1. Impact of Na Doping on the Carrier Transport Path in Polycrystalline Flexible Cu2ZnSn(S,Se)4 Solar Cells
- Author
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Kyung Pil Kim, Seung Hyun Mun, William Jo, Ha Kyung Park, Dong-Seon Lee, Juran Kim, Woo Lim Jeong, Jung-Hong Min, Je Sung Lee, Sung-Tae Kim, and Jae-Hyung Jang
- Subjects
Materials science ,General Chemical Engineering ,General Physics and Astronomy ,Medicine (miscellaneous) ,02 engineering and technology ,doping ,010402 general chemistry ,01 natural sciences ,Biochemistry, Genetics and Molecular Biology (miscellaneous) ,flexible electronics ,law.invention ,law ,Solar cell ,General Materials Science ,lcsh:Science ,thin‐film solar cells ,carrier transport ,business.industry ,Doping ,General Engineering ,021001 nanoscience & nanotechnology ,Flexible electronics ,0104 chemical sciences ,CZTSSe ,Optoelectronics ,Grain boundary ,lcsh:Q ,Crystallite ,0210 nano-technology ,business ,Short circuit ,Volta potential ,Voltage - Abstract
It is well‐known that the alkali doping of polycrystalline Cu2ZnSn(S,Se)4 (CZTSSe) and Cu(In,Ga)(Se,S)2 has a beneficial influence on the device performance and there are various hypotheses about the principles of performance improvement. This work clearly explains the effect of Na doping on the fill factor (FF) rather than on all of the solar cell parameters (open‐circuit voltage, FF, and sometimes short circuit current) for overall performance improvement. When doping is optimized, the fabricated device shows sufficient built‐in potential and selects a better carrier transport path by the high potential difference between the intragrains and the grain boundaries. On the other hand, when doping is excessive, the device shows low contact potential difference and FF and selects a worse carrier transport path even though the built‐in potential becomes stronger. The fabricated CZTSSe solar cell on a flexible metal foil optimized with a 25 nm thick NaF doping layer achieves an FF of 62.63%, thereby clearly showing the enhancing effect of Na doping.
- Published
- 2020