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The Laguna Amarga Metamorphic Complex is a major stratigraphic component of the southern Central Andes. The occurrence of crystalline basement pieces extensively exposed in the western Andes of Catamarca (Argentina), has been known for decades, nevertheless, a lack of detailed field-based and geochronological survey has precluded an accurate correlation of the Laguna Amarga Complex with other basement exposures in the Central Andes. The Laguna Amarga Metamorphic Complex outcrops in several fault-bounded blocks spread over about 360 km2, always underlying Neopaleozoic strata and Neogene volcanic strata from the Central Volcanic Zone. The northern part of the complex consists of amphibolite-facies metamorphic rocks derived from sedimentary and igneous precursors grouped in an association named Cazadero Grande. The original stratigraphic succession was interbedded siliciclastic sediments, carbonaceous, and mafic rocks. The southern segment of the complex is dominated by granulite-facies migmatites and ortho-amphibolites grouped in an association called Los Aparejos. In the Cazadero Grande Association, four deformational events are recognized. The first three phases gave rise to an imbricate S-verging over-thrusting system and prevailing tectonic transport to the south in response to progressive non-coaxial strains. The mineral assemblages linked to the metamorphic climax equilibrated coeval with the early stages of fabric-forming deformation. The posthumous fourth phase of deformation produces gentle folds with kilometer-scale wavelengths whose axial planes (non-penetrative) have an NNE strike, and are as related to Andean deformation. Three incremental deformation events coeval with the metamorphic climax are registered in the Los Aparejos Association that indicate a kinematics transport to the east. First U–Pb zircon ages are reported for the Laguna Amarga Metamorphic Complex. Age distributions are polymodal, but the dominant populations make well-defined clusters. The most prominent concord age peak is at 389 Ma, revealing the age of the metamorphic climax. Another noteworthy aspect is the presence of dominant Mesoproterozoic concord age peaks (1119-1082 Ma), interpreted as inheritance ages of their protolith. A point to highlight is the absence of ages reflecting the source with Brasiliano-Pan-African orogenic ages that dominates detrital provenance from the West Gondwana. The Mesoproterozoic protolith ages allow the correlation of this metamorphic complex with nearby basement detached from Laurentian realms. The analysis of the ages shows that the metamorphic peak and the generalized deformation that affected the entire basement of the complex developed in the Middle Devonian (Eifelian), this being a very little known event for the Paleozoic evolution of western Gondwana. The work discusses how a better understanding of the crystalline basement of the high Andes impacts the geodynamic history of the proto-Andean Gondwana margin. It also provides new information on the geodynamic configuration of the Lower to Middle Paleozoic and its link with the processes of accretion-collision of terranes. • Tectonic cover slices from the Cuyania/Precordillera terrane are exposed in the high Andes of Catamarca, Argentina. • Zircon U–Pb dating yields Mesoproterozoic ages in inherited grains while Devonian ages in metamorphic rims. • Structural analyses imply top-S nappe stacking closely following a Devonian metamorphic peak. • A narrow suture zone separating Laurentia-derived crust from the Early Ordovician Famatinian arc. [ABSTRACT FROM AUTHOR]

Subduction zone magmatism plays a crucial role in driving the exchange of chemical elements between Earth's interior and surface. This survey focuses on the compositional analysis of primitive mafic rocks within an ancient Early Palaeozoic subduction-related magmatic belt. The primary objective is to assess the petrological processes involved in the cycling of chemical elements from the Earth's surface, through the slab and mantle reservoirs, to the crustal arc magmatic systems. By examining the composition of primitive mafic rocks and utilizing inverse modelling techniques, we estimate the composition of the ambient mantle source, which appears to have undergone depletion due to melt extraction before being metasomatized by slab agents. The inverse approach reveals that fluid-mobile elements (Th, U, La, Ce, and Sr) were primarily derived from the slab contribution and suggests that subduction had influenced the abundances of Nb and Ta in the modified mantle source. Conversely, Zr, Hf, and Ti were sourced from the ambient mantle. However, the available mineral/melt partition coefficients used in inverse modelling may overestimate the contribution of Sr and Nb from the slab. Instead, forward modelling is limited by the incomplete preservation of ancient volcanic arc geology. The forward mixing models that consider the interaction between slab-released sedimentary-derived melts and the ambient depleted mantle can explain the observed variations in Nd and Sr isotopic ratios in primitive mafic rocks. Two-component mixing shows that a small mass fraction (≤1.5 wt%) of average Cambrian continental sediments subducted beneath the Early Ordovician arc into a MORB-depleted mantle source account for the abundance of sedimentary-supplied elements such as Th, La, and Ba, as well as radiogenic isotope ratios of 143Nd/144N and 87Sr/86Sr in the primitive mafic magmas. The chemical and isotopic composition of deep-seated primitive mafic rocks reveals a decoupling between incompatible trace elements, which display minimal variation, and radiogenic isotopic ratios, which exhibit a wide range and reflect contributions from continental crustal reservoirs. To explain the observed variations in trace elements and isotopes, we propose a simple model involving simultaneous bulk assimilation (A) and imperfect fractional crystallization (IFC) in an open igneous system, where crystal accumulation and assimilation occur concurrently. Especially, deep crustal physicochemical interaction of primitive arc magmas with supracrustal host rocks may mask the expected clear signature of subarc mantle petrological processes. Our assessment of the Famatinian-Puna arc, an ancient subduction zone, concurs with estimates from active volcanic arcs, underscoring the general applicability of this study case to subduction zone magmatism. [Display omitted] • The study stresses underlying phenomena complicating the geochemical interpretation. • The pre-arc continental crust is an essential part of the subduction factory. • Crustal contamination could mask the signature of the subducting sedimentary layer. • Lithophile trace elements influx into the mantle wedge comes from subducted sediments. [ABSTRACT FROM AUTHOR]

Trace element abundances in constituent minerals from mafic and ultramafic rocks of a deep arc crustal section are studied to observe their abundance and distribution. Five cumulate rocks were selected from a sequence that consists of pyroxene hornblende peridotite, olivine hornblende gabbronorite, pyroxene hornblende gabbronorite, hornblende gabbronorite, gabbro and anorthosite. Solid/liquid partition coefficients calculated with the equilibrium distribution model indicate that Cr, Ni, Co, Zn and V are highly compatible with an olivine-dominated mineral assemblage from the mafic and ultramafic cumulates. The compatibility of Ti and Sc would be dependent on the stability of clinopyroxene, amphibole and oxides in the magmatic system. With few exceptions, the other trace elements are incompatible with the minerals that form the cumulate. At most half the mass of Sr carried by a primitive arc magma could be stored in anorthite-rich plagioclase from the mafic cumulates. Magmatic amphibole fractionates Y, middle and heavy REE from other incompatible elements during crystal accumulation of mafic cumulates. In contrast, late magmatic to subsolidus amphibole has no effect on the differentiation of a primitive arc magma. In fact, the trace element variability of amphibole and clinopyroxene is easily related to different stages of magmatic evolution within the cumulate pile. The results presented here are helpful for modelling other cases of arc magma petrogenesis where the cumulate rocks with dominant mafic assemblages are not exposed. [ABSTRACT FROM AUTHOR]

The granulite-complexes of the Sierras de Córdoba, inside context of Sierras Pampeanas, expose the deeply-uplifted internal metamorphic zone of an early Cambrian orogen. One of the largest granulite-complexes in the north-central of Sierra de Comechingones consists mainly of a set of stromatic and diatexitic migmatites all derived from metasedimentary progenitors. Migmatites vary over a spectrum of morphologies ranging from patch, net, and stromatic metatexites to schollen-schlieren and nebulite diatexites with widespread interspersed anatectic granites. The granulite-complex subordinately includes amphibolites, marbles, serpentinized ultramafic rocks, and mafic plutonic rocks. Petrographic analysis, textural and structural interpretation, thermobarometric estimates, and inherited and metamorphic zircon dating reveal the metamorphic history of migmatites in the north-central part of the Sierra de Comechingones. Metastable preservation of kyanite reflects that migmatites were buried (0.69–0.78 GPa) and heated (~650 °C) along a prograde trajectory before the onset of extensive anatexis. Then migmatites were further heated to granulite-facies peak temperatures (≥800 °C) at similar pressures (0.77 ± 0.06 GPa) through the sillimanite stability field. Widespread partial melting of the metasedimentary sequence occurred during peak metamorphism. The entire granulite-complex cooled to temperatures below 550 °C and ascended to middle crustal depths (0.3–0.5 GPa). The prograde heating trajectory and decompression during uplift overcoming cooling and tectonic exhumation are compatible with a predominantly compressive deformation. Coeval widespread partial melting with contractional non-coaxial deformation triggered self-reorganization of anatectic melts giving rise syn-deformational migmatites. In all the analyzed migmatites, U–Pb zircon geochronology yields inherited ages corresponding to those of orogenic systems that characterize the West Gondwana supercontinent. Inherited ages show a polymodal distribution pattern with contributions from Neoproterozoic (551–734 Ma; i.e., Brasiliano - Pan-African) and Mesoproterozoic detrital zircons (850–1182 Ma; i.e., Grenvillian), and minor proportions of Paleoproterozoic zircon grains (1751–1839 Ma). Ages interpreted as metamorphism and anatexis suggest the development of a single metamorphic event and restricted anatexis to a relatively short period of about 15 Ma (ca. 540-525 Ma). Metamorphic ages associated with the metamorphic peak trajectory are related to the Cambrian Pampean Orogeny. • P-T- t path shows a clockwise evolution along a single metamorphic event. • U–Pb zircon geochronology constraints granulite-facies metamorphism to ~540-525 Ma. • Metamorphic evolution was coeval with a compressive non-coaxial deformation. • Metatexites and diatexites are Early Cambrian syn-deformational lithological products. [ABSTRACT FROM AUTHOR]

Four major igneous suites with different geochemical characteristics are identified in the accretionary complex of the Pampean orogeny from the southern Sierras de Córdoba, Argentina. Crystallization ages of gabbroic and trondhjemitic plutonic rocks are Early to Middle Cambrian. The plutonic suites include mafic to intermediate alkaline OIB-like rocks, mafic tholeiitic N-MORB rocks, transitional mafic rocks, and minor trondhjemitic rocks with adakitic geochemical signature. The multiple igneous suites are spatially and temporally related to what reveals simultaneous tapping of distinct source reservoirs with their respective melts remaining distinctive from extraction to emplacement at middle crustal depths. The alkaline mafic-intermediate rocks with OIB-like geochemistry were generated by the partial melting of an enriched or metasomatized mantle source. By contrast, tholeiitic mafic rocks with N-MORB geochemical signature came out from a depleted mantle source. Trace element abundances of the transitional mafic magmas reflect variable mixtures between OIB-like and MORB-type magmas. Trondhjemitic rocks exhibit geochemical features highlighting their parent melts formed by low degree melting of a metasomatized subducting oceanic crust. The most reliable setting to generate all these diverse magmatic suites at the same time is a convergent margin where the opening of a slab window followed ridge-trench interaction. A corollary is that widespread mafic magmatism enhanced heat advection and gave rise to extensive intra-crustal anatexis in an accretionary complex of crustal extension. • Coexistence of multiple magmatic sources in the Early to Middle Cambrian Pampean orogen. • Alkaline, transitional and N-MORB mafic magmas intruded into metamorphic sequences. • Trondhjemite silicic adakite magmas spatially associated with alkaline mafic magmas. • Atypical subduction environment driven by slab-window following active ridge subduction. [ABSTRACT FROM AUTHOR]