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Ash emission in explosive silicic eruptions can have widespread impacts for human health, agriculture, infrastructure, and aviation. Estimates of the total grainsize distribution (TGSD) generated during explosive magma fragmentation underpins eruption models and ash dispersal forecasts. Conventionally, the TGSD constrained via erupted deposits is assumed to match the TGSD produced at explosive fragmentation. Here we present observations from within the vent of a recent rhyolitic eruption (Cordón Caulle, Chile, 2011–2012), demonstrating that fine (<63 μm diameter) and ultra-fine (<2.5 μm diameter) ash particles are captured and sintered to fracture surfaces, and thus sequestered in the shallow subsurface, rather than emitted. We establish a conceptual model—uniquely contextualised through a combination of syn-eruptive observations and detailed post-eruption field investigation—in which turbophoresis (particle migration towards zones of lower turbulence) and rapid sintering create an inverse relationship between particle size and the probability of its subsurface capture. Such size-dependent capture efficiency preferentially removes submicron-diameter ash from the erupted componentry, decoupling the erupted size distribution from magmatic source conditions and potentially playing an important role in modulating eruption dynamics. Here the authors document evidence of ultrafine ash captured within ash-venting nozzles at Cordón Caulle volcano (Chile). This decouples eruptive processes from the emitted products, as explained by a new model of in-vent ash migration and sticking. [ABSTRACT FROM AUTHOR]

The caldera-forming Samalas eruption of the Samalas–Rinjani volcanic complex on Lombok, Indonesia, in 1257 CE ranks as one of the most explosive and sulphur-rich eruptions of the past thousand years. Along with other significant events (e.g. Tambora 1815, El Chichón 1982), Samalas 1257 forms a class of powerful eruptions of magmas of intermediate alkaline composition, which remain relatively understudied. This study aims to better understand the pre-eruptive magma reservoir conditions and volatile storage capacities of intermediate alkaline systems, using the 1257 Samalas eruption as a case study. Systematic partial-equilibrium experiments were run to constrain potential magma reservoir conditions (25–200 MPa and 850–1000°C) by examining changes in the chemistry and textures of experimental glass and mineral products. Natural trachydacite pumice from the 1257 Samalas eruption was used as the experimental charge for a series of water-saturated experiments run in cold-seal pressure vessels, buffered at an oxygen fugacity ƒ O2 of NNO/NNO + 1 log units. Assessing the match between natural and experimental glass compositions and mineral phases and textures reveals that pre-eruptive magma reservoir conditions were between 875°C and 930°C and ca. 100–150 MPa (4.5 ± 1km depth). Breakdown of experimental amphibole at pressures below 75 MPa, and plagioclase instability at 950°C/100 MPa, provide the strongest constraints on phase stabilities that are consistent with the magma storage region. In the observed temperature and pressure range, the natural compositions of plagioclase, amphibole and orthopyroxene are replicated in experimentally precipitated rims. Clinopyroxene and high anorthite plagioclase (An>64) in the natural mineral assemblage could not be replicated in the experiments, implying that these compositions most likely did not grow in the shallow pre-eruptive reservoir of Mt Samalas. The pre-eruptive storage depths of trachydacite magma are significantly shallower than the postulated magma storage at the currently active basaltic-andesite magmatic system at Rinjani, and thus monitoring magma storage depth may be a useful indicator of changing magma composition in the future. Our findings show that highly explosive VEI 7 eruptions of intermediate alkaline magma can be fed from a relatively limited range of storage pressures (100–150 MPa), suggesting accumulation of magma in one place, rather than the rapid extraction of magma from a vertically extensive, transcrustal magma system. [ABSTRACT FROM AUTHOR]

Understanding the conditions that culminate in explosive eruptions of silicic magma is of great importance for volcanic hazard assessment and crisis mitigation. However, geological records of active volcanoes typically show a wide range of eruptive behavior and magnitude, which can vary dramatically for individual eruptive centers. In order to evaluate possible future scenarios of eruption precursors, magmatic system variables for different eruption types need to be constrained. Here we use petrological experiments and microanalysis of crystals to clarify the P – T – x state under which rhyodacitic melts accumulated prior to the H3 eruption; the largest Holocene Plinian eruption of Hekla volcano in Iceland. Cobalt-buffered, H 2 O-saturated phase equilibrium experiments reproduce the natural H3 pumice phenocryst assemblage (pl > fa + cpx > ilm + mt > ap + zrc) and glass chemistry, at 850 ± 15 °C and P H 2 O of 130 to 175 MPa, implying shallow crustal magma storage between 5 and 6.6 km. The systematics of FeO and anorthite (CaAl 2 Si 2 O 8 ) content in plagioclase reveal that thermal gradients were more important than compositional mixing or mingling within this magma reservoir. As these petrological findings indicate magma storage much shallower than is currently thought of Hekla's mafic system, we use the constrained storage depth in combination with deformation modeling to forecast permissible surface uplift patterns that could stem from pre-eruptive magma intrusion. Using forward modeling of surface deformation above various magma storage architectures, we show that vertical surface displacements caused by silicic magma accumulation at ∼6 km depth would be narrower than those observed in recent mafic events, which are fed from a lower crustal storage zone. Our results show how petrological reconstruction of magmatic system variables can help link signs of pre-eruptive geophysical unrest to magmatic processes occurring in reservoirs at shallow depths. This will enhance our abilities to couple deformation measurements (e.g. InSAR and GPS) to petrological studies to better constrain potential precursors to volcanic eruptions. [ABSTRACT FROM AUTHOR]

Magma reservoirs underneath volcanoes grow through episodic emplacement of magma batches. These pulsed magma injections can substantially alter the physical state of the resident magma by changing its temperature, pressure, composition, and volatile content. Here we examine plagioclase phenocrysts in pumice from the 2014 Plinian eruption of Kelud (Indonesia) that record the progressive capture of small melt inclusions within concentric growth zones during crystallization inside a magma reservoir. High-spatial-resolution Raman spectroscopic measurements reveal the concentration of dissolved H2O within the melt inclusions, and provide insights into melt-volatile behavior at the single crystal scale. H2O contents within melt inclusions range from ~0.45 to 2.27 wt% and do not correlate with melt inclusion size or distance from the crystal rim, suggesting that minimal H2O was lost via diffusion. Instead, inclusion H2O contents vary systematically with anorthite content of the host plagioclase (R2 = 0.51), whereby high anorthite content zones are associated with low H2O contents and vice versa. This relationship suggests that injections of hot and H2O-poor magma can increase the reservoir temperature, leading to the dilution of melt H2O contents. In addition to recording hot and H2O-poor conditions after these injections, plagioclase crystals also record relatively cold and H2O-rich conditions such as prior to the explosive 2014 eruption. In this case, the elevated H2O content and increased viscosity may have contributed to the high explosivity of the eruption. The point at which an eruption occurs within such repeating hot and cool cycles may therefore have important implications for explaining alternating eruptive styles. [ABSTRACT FROM AUTHOR]

The original version of this Article contained an error in the Acknowledgement Section, which incorrectly read "The authors thank N. Perez and M. Pankhurst for a sample permit". The original article can be found online at https://doi.org/10.1038/s41467-022-30905-4. [Extracted from the article]

In June 2011, an eruption of rhyolite magma began at the Puyehue–Cordón Caulle volcanic complex, southern Chile. By January 2012, explosive activity had declined from sustained pyroclastic (Plinian to sub-Plinian) fountaining to mixed gas and ash jetting punctuated by Vulcanian blasts. This explosive activity was accompanied by synchronous effusion of obsidian lava in a hybrid explosive–effusive eruption. Fortuitous climatic conditions permitted ground-based observation and video recording of transient vent dynamics as well as real-time collection of proximal juvenile ash as it sedimented from the active plume. The main eruptive vent complex and site of lava effusion were represented by two loci of Vulcanian blasts within a single tephra cone containing a pancake-shaped proto-lava dome. These blast loci each consisted of clusters of sub-vents that expressed correlated shifts in eruption intensity, indicating the presence of partially connected and/or branching zones of high permeability within the upper conduit. Pyroclast textures were examined by X-ray computed microtomography and their permeability was modelled by lattice Boltzmann simulations. The porosity (39 to 67%) and Darcian permeability (3.1×10−15 m2 perpendicular to fabric to 3.8×10−11 m2 parallel to fabric) of fine ash emitted during ash jetting indicate that the permeable zones comprised highly sheared, tube-like bubbly magma, and contrast with the low porosity (~17%) and nul permeability of bombs ejected to hundreds of metres from the vent in Vulcanian blasts. Residual H2O content of ash (0.14wt.%) and two bombs (0.2–0.25wt.%), determined by Karl–Fischer titration indicate degassing of this pyroclastic material to near-atmospheric pressures. Ash textures and simple degassing/vesiculation models indicate the onset of permeability by ductile processes of shear-enhanced bubble coalescence in the upper 1 to 1.5km of the conduit. Repeated ash jetting and Vulcanian blasts indicate that such ductile processes were not sufficiently effective to accommodate all degassing requirements, and additional brittle (e.g., fragmentation) events transiently assisted in maintaining an open-system degassing regime that permitted long-lived, hybrid explosive–effusive activity. The eruption at Cordón Caulle has provided an excellent opportunity to closely observe key processes of silicic volcanism. [ABSTRACT FROM AUTHOR]

Abstract: Explosive volcanic eruptions of silicic magma often evolve towards non-explosive emissions of lava. The mechanisms underlying this transition remain unclear, however, a widely cited idea holds that shear-induced magma fragmentation plays a critical role by fostering volatile loss from fragmentary magma and through ash-filled cracks termed tuffisite. We test this hypothesis by measuring H2O concentrations within glassy tuffisite from the 2008–2011 rhyolitic eruption at volcán Chaitén, Chile. We show that while H2O concentrations decrease next to tuffisite veins and at the margins of obsidian fragments, the depletions cannot account for the disparity in H2O between explosively and effusively erupted rhyolite. Tuffisite vein lifetimes derived from diffusion modeling (min to h) imply degassing rates that are too slow to effectively degas magma, unless the magma was entirely fragmented to mm or smaller particles. This level of brecciation may locally develop near conduit margins, but is unrealistic for entire conduits. The primary role of melt fracturing may therefore be to provide gas-escape pathways for more efficient degassing of permeable vesicular magma in the conduit interior. [Copyright &y& Elsevier]

Rhyolite magma has fuelled some of the Earth’s largest explosive volcanic eruptions. Our understanding of these events is incomplete, however, owing to the previous lack of directly observed eruptions. Chaitén volcano, in Chile’s northern Patagonia, erupted rhyolite magma unexpectedly and explosively on 1 May 2008 (ref. 2). Chaitén residents felt earthquakes about 24 hours before ash fell in their town and the eruption escalated into a Plinian column. Although such brief seismic forewarning of a major explosive basaltic eruption has been documented, it is unprecedented for silicic magmas. As precursory volcanic unrest relates to magma migration from the storage region to the surface, the very short pre-eruptive warning at Chaitén probably reflects very rapid magma ascent through the sub-volcanic system. Here we present petrological and experimental data that indicate that the hydrous rhyolite magma at Chaitén ascended very rapidly, with velocities of the order of one metre per second. Such rapid ascent implies a transit time from storage depths greater than five kilometres to the near surface in about four hours. This result has implications for hazard mitigation because the rapidity of ascending rhyolite means that future eruptions may provide little warning. [ABSTRACT FROM AUTHOR]

Rhyolitic eruptions often begin explosively and then shift to extrusions of lava. It is widely believed that the style of eruption is dependent on magma flow rate within the conduit, with fast ascent leading to explosive eruption and slow ascent favoring effusive behavior. Currently, the velocity of rhyolite magma flowing in a conduit is unknown, and therefore eruption models remain untested against geologic evidence of magma ascent. We show that explosively erupted rhyolite magma from the Inyo volcanic chain ascended slowly (centimeters per second), at the same rates as the dome-building phases. We propose that the explosive-effusive transition in sub-Plinian rhyolite eruptions is governed by the alleviation of exsolved volatile pressure in the shallow conduit rather than the magma flow rate. [ABSTRACT FROM AUTHOR]

Understanding lava flow processes is important for interpreting existing lavas and for hazard assessments. Although substantial progress has been made for basaltic lavas our understanding of silicic lava flows has seen limited recent advance. In particular, the formation of lava flow breakouts, which represent a characteristic process in coolinglimited basaltic lavas, but has not been described in established models of rhyolite emplacement. Using data from the 2011-2012 rhyolite eruption of Puyehue-Cordón Caulle, Chile, we develop the first conceptual framework to classify breakout types in silicic lavas, and to describe the processes involved in their progressive growth, inflation, and morphological change. By integrating multiscale satellite, field, and textural data from Cordón Caulle, we interpret breakout formation to be driven by a combination of pressure increase (from local vesiculation in the lava flow core, as well as from continued supply via extended thermally preferential pathways) and a weakening of the surface crust through lateral spreading and fracturing. Small breakouts, potentially resulting more from local vesiculation than from continued magma supply, show a domed morphology, developing into petaloid as inflation increasingly fractures the surface crust. Continued growth and fracturing results in a rubbly morphology, with the most inflated breakouts developing into a cleft-split morphology, reminiscent of tumulus inflation structures seen in basalts. These distinct morphological classes result from the evolving relative contributions of continued breakout advance and inflation. The extended nature of some breakouts highlights the role of lava supply under a stationary crust, a process ubiquitous in inflating basalt lava flows that reflects the presence of thermally preferential pathways. Textural analyses of the Cordón Caulle breakouts also emphasize the importance of late-stage volatile exsolution and vesiculation within the lava flow. Although breakouts occur across the compositional spectrum of lava flows, the greater magma viscosity is likely to make late-stage vesiculation much more important for breakout development in silicic lavas than in basalts. Such late-stage vesiculation has direct implications for hazards previously recognized from silicic lava flows, enhancing the likelihood of flow front collapse, and explosive decompression of the lava core. [ABSTRACT FROM AUTHOR]

The development of gas permeability in magmas is a complex phenomenon that directly influences the style of a volcanic eruption. The emergence of permeability is linked to the concept of percolation threshold, which is the point beyond which gas bubbles are connected in a continuous network that allows gas escape. Measurements of the percolation threshold, however, range from ∼30 to 78 vol%. No known combination of parameters can explain such a wide range of threshold values, which affects our understanding of the relationship between percolation and permeability. We present permeability calculations on bubble-bearing rhyolitic melts that underwent experimental decompression. Samples were analyzed by X-ray microtomography to image the bubble networks in 3D. We develop a percolation threshold for magmas that depends on the bubble network characteristics of this sample set. This relationship recovers the behavior of a wide range of volcanic samples by separating permeable samples from impermeable ones with a success rate of 88%. We use this percolation threshold to propose simplified permeability relationships that rely on parameters widely used in numerical modeling of magma flow. These relationships are valid within one order of magnitude for the viscous permeability coefficient and within two orders of magnitude for the inertial coefficient. They recover the ranges of values previously covered by isolated relationships, reassembling them within a single framework. We test the implications of such unification on eruptive dynamics with a 1D, two-phase conduit flow model. This test shows that varying the percolation threshold has little influence on vertical gas loss and ascent dynamics. [ABSTRACT FROM AUTHOR]

Several mechanisms have been proposed to allow highly viscous silicic magma to outgas efficiently enough to erupt effusively. There is increasing evidence that challenges the classic foam-collapse model in which gas escapes through permeable bubble networks, and instead suggests that magmatic fracturing and/or accompanying localized fragmentation and welding within the conduit play an important role in outgassing. The 2011–2012 eruption at Cordón Caulle volcano, Chile, provides direct observations of the role of magmatic fractures. This eruption exhibited a months-long hybrid phase, in which rhyolitic lava extrusion was accompanied by vigorous gas-and-tephra venting through fractures in the lava dome surface. Some of these fractures were preserved as tuffisites (tephra-filled veins) in erupted lava and bombs. We integrate constraints from petrologic analyses of erupted products and video analyses of gas-and-tephra venting to construct a model for magma ascent in a conduit. The one-dimensional, two-phase, steady-state model considers outgassing through deforming permeable bubble networks, magmatic fractures, and adjacent wall rock. Simulations for a range of plausible magma ascent conditions indicate that the eruption of low-porosity lava observed at Cordón Caulle volcano occurs because of significant gas flux through fracture networks in the upper conduit. This modeling emphasizes the important role that outgassing through magmatic fractures plays in sustaining effusive or hybrid eruptions of silicic magma and in facilitating explosive-effusive transitions. [Display omitted] • Combines observations with a magma ascent model to quantify magmatic fracture outgassing • A significant proportion of outgassing needs to occur through magmatic fractures to produce the Cordón Caulle hybrid eruption • Outgassing through magmatic fractures is likely important for explosive-effusive transitions in many silicic volcanoes [ABSTRACT FROM AUTHOR]

• The matrix glass from the 1921–1922 Cordón Caulle eruption is less evolved than the one from the 1960 and 2011–2012 events. • Magma storage was deeper in 1960 than in 1921–1922. Magma storage in 2011–2012 covered a broad range. All were in the shallow crust. • Magma extraction from a mush and magma storage occurred contiguously in the shallow crust, with extraction being slightly deeper than storage. • The deeper magma in 1960 likely contained less exsolved volatiles. Its eruption was probably facilitated by the M w 9.5 Great Chilean earthquake that occurred two days earlier. Cordón Caulle in southern Chile has produced three dacitic to rhyolitic fissure eruptions over the past century (in 1921–1922, 1960 and 2011–2012), and thereby provides an ideal opportunity to examine the architecture of its underlying silicic system. While the 2011–2012 eruption has been extensively studied, comparatively little is known about the 1921–1922 and 1960 events. Major-element matrix glass analyses from the 1960 products (71.5 wt.% SiO 2) are indistinguishable from the 2011–2012 data (72.2 wt.% SiO 2), but the 1921–1922 analyses form a discrete, slightly less evolved sub-population (69.0 wt.% SiO 2). We utilise rhyolite-MELTS geobarometry to estimate both the storage and extraction depths of all three magmas. For all three eruptions, magma was stored in the shallow crust, between 80–150 MPa (3.5–6.6 km). The 2011–2012 magma body spanned this whole depth range but the 1921–1922 and 1960 magma bodies were more confined in pressure, at 90–112 MPa (4.0–5.0 km) and 123–143 MPa (5.4–6.3 km) respectively. Melt extraction from a parental crystal-mush occurred in the range 70–200 MPa (3.1–9.0 km) for all three eruptions, suggesting contiguous melt segregation and storage in the shallow crust. Finally, we discuss whether the deeper magma storage in 1960 reflects the influence of a seismic trigger by events associated with the M w 9.5 Great Chilean earthquake. [ABSTRACT FROM AUTHOR]