1. Elasticity of ε-FeOOH: Seismic implications for Earth's lower mantle.
- Author
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Thompson, E. C., Campbell, A. J., and Tsuchiya, J.
- Abstract
We have calculated the structure and elasticity of low-spin ferromagnetic ε-FeOOH to 140 GPa using density functional theory calculations with a Coulombic self-interaction term ( U). Using these data, the elastic moduli and sound velocities of ε-FeOOH were calculated across the pressure stability of the hydrogen bond symmetrized structure (30 to 140 GPa). The obtained values were compared with previously published values for phase H (MgSiH2O4) and δ-AlOOH, which likely form a solid solution with ε-FeOOH. In contrast to these Mg and Al end-members, ε-FeOOH has smaller diagonal and larger off-diagonal elastic constants, leading to an eventual negative pressure dependence of its shear wave velocity. Because of this behavior, iron-enriched solid solutions from this system have smaller shear wave velocities than surrounding mantle and therefore are a plausible contributor to large low-shear velocity provinces (LLSVPs) which exhibit similar seismic properties. Additionally, ε-FeOOH has substantial shear wave polarization anisotropy. Consequently, if iron-rich solid solutions from the FeOOH-AlOOH-MgSiH2O4 system at the core-mantle boundary exhibit significant lattice-preferred orientation due to the strong shear stresses which occur there, it may help explain the seismically observed S H > S V anisotropy in this region. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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