1. Role of heterogeneous inactive component distribution induced by drying process on the mechanical integrity of composite electrode during electrochemical operation.
- Author
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Zhu, Zuoquan, He, Yaolong, and Hu, Hongjiu
- Subjects
ELECTROCHEMICAL electrodes ,COHESION ,DRYING ,LITHIUM cells ,STORAGE batteries ,INTEGRITY - Abstract
The drying rate would significantly affect the quality of the composite electrode after solidification. In order to clarify the underlying effect mechanism of ingredient heterogeneity in the electrode caused by the drying process on the mechanical integrity of lithium secondary batteries in service, an integrated analysis approach is developed to determine the mechanical properties and lithium diffusion-induced stress of the composite electrode with gradient distributed binder and conductive agent. A faster solidification is found to broaden the inhomogeneous extent of inactive components in the electrode coating across its thickness, markedly. As a result, it will not only enlarge the tensile stress in the brittle electrode upon electrochemical operation due to the increased effective modulus of composite near the surface, but will also impair the interfacial strength between the active layer and current collector. Moreover, a two-stage drying protocol (initially fast, followed by slow evaporation of solvent) is found to be greatly beneficial to boosting the resistance to cohesion failure and surface damage of the composite electrode, and the optimized processing parameters are proposed to obtain a robust production with high efficiency. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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