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We present a spatial analysis of volcano distribution and morphology in the young, intraoceanic Mariana Arc. Both the quality of fit to idealized models and the divergence from those ideals indicate that Mariana Arc volcanoes are arranged into five great circle segments, rather than a single small circle or multiple small circles. The alignment of magmatic centers suggests that magma transport is controlled by the stress regime in the deep crust and/or lithospheric mantle of the Philippine Sea Plate, into which the arc is emplaced, and that arc-normal tension is the dominant process operating in the deep lithosphere along the whole arc. Volcano morphologies indicate that the stress regime in the shallow crust varies between arc-normal tension and compression, which also implies that the stress field can vary with depth in the arc lithosphere. We show that this horizontal and vertical stress partitioning can be related to the changing dip of the subducting plate and the breadth of the zone where it is coupled with the overriding plate. The variation in stress regime is consistent with both the distribution of seismicity in the Philippine Sea Plate and with the structural fabrics of the nonvolcanic part of the plate margin to the south. Our analysis suggests that the upper plate exerts the principal control on the distribution of volcanoes in the Mariana Arc. Where tension in the deeper parts of arc lithosphere is sufficiently concentrated, then a distinct volcanic front is produced. [ABSTRACT FROM AUTHOR]

New 40Ar/39Ar ages are presented for volcanic rocks from the Karacadağ Volcanic Complex (KVC) in SE Anatolia. These extend the oldest age recognised for the KVC for lavas from the Siverek Phase plateau basalt back to at least 17 Ma. Our data agree with prior studies that the second, Karacadağ Phase of igneous activity began at about 4.5 Ma with a peak between 2 and 1 Ma, but in contrast to previous work we find that this included volcanism on the Mt. Karacadağ ridge from the earliest part of this phase. Construction of the Mt. Karacadağ ridge coincided with development of the prominent east-west striking Abd El Aziz and Sinjar compressional antiforms, which lie approximately 100 km to the south. These provide complementary evidence for the orientation of compressional deformation across a broad zone of the leading edge of the Arabian Plate as it collided with Anatolia between 4 and 1 Ma. The new data also indicate that the compression-aligned deformation of the foreland magmatism may have permitted tapping of melts from greater depth in the probably asthenospheric mantle than occurred prior to 4 Ma. However, magmas from throughout the history of the KVC contain some components derived from the lithospheric mantle. [ABSTRACT FROM AUTHOR]

Pliocene to Quaternary magmatism in the Karacadağ Volcanic Complex in SE Turkey occurred in the foreland region of the Arabia–Eurasia collision and can be divided into two phases. The earlier Karacadağ phase formed a north–south-trending volcanic ridge that erupted three groups of lavas. The same range of mantle sources contributed to the younger Ovabağ phase lavas, which were erupted from monogenetic cones to the east of the Karacadağ fissure. As at several other intraplate localities across the northern Arabian Plate this magmatism represents mixtures of melt from shallow, isotopically enriched mantle and from deeper, more depleted mantle. The deep source is similar to the depleted mantle invoked for other northern Arabian intraplate volcanic fields but at Karacadağ this source contained phlogopite. This source could be located in the shallow convecting mantle or may represent a metasomatic layer in the base of the lithosphere. There is no evidence for a contribution from the Afar mantle plume, as has been proposed elsewhere in northern Arabia. Melting during the Karacadağ and Ovabağ phases could have resulted from a combination of upwelling beneath weak or thinned lithosphere and restricted local extension of that weakened lithosphere as it collided with Eurasia. Tension associated with the collision focused magma of the Karacadağ phase into the elongate shield volcano of Mt. Karacadağ. The northern end of the fissure accommodated more extensive differentiation of magma, with isolated cases of crustal contamination, consistent with greater stress in the lithosphere closest to the collision. Most magma batches of the Karacadağ and Ovabağ phases differentiated by fractional crystallization at ∼5 MPa, near the boundary between the upper and lower crust. Magma batches dominated by melt from garnet lherzolite show evidence for restricted amounts of differentiation at ∼22·5 MPa, which is close to the base of the lithospheric mantle. [ABSTRACT FROM AUTHOR]

The Gede Volcanic Complex (GVC) of the Sunda island arc (West Java, Indonesia) consists of multiple volcanic centres and eruptive groups with complex magmatic histories. We present new petrological, mineralogical, whole-rock major and trace element and Sr–O isotopic data to provide constraints on the relative importance of fractional crystallisation and magma mixing in petrogenesis, as well as on the role and nature of the arc crust. Banded juvenile scoria from Young and Old Gede provide unequivocal evidence for the (late-stage) interaction of distinct magmas at Gede volcano. However, the relatively small-degree compositional zoning observed in plagioclase phenocrysts of all eruptive groups (up to ~20 mol% An) may be attributed to physical changes in magma properties (e.g. P, T, and PH2O) rather than changes in melt composition. Major element and trace element variations within each eruptive series are inconsistent with magmatic evolution through simple mixing processes. Instead, mixing of variably fractionated magma batches is suggested to account for the significant scatter in some element variation diagrams. No correlation is observed between textural complexity and/or mineral disequilibrium and whole-rock geochemistry. REE data and geochemical modelling indicate that fractional crystallisation involving amphibole in the mid- to lower crust, and fractionation of plagioclase, clinopyroxene, Fe–Ti oxide ± olivine ± orthopyroxene provide strong control on the geochemical evolution of GVC rocks. Two-pyroxene geothermobarometry provides pre-eruption crystallisation temperatures of 891–1,046°C and pressures of 3.4–6.5 kbar, equivalent to ~13–24 km depth beneath the volcanoes (mid- to lower crust). Low, mantle-like clinopyroxene δ18O values of GVC lavas and poor correlation of Sr isotope ratios with indices of differentiation precludes significant assimilation of isotopically distinct crust during magmatic differentiation. Therefore, we suggest that the geochemical character of the moderately thick West Javan arc crust is relatively immature compared to typical continental crust. Trace element ratios and strontium isotopes show that the magmatic source composition of the older geographical units, Gegerbentang and Older Quaternary, is distinct from the other GVC groups. [ABSTRACT FROM AUTHOR]

Abstract: New analyses of major and trace element concentrations and Sr, Nd and Pb isotopic ratios are presented for Plio-Pleistocene basalts and basaltic andesites from the Semporna peninsula in Sabah, Borneo, at the southern end of the Sulu Arc. Depletion of high field strength elements (HFSE), which is characteristic of many subduction-related magmatic suites, is present in more evolved Semporna rocks but is associated with radiogenic Sr and Pb, and less radiogenic Nd isotopic ratios and results from contamination of mafic melt by, possibly ancient, crustal basement. The most mafic lavas from Semporna, and elsewhere in the Sulu Arc, display no HFSE depletion relative to other elements with similar compatibility. High-Nb basalt from Semporna formed when mantle resembling the source of Ocean Island Basalt (OIB) upwelled into lithospheric thin spots created during earlier subduction. This mantle did not experience enrichment by fluids or melt derived from subducted crust. The presence of similar lavas throughout the Sulu Arc and around the South China Sea suggests that the OIB-like component resides in the convecting upper mantle. Depletion of light rare earth elements, with respect to other incompatible elements, throughout the Sulu Arc could result from melt–mantle interaction during magma transport through the lithosphere. Such depletion is absent in suites from the South China Sea, where magma probably migrated along large, lithosphere-penetrating structures. Semporna high-Nb basalts are not associated with adakitic magmatism which is a frequent, but not ubiquitous, association in some active subduction zones. Both geochemical signatures are developed early in the history of a melt pulse, either in the source (high-Nb basalt) or during deep differentiation (adakite). Preservation of these distinctive geochemical signatures is favoured in settings that minimise (1) interaction with other, more copious melt types, and/or (2) subsequent differentiation in the shallow crust. Where found, the high-Nb basalt–adakite association is a result of transport through favourable lithospheric conditions and not due to any link between their mantle sources. [Copyright &y& Elsevier]

The Philippine Trench marks a nascent plate margin where subduction initiation is propagating from north to south. Magma compositions in the East Philippine Arc record thinning of arc lithosphere as it is eroded from below. Lithosphere is thicker beneath the younger, southern part of the arc, causing basaltic magma to stall and fractionate garnet at high pressure. In the mature, northern section, basaltic magma differentiates at shallower levels, at pressures where garnet is not stable. Local variations in lithosphere thickness suggest that thinning is rapid and may be piecemeal. Fluctuations in arc lithosphere thickness throughout the history of this margin appear to control spatial and temporal variations in magma fluxes into the arc crust. Varying fractionation depths of hydrous basalt may help to explain the andesitic composition of bulk continental crust. [ABSTRACT FROM AUTHOR]

Abstract: New geochemical data for Pleistocene magmatic rocks from the Surigao peninsula, eastern Mindanao, the Philippines, demonstrate typical adakitic traits, including elevation of Sr/Y and depletion of the heavy rare earth elements. 87Sr/ 86Sr and 143Nd/ 144Nd ratios of the adakites do not support melting of the subducted Philippine Sea Plate but resemble Pliocene arc lavas generated in the same subduction zone. Excepting the heavy rare earth elements, the adakites and arc lavas also possess similar ratios of incompatible elements suggesting that the adakites were ultimately derived from melting of the mantle wedge. The wide range of SiO2 in the adakites and its strong correlation with trace element concentrations and ratios indicate two possible mechanisms for generating the adakitic signature. (1) Adakitic melt was produced from basaltic arc magma by fractional crystallisation of a garnet-bearing assemblage. (2) Solidified basaltic rock containing garnet melted to yield adakitic magma. In either case the basaltic precursor was generated from fluid-modified mantle then differentiated within the garnet stability field. In Surigao this requires differentiation within mantle. The Surigao example suggests that any subduction zone has the potential to produce adakitic magma if basalt crystallises at sufficient depth. This has important implications for the geodynamics of modern and ancient subduction zones that have generated similar rocks. [Copyright &y& Elsevier]

Abstract: New helium and oxygen isotope data and trace element concentrations are reported for volcanic rocks from central Iceland. Basalts that are depleted in the most incompatible trace elements possess a wide range in 3He/4He but most ratios are similar to or higher than those of mid-ocean ridge basalt (MORB:∼8R A[1] [D.W. Graham, Noble gas geochemistry of mid-ocean ridge and ocean island basalts: characterisation of mantle source reservoirs, in: D.P. Porcelli, C.J. Ballentine, R. Wieler (Eds.), Noble gases in Geochemistry and Cosmochemistry, Rev. Mineral. Geochem., vol. 47, 2002, pp. 247–317]). The low concentrations of helium in these rocks suggest that significant degassing has made them susceptible to contamination by low-3He/4He crust, therefore all measured 3He/4He are considered minimum estimates for their sources. Elevated helium isotope ratios in the source of these rocks result from interaction with high-3He/4He mantle. The highest oxygen isotope ratios in the depleted rocks are similar to those in melts from typical depleted upper mantle and the range of δ 18O values is consistent with variable, limited amounts of contamination by Icelandic crust. Most of the incompatible trace element-enriched rocks possess 3He/4He ratios that are similar to or lower than those in MORB. These rocks were erupted close to the postulated centre of the Iceland plume. This observation contradicts models in which high-3He/4He characterises the focus of mantle upwelling. A source with MORB-like 3He/4He ratios may also be common to other parts of the North Atlantic Igneous Province. The highest δ 18O values in the enriched rocks are lower than those in MORB and do not appear to have been affected by interaction with low-δ 18O Icelandic crust. Recycling of hydrothermally altered oceanic crust that has been subducted into the mantle provides a plausible mechanism for generating an 18O-poor source with the trace element and isotopic characteristics of the enriched lavas. [Copyright &y& Elsevier]