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Trombe walls figure among many passive devices used in the Mediterranean climate to minimize heating demands in residential buildings. The thickness of this massive wall is a critical parameter that influences the effectiveness of the system. Insufficient wall thickness conducts to an important interior temperature fluctuation, and huge wall thickness will increase costs and thermal resistance. In this paper, the optimum thickness of four different construction materials (concrete, stone, adobe, and brick), which can be used in the Trombe wall, was determined using an energetic and economic analysis. The energetic results with TRNSYS software show that the best materials, which can contribute to a reduction by 50% in heating loads of a single room, are stone and concrete. For the economic analysis, the life cycle cost and the payback period were calculated for each construction material. The results show that the optimum thickness for stone and concrete are, respectively, 34 and 32 cm with a payback period of 2.85 and 2.65 years. [ABSTRACT FROM AUTHOR]