to hydrocarbons. By using the same original and efficient Cu-based catalysts at both electrodes of the electrolyzer, and by minimizing all possible energy losses associated with the electrolyzer device, we have achieved CO2 reduction to ethylene and ethane with a 21% energy efficiency. Coupled with a state-of-the-art, low-cost perovskite photovoltaic minimodule, this system reaches a 2.3% solar-to-hydrocarbon efficiency, setting a benchmark for an inexpensive all–earth-abundant PV–EC system. ISSN:0027-8424 ISSN:1091-6490

Published
2019

8. Molecular grafting on silicon anodes: artificial Solid-Electrolyte Interphase and surface stabilization

Author

Georges Caillon, Christian Jordy, Khalid Lahlil, Jean-Noël Chazalviel, Anne Chantal Gouget-Laemmel, Michel Rosso, Thierry Gacoin, François Ozanam, and Daniel Alves Dalla Corte

Subjects
Amorphous silicon, Materials science, Silicon, General Chemical Engineering, chemistry.chemical_element, 02 engineering and technology, Electrolyte, 010402 general chemistry, 021001 nanoscience & nanotechnology, Grafting, Electrochemistry, 01 natural sciences, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Chemical engineering, Monolayer, Electrode, Interphase, 0210 nano-technology
Abstract

Silicon electrodes represent a great potential on increasing the energy density of Li-ion batteries, but stabilization during cycling is an important issue to be solved for enabling a reliable application. Such stabilization has been sought for by surface grafting of hydrogenated amorphous silicon (a-Si:H) electrodes. Grafting a molecular monolayer of carboxydecyl moieties (acid grafting) or poly(oxoethylene) (PEG) chains decreases the irreversible capacity and stabilizes the solid-electrolyte interphase (SEI) on a-Si:H. FTIR spectroscopy confirms a breathing behavior of the SEI layer at each step of charge/discharge through in-situ experiments, but also shows that acid grafting reduces this behavior to a large extent. In this way, acid grafting decreases the amount of charge irreversibly consumed for the formation of a spontaneous SEI and stabilizes the SEI along the electrochemical cycles.

Published
2016

9. Lithiation Mechanism of Methylated Amorphous Silicon Unveiled by Operando ATR-FTIR Spectroscopy

Author

Jean-Noël Chazalviel, Michel Rosso, Bon Min Koo, Daniel Alves Dalla Corte, François Ozanam, Fouad Maroun, Laboratoire de physique de la matière condensée (LPMC), École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), and Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Amorphous silicon, Materials science, Renewable Energy, Sustainability and the Environment, Atr ftir spectroscopy, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Chemical engineering, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, General Materials Science, 0210 nano-technology, Mechanism (sociology), ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2018

10. Competition between Metal Dissolution and Gas Release in Li-Rich Li 3 Ru y Ir 1– y O 4 Model Compounds Showing Anionic Redox

Author

Quentin Jacquet, Gwenaëlle Rousse, Matthieu Saubanère, Antonella Iadecola, Jean-Marie Tarascon, Erik J. Berg, Marie-Liesse Doublet, Daniel Alves Dalla Corte, Louis Lemarquis, Collège de France - Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Paul Scherrer Institute (PSI), Chaire Chimie du solide et énergie, Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), and Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)

Subjects
Materials science, Absorption spectroscopy, 020209 energy, General Chemical Engineering, 02 engineering and technology, General Chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Electrochemistry, Mass spectrometry, Redox, Ultraviolet visible spectroscopy, Chemical engineering, 0202 electrical engineering, electronic engineering, information engineering, Materials Chemistry, Degradation (geology), [CHIM]Chemical Sciences, Density functional theory, 0210 nano-technology, Dissolution
Abstract

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.8b02955. Crystallographic data, additional Rietveld refinements, and EXAFS analysis (PDF) PDF cm8b02955_si_001.pdf (1.91 MB); International audience; Li-ion batteries have experienced tremendous progress over the past decade; however, their energy density should still be increased to power electric vehicles. Following this aim, the energy density of the cathode material can be drastically increased by making use of anionic redox, although it often comes along with material degradation. In this study, through a detailed analysis of the charge compensation mechanism of Li3RuO4 by online electrochemical mass spectrometry, X-ray absorption spectroscopy, and ultraviolet spectroscopy, we unveiled a new degradation mechanism for a cathode material showing anionic redox, namely the dissolution of Ru forming RuO4/RuO4– species with limited release of gas from the material. We show that this dissolution can be effectively tackled by substituting Ru with Ir. However, such a strategy leads to a massive increase in the release of O2 gas at the end of the charge. Density functional theory calculations prove that the relative stability of the end members RuO4 and IrO4 versus oxygen release is at the origin of this competition between metal dissolution and gas release.

Published
2018
Full Text
View/download PDF

11. Assessment of the Electrochemical Stability of Carbonate-Based Electrolytes in Na-Ion Batteries

Author

Nathalie Madern, Wei Yin, Guochun Yan, Jean-Marie Tarascon, Daniel Alves-Dalla-Corte, Grégory Gachot, Collège de France - Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL), Laboratoire réactivité et chimie des solides - UMR CNRS 7314 (LRCS), and Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Materials science, Renewable Energy, Sustainability and the Environment, 020209 energy, Inorganic chemistry, 02 engineering and technology, Electrolyte, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Electrochemistry, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, 0202 electrical engineering, electronic engineering, information engineering, Materials Chemistry, Carbonate, 0210 nano-technology
Abstract

International audience; The large abundance of Na combined with the feasibility of Na-based insertion compounds, such as Na3V2(PO4)(2)F-3, makes the Na-ion battery an attractive technology compared with Li-ion battery for a few applications. Nonetheless, one identified limitation of the Na3V2(PO4)(2)F-3/HC system is its poor long-term cycling performance at elevated temperature, hence the sorely need to screen the proper electrolyte formulation. Here, we report a thorough survey aiming to assess the pros and cons of cyclic vs. linear carbonates with respect to the performances of Na3V2(PO4)(2)F-3/HC cells. Through complementary in-situ UV and CV analytical techniques we reveal the formation of soluble species stemming from the partial decomposition of linear carbonates (DMC and EMC) in reduction into soluble products, hence stressing their failure to provide a stable solid electrolyte interphase (SEI) at the hard carbon electrode and by the same token accounting for the poor performance of the overall cell. We discuss the decomposition reaction paths, and propose a shuttle mechanism to account for the cell deterioration. Our results, which underscores the detrimental effects of linear carbonates in full Na-ion Na3V2(PO4)(2)F-3/HC cells, should serve as an impetus to identify superior electrolyte formulation for increasing the high temperature robustness of this technology. (C) 2018 The Electrochemical Society.

Published
2018

12. Methylated silicon: A longer cycle-life material for Li-ion batteries

Author

A. Cheriet, Daniel Alves Dalla Corte, Catherine Henry de Villeneuve, Noureddine Gabouze, Larbi Touahir, Aissa Keffous, Ionel Solomon, Michel Rosso, François Ozanam, Jean-Noël Chazalviel, Laboratoire de physique de la matière condensée (LPMC), and École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Amorphous silicon, Materials science, Silicon, Inorganic chemistry, Energy Engineering and Power Technology, chemistry.chemical_element, 02 engineering and technology, 010402 general chemistry, 7. Clean energy, 01 natural sciences, chemistry.chemical_compound, Plasma-enhanced chemical vapor deposition, [CHIM]Chemical Sciences, Electrical and Electronic Engineering, Physical and Theoretical Chemistry, ComputingMilieux_MISCELLANEOUS, Renewable Energy, Sustainability and the Environment, Nanocrystalline silicon, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Anode, Amorphous solid, Chemical engineering, chemistry, Electrode, 0210 nano-technology, Carbon
Abstract

Using Plasma Enhanced Chemical Vapor Deposition, one can prepare methylated amorphous silicon thin-layer anodes for Li-ion batteries exhibiting good cyclability. The properties of that material are investigated here in view of this target application. In comparison with pure amorphous silicon prepared in the same conditions, the improvement is twofold: longer lifetime, and capability of working with thicker electrodes. For example, capacity retention after 100 cycles of 150 nm thick layers with 10% carbon content is almost 70% larger than that of pure a-Si layers. The observed improvement is attributed to mechanical softening of amorphous Si by incorporation of CH3 groups.

Published
2013

13. A Fully Ordered Triplite, LiCuSO 4 F

Author

Marie-Liesse Doublet, Jean-Marie Tarascon, Meiling Sun, Gwenaëlle Rousse, Daniel Alves Dalla Corte, Saubanère Matthieu, Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Collège de France - Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Centre National de la Recherche Scientifique (CNRS), Laboratoire de physique de la matière condensée (LPMC), École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), ANR-12-PRGE-0005,HIPOLITE,Development of New High Voltage Positive Electrodes for Sustainable Li-Ion Batteries(2012), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Chaire Chimie du solide et énergie, Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Muséum national d'Histoire naturelle (MNHN)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), and Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)

Subjects
Materials science, General Chemical Engineering, Materials Chemistry, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, 0210 nano-technology, 01 natural sciences, ComputingMilieux_MISCELLANEOUS, 0104 chemical sciences
Abstract

International audience

Published
2016

14. Microsized Sn as Advanced Anodes in Glyme-Based Electrolyte for Na-Ion Batteries

Author

Gwena�lle Rousse, Daniel Alves Dalla Corte, Romain Dugas, Biao Zhang, Jean-Marie Tarascon, Dominique Foix, Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Aix Marseille Université (AMU)-Université de Pau et des Pays de l'Adour (UPPA)-Université de Nantes (UN)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Advanced Lithium Energy Storage Systems - ALISTORE-ERI (ALISTORE-ERI), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU), Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM), Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Collège de France - Chaire Chimie du solide et énergie, and Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Materials science, Na ion battery, Mechanical Engineering, Inorganic chemistry, chemistry.chemical_element, microsize, 02 engineering and technology, Electrolyte, electrolyte, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 7. Clean energy, 0104 chemical sciences, Anode, chemistry, Mechanics of Materials, Tin, Energy density, [CHIM]Chemical Sciences, General Materials Science, 0210 nano-technology, Carbon
Abstract

International audience; Microsized Sn presents stable cyclic performance in glyme-based electrolyte, which brings 19% increase in energy density of Sn/Na3V2(PO4)3 cells as compared to the cells using hard carbon anode. The Na[BOND]Sn intermediate phases are also clarified.

Published
2016

15. Area Effects on the Mott-Schottky Behavior of Anodic Films Formed on AISI 304 Stainless Steel

Author

Daniel Alves Dalla Corte, Luis Frederico Pinheiro Dick, and L. V. Taveira

Subjects
Materials science, Metallurgy, Mott schottky, Anode
Abstract

The electronic properties of thick oxide films formed on AISI 304L by hot acid anodizing was investigated using the Mott-Schottky approach. All modified films showed n-type and p-type behavior, depending on the applied potential. The incorporation of molybdate and niobil oxalate during the anodization affected mainly the acceptor concentration. The apparent increase in the dopant concentrations is mainly explained by surface area increase associated to the treatments.

Published
2010

16. Spectroscopic Insight into Li-Ion Batteries during Operation: An Alternative Infrared Approach

Author

Christian Jordy, Georges Caillon, François Ozanam, Daniel Alves Dalla Corte, Jean-Noël Chazalviel, and Michel Rosso

Subjects
Amorphous silicon, Materials science, Silicon, Renewable Energy, Sustainability and the Environment, Analytical chemistry, Infrared spectroscopy, chemistry.chemical_element, 02 engineering and technology, Electrolyte, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Chemical engineering, Phase (matter), Electrode, General Materials Science, Lithium, 0210 nano-technology, Absorption (electromagnetic radiation)
Abstract

Multiple-internal-reflection infrared spectroscopy allows for the study of thin-film amorphous silicon electrodes in situ and in operando, in conditions typical of those used in Li-ion batteries. It brings an enhanced sensitivity, and the attenuated-total-reflection geometry allows for the extraction of quantitative information. When electrodes are cycled in representative electrolytes, the simultaneously recorded infrared spectra give an insight into the solid/electrolyte interphase (SEI) composition. They also unravel the dynamic behavior of this SEI layer by quantitatively assessing its thickness, which increases during silicon lithiation and partially decreases during delithiation. Li-ion solvation effects in the vicinity of the electrode indicate that lithium incorporation in the solid phase is the rate-determining step of the electrochemical processes during lithiation. The lithiation of the active material also results in the irreversible consumption of a large quantity of hydrogen in the pristine material. Finally, the evolution of the electronic absorption of the electrode material suggests that lithium diffusion is much easier after the first lithiation than in the pristine material. Therefore, in situ Fourier-transform infrared spectroscopy performed in a well-suited configuration efficiently extracts original and quantitative pieces of information on the surface and bulk phenomena affecting Li-ion electrodes during their operation in realistic conditions.

Published
2015

17. Selective Dissolution of Ni from Nitinol for Increasing the Biocompatibility

Author

Daniel Alves Dalla Corte and Luis Frederico Pinheiro Dick

Subjects
Materials science, Biocompatibility, Scanning electron microscope, Alloy, chemistry.chemical_element, Electrolyte, Shape-memory alloy, engineering.material, Corrosion, Nickel, chemistry, Chemical engineering, engineering, Dissolution
Abstract

Different electrochemical surface treatments were applied to the Ni-Ti shape memory alloy and to pure Ti and Ni for comparison. Electrolytes containing complexing ions, as F- or Cl-, produced localized corrosion on Ni-Ti. However, by Rutherford backscattering spectroscopy and scanning electron microscopy a loss of nickel and morphological modifications of the surface were verified for Ni-Ti polarized in 1M H3PO4 or 1M H2SO4. Corrosion resistance improvement in Hank's solution was observed for the Ni-Ti alloy polarized at 3V in 1M H3PO4.

Published
2007

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