1. Enhanced UV stability of perovskite solar cells with a SrO interlayer
- Author
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Yoon-Jung Lee, Jaebong Jung, Chan Bin Mo, Jihun Chun, Hae-Seok Lee, Kyung-Jin Cho, Taewon Chung, Soohyun Bae, Sang Won Lee, Yeon Ji Moon, Sungeun Park, Jae Keun Hwang, Yoonmook Kang, Inseol Song, Seongtak Kim, Donghwan Kim, and Won-Kyu Lee
- Subjects
Fabrication ,Materials science ,Passivation ,Perovskite solar cell ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,law.invention ,Biomaterials ,chemistry.chemical_compound ,law ,Solar cell ,Materials Chemistry ,Electrical and Electronic Engineering ,Strontium oxide ,Perovskite (structure) ,General Chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,chemistry ,Chemical engineering ,Degradation (geology) ,0210 nano-technology ,Layer (electronics) - Abstract
We investigated strontium oxide (SrO) as an interlayer material to enhance the UV stability of a CH3NH3PbI3 perovskite solar cell. Moisture and over 400 nm wavelength of light were excluded to investigate the effect of UV light only. Two different interlayer fabrication processes were examined to optimize the performance of this solar cell. Devices fabricated by dipping for 30 min in SrO solution exhibited photoconversion efficiencies of 15.5%, whereas those fabricated with 60-min dipping showed photoconversion efficiencies of 15% and exhibited local Sr agglomeration. Devices with SrO displayed lower initial efficiencies than those without any SrO layer (17.6%), However, a device without SrO retained only 34.4% of its initial efficiency after 100 h of UV exposure. In contrast, SrO-incorporated devices retained almost 60.0% of their initial efficiency. Severe μ-PL mapping intensity degradation was observed in devices that did not include the interlayer, but no degradation was observed in those with the SrO interlayer. This can be attributed to the passivation of the degradation sites by SrO.
- Published
- 2018
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