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Within the perspective of the current and future space missions, the detection and separation of building blocks such as amino acids are important subjects which are becoming fundamental in the search for the origin of life and traces of life in the solar system. In this work, we have developed and optimized a strategy adapted to space experimentation to detect the presence of amino acid-like compounds using gas chromatography coupled to mass spectrometry (GC-MS). Selected derivatization methods meet the instrument design constraints imposed on in situ extraterrestrial experiments. Coupled to a fast selective extraction, GC analysis would be highly efficient for the detection of organic materials. In the future, the corresponding GC-MS TIC could facilitate simple and fast selection of sediments/dust samples onboard GC-MS-equipped rovers for sample return-to-Earth missions. [ABSTRACT FROM AUTHOR]

Mass spectrometry (MS) has played a remarkable role in exploring the chemical make‐up of our solar system. In situ probes were historically developed to analyze inorganic/elemental compositions while leveraging native ions or harsh ionization methods to aid in exploring astrophysics applications (e.g., heliophysics). The part played by MS is demonstrated in a majority of scientific payloads focused on exploration, particularly at the turn of the century with missions including Cassini‐Huygens, Rosetta, and now Mars Science Laboratory. Plasma mass spectrometers have grown more sophisticated to interrogate fundamental inorganic analysis (e.g., solar wind and magnetospheres) including both native ions and neutrals. Cosmic dust floating in‐between and orbiting planetary bodies has been targeted by unique sampling via impact ionization. More complex systems rely on landed planetary instrumentation with lessons learned from pioneering missions in the 1970s and 1980s to near neighbors Mars and Venus. Modern probes have expanded applicable target chemicals by recognizing the needs to provide for molecular analyses, extended mass range, and high resolution to provide unequivocal detection and identification. Notably, as the field surrounding astrobiology has gained momentum, so has the in situ detection of complex molecular chemistry including the chemical evolution of organic molecules. Mission context often includes long term timelines from spacecraft launch to arrival and additionally the diverse target environments across various planets. Therefore, customized experimental designs for space MS have been born of necessity. To this point, the development of MS instrumentation on Earth has now far outpaced development for experiments in space. Therefore, exciting developments lie ahead among various international space agencies conducting current and future mission planning with increasingly enhanced instrumentation. For instance, near‐neighbor Mars has entertained considerable attention with complex MS instrumentation with laser desorption ionization aboard the Mars Organic Molecule Analyzer instrument. To study comets, the Rosetta mission employs a secondary ionization mechanism. Meanwhile, the various moons of Jupiter and Saturn have intriguing surface and subsurface properties that warrant more advanced analyzer systems. Instrumentation design will continue to evolve as requirements develop and this review serves as a reflection of the contribution of in situ MS to space exploration in the past 20 years and the anticipated contribution yet to come. © 2020 John Wiley & Sons Ltd. Mass Spec Rev [ABSTRACT FROM AUTHOR]

So far no designated mission to either of the two ice giants, Uranus and Neptune, exists. Almost all of our gathered information on these planets comes from remote sensing. In recent years, NASA and ESA have started planning for future mission to Uranus and Neptune, with both agencies focusing their attention on orbiters and atmospheric probes. Whereas information provided by remote sensing is undoubtedly highly valuable, remote sensing of planetary atmospheres also presents some shortcomings, most of which can be overcome by mass spectrometers. In most studies presented to date a mass spectrometer experiment is thus a favored science instrument for in situ composition measurements on an atmospheric probe. Mass spectrometric measurements can provide unique scientific data, i.e., sensitive and quantitative measurements of the chemical composition of the atmosphere, including isotopic, elemental, and molecular abundances. In this review paper we present the technical aspects of mass spectrometry relevant to atmospheric probes. This includes the individual components that make up mass spectrometers and possible implementation choices for each of these components. We then give an overview of mass spectrometers that were sent to space with the intent of probing planetary atmospheres, and discuss three instruments, the heritage of which is especially relevant to Uranus and Neptune probes, in detail. The main part of this paper presents the current state-of-art in mass spectrometry intended for atmospheric probe. Finally, we present a possible descent probe implementation in detail, including measurement phases and associated expected accuracies for selected species. [ABSTRACT FROM AUTHOR]

Plain Language Summary: Miller et al. [2015, https://doi.org/10.1002/2015JE004825] described the result of experiments testing the potential of Tenax TA, a polymer used on Sample Analysis at Mars (SAM), as a source of chlorinated benzene. Miller et al. [2015] conclude that the amount of chlorobenzene produced is low and that Tenax TA cannot be the source of the chlorobenzene observed on Mars by SAM. Miller et al. [2015] did not provide the identification of two unknown compounds produced during these pyrolysis experiments, though their abundance is orders of magnitude higher than that of chlorobenzene. Here, we tentatively identify these compounds based on the mass spectra provided by Miller et al. [2015], the most abundant of which is a chlorinated monomer of Tenax TA. This chlorinated monomer is likely to accumulate in the hydrocarbon Tenax trap and in the transfer line between the trap and the mass spectrometer. Further breakdown of these compounds could lead the high background of chlorobenzene observed on Mars. Key Points: Unknown compounds of Miller et al. [2015] are tentatively identified as rearranged monomers and chlorinated monomers of the Tenax TAThe chlorinated monomer is two orders of magnitude more abundant than chlorobenzene produced in the same experimentsChlorobenzene moieties of chlorinated Tenax TA monomers could provide high backgrounds during analysis of Mars samples by SAM's GC‐MS [ABSTRACT FROM AUTHOR]

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Mass spectrometry (MS) can become a potentially useful instrument type for aerosol, droplet and fomite (ADF) contagion surveillance in pandemic outbreaks, such as the ongoing SARS-CoV-2 pandemic. However, this will require development of detection protocols and purposing of instrumentation for in situ environmental contagion surveillance. These approaches include: (1) enhancing biomarker detection by pattern recognition and machine learning; (2) the need for investigating viral degradation induced by environmental factors; (3) representing viral molecular data with multidimensional data transforms, such as van Krevelen diagrams, that can be repurposed to detect viable viruses in environmental samples; and (4) absorbing engineering attributes for developing contagion surveillance MS from those used for astrobiology and chemical, biological, radiological, nuclear (CBRN) monitoring applications. Widespread deployment of such an MS-based contagion surveillance could help identify hot zones, create containment perimeters around them and assist in preventing the endemic-to-pandemic progression of contagious diseases. [ABSTRACT FROM AUTHOR]

Martian meteorites are the only samples from Mars available for extensive studies in laboratories on Earth. Among the various unresolved science questions, the question of the Martian atmospheric composition, distribution, and evolution over geological time still is of high concern for the scientific community. Recent successful space missions to Mars have particularly strengthened our understanding of the loss of the primary Martian atmosphere. Noble gases are commonly used in geochemistry and cosmochemistry as tools to better unravel the properties or exchange mechanisms associated with different isotopic reservoirs in the Earth or in different planetary bodies. The relatively low abundance and chemical inertness of noble gases enable their distributions and, consequently, transfer mechanisms to be determined. In this review, we first summarize the various in situ and laboratory techniques on Mars and in Martian meteorites, respectively, for measuring noble gas abundances and isotopic ratios. In the second part, we concentrate on the results obtained by both in situ and laboratory measurements, their complementarity, and the implications for the Martian atmospheric dynamic evolution through the last billions of years. Here, we intend on demonstrating how the various efforts established the Mars-Martian meteorites connection and its significance to our understanding of the red planet. [ABSTRACT FROM AUTHOR]

The search for biomarkers in our solar system is a fundamental challenge for the space research community. It encompasses major difficulties linked to their very low concentration levels, their ambiguous origins (biotic or abiotic), as well as their diversity and complexity. Even if, in 40 years' time, great improvements in sample pre-treatment, chromatographic separation and mass spectrometry detection have been achieved, there is still a need for new in situ scientific instrumentation. This work presents an original liquid chromatographic system with a trapping unit dedicated to the one-pot detection of a large set of non-volatile extra-terrestrial compounds. It is composed of two units, monitored by a single pump. The first unit is an online trapping unit able to trap polar, apolar, monomeric and polymeric organics. The second unit is an online analytical unit with a high-resolution Q-Orbitrap mass spectrometer. The designed single pump system was as efficient as a laboratory dual-trap LC system for the analysis of amino acids, nucleobases and oligopeptides. The overall setup significantly improves sensitivity, providing limits of detection ranging from ppb to ppt levels, thus meeting with in situ enquiries. [ABSTRACT FROM AUTHOR]