1. Lanthanide Complexes of Related Click Tripodal 1,2,3-Triazole-Containing Ligands on the Ph3P(O) Platform. The N2 and N3 Coordination of Triazole Fragments.
- Author
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Matveeva, A. G., Pasechnik, M. P., Aysin, R. R., Bykhovskaya, O. V., Matveev, S. V., Baulina, T. V., Kudryavtsev, I. Yu., Turanov, A. N., Karandashev, V. K., and Brel, V. K.
- Subjects
RARE earth metals ,IONIC equilibrium ,TRIAZOLES ,LIGANDS (Chemistry) ,NUCLEAR magnetic resonance spectroscopy ,RAMAN spectroscopy - Abstract
The coordination and extraction properties of two related tripodal ligands differed by types of addition of the triazole fragment and linker length in the {2-[(4-Ph-1,2,3-triazol-1-yl)CH
2 CH2 O]C6 H4 }3 P(O) (L1 ) and {2-[(1-Ph-1,2,3-triazol-4-yl)CH2 O]C6 H4 }3 P(O) (L2 ) are compared. The structures of the complexes [Lа(NO3 )3 L1 ] (I) and [Lu(NO3 )3 L1 ] (II) are studied in the solid phase (elemental analysis, IR and Raman spectroscopy) and in solutions (IR and multinuclear1 H,13 C, and31 P NMR spectroscopy). A normal coordinate analysis at the TPSS-D4/Def2-SVP level is performed for an isolated molecule of the model complex [La{P(O),N3 ,N2 -L3 }(O,O-NO3 )3 ] (L3 = {2-[(4-Me-1,2,3-triazol-1-yl)CH2 CH2 O]C6 H4 }3 -P(O)). According to the set of spectral and quantum chemical data, ligand L1 exhibits the tridentate P(O),N2 ,N2 coordination in lanthanide complexes I and II. These are neutral complexes in the solid state and in CD3 CN solutions, and the dynamic equilibrium of the neutral and ionic complexes is observed in CDCl3 . Unlike ligand L1 , ligand L2 exhibits the tetradentate P(O),N3 ,N3 ,N3 coordination in the [Ln(NO3 )3 L2 ] complexes with the same metals (Ln = La3+ , Lu3+ ) in solutions. The efficiency of extraction of microquantities of f elements from the aqueous phase to 1,2-dichloroethane by compounds L1 and L2 is discussed in comparison with the structures of the complexes of both ligands in solutions. [ABSTRACT FROM AUTHOR]- Published
- 2024
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