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As hydrogen (H2) gas is highly reactive and explosive in ambient atmosphere, its prompt detection in industrial areas is imperative to prevent serious accidents. In particular, high-performance H2 sensors that can promptly detect even low-concentrations of H2 gas are necessary for safety. Carbon nanotubes (CNTs) have a large surface area and a high surface-to-volume ratio, and therefore, they are suitable for use as sensing materials in gas sensors. Moreover, gold, platinum, and palladium are known to be excellent catalyst metals that increase reactivity with H2 gas through the catalytic effect referred to as spill-over mechanism. In this study, a CNT felt sensor with a palladium (Pd) layer was fabricated, and its reactivity with H2 was evaluated. The sensitivity of a CNT felt sensor to H2 gas at room temperature was found to improve when coated with Pd layer.

The ferroelectric field-effect transistor (FeFET) is one of the most promising candidates for emerging nonvolatile memory devices owing to its low write energy and high $I_{\mathrm {ON}}/I_{\mathrm {OFF}}$ ratio. For FeFET applications as nonvolatile memory devices, 1FeFET, 1T-1FeFET, 2T-1FeFET, and 3T-1FeFET cells have been proposed. The 1FeFET cell exhibits the highest density but suffers from write disturbance. Although the 1T-1FeFET and 2T-1FeFET cells resolve the write disturbance, they use a write scheme with a negative write voltage ( $V_{\mathrm {W}}$ ), which requires voltage swings of many control signals, leading to a significantly high write energy consumption. The 3T-1FeFET cell uses a write scheme without a negative $V_{\mathrm {W}}$ ; however, it exhibits the largest area overhead. Although the 1T-1FeFET cell resolves the write disturbance with a small area overhead; however, it exhibits high write energy consumption because of the use of a negative $V_{\mathrm {W}}$ . In this paper, to significantly reduce the write energy consumption, we propose a less control signal swing (LCSS) write scheme without using a negative $V_{\mathrm {W}}$ . Simulation results indicate that the worst, average, and best cases of the proposed LCSS write scheme can achieve 35%, 66%, and 96% lower write energy consumption, respectively, than the write scheme with a negative $V_{\mathrm {W}}$ in the 1T-1FeFET cell. We also identify the available sensing schemes for each FeFET cell in the read operation according to the FeFET threshold voltage distribution.

Recently, nonvolatile systems with nonvolatile flip-flops (NVFFs) have gained prominence for their energy efficiency in energy-harvesting devices and battery-operated Internet of Things applications. They are normally-off instantly-on, and thus, can save energy effectively owing to their zero standby power consumption. An NVFF stores the computing state in nonvolatile memories (NVMs) when the power is off. A ferroelectric field-effect transistor (FeFET) is one of the most promising NVMs owing to its high $\text{I}_{\mathrm {on}}/\text{I}_{\mathrm {off}}$ ratio and low write power. Three FeFET-based NVFFs (previous FeFET-out NVFF-1/-2 and FeFET-in NVFF) were recently proposed to improve the area, power, and speed; however, they still have their own problems. Previous FeFET-out NVFF-1 has large area overhead and previous FeFET-out NVFF-2 does not properly perform restore operation. Previous FeFET-in NVFF has a long clock-to-Q delay and high operating energy. This paper introduces two novel FeFET-based NVFFs (proposed FeFET-out and -in NVFFs). Proposed FeFET-out NVFF reduces the large area overhead of previous FeFET-out NVFF-1 and corrects the malfunction in the restore operation of previous FeFET-out NVFF-2. Proposed FeFET-in NVFF achieves a better clock-to-Q delay, operating energy, and area than the previous FeFET-in NVFF. Monte Carlo simulations based on an industry-compatible 10-nm FinFET model are performed for a comparative analysis. Proposed FeFET-out NVFF achieves 17.6% smaller area with slightly higher (6.3%) operating energy and only 0.8% slower clock-to-Q delay than previous FeFET-out NVFF-1. Proposed FeFET-in NVFF achieves 18.9% shorter clock-to-Q and 3.0% smaller operating energy with 8.7% smaller area than the previous FeFET-in NVFF.

Palladium-coated multi-walled carbon nanotube (Pd-MWCNT) nanocomposites have been experimentally proven to show highly improved hydrogen (H2) gas detection characteristics at room temperature when compared with single MWCNTs. In this context, we develop an efficient and convenient method for forming nanocomposites by coating Pd nanoparticles on an MWCNT film. Furthermore, we test the applicability of the nanocomposites as sensing materials in detecting H2 gas at room temperature in a reliable and sensitive manner in contrast with ordinary metal-oxidebased gas sensors that operate at high temperatures. We first study the detection efficacy of the Pd-MWCNT film relative to pure MWCNT film. Subsequently, we investigate the Pd-MWCNT sensor’s sensitivity over time for different gas concentrations, the sensor response time, and sensor reproducibility and reliability under various conditions including bending tests. Our sensor exhibits stable reliable detection characteristics and excellent structural flexibility.

In this study, pristine carbon nanotubes (CNTs) and the CNTs functionalized through heat treatment were fabricated, and their hydrogen (H2) gas sensing characteristics were evaluated at room temperature. Pristine CNTs exhibited relatively low reactivity toward H2 gas, whereas functionalized CNTs demonstrated linear electrical response characteristics with an increase in the gas concentration due to the presence of functional groups (such as COOH and OH) on the CNT surface, which reduced the activation energy for the adsorption of H2 molecules and provided additional reactive sites. Thus, functionalized CNTs can be potentially utilized in various fields because their operation does not require high-temperature environments (unlike the currently used metal oxide-based H2 sensors), while the power consumption and explosion risks of these materials are easily reduced through a simple heat treatment process.

In this study, experimental variables pertaining to the formation of nano-pillar arrays using p-type silicon were optimized by controlling current density and chamber temperature. Three factors aff...

In this study, we have studied coating method using high reflective White silicon on the whole Zener diode in order to resolve the reducing the luminance of the LED problem caused by the Ze...

The block shear equations specified in the current AISC specification for structural steel buildings and North American cold-formed steel design specifications are based on research results of carbon steel bolted connections. These equations were found to be inapplicable for the welded connections in the literature. This issue is primarily associated with the use of the incorrect assumption on block shear failure mechanism. The present paper examines the accuracy of various block shear equations available in the design specifications and in the literature. The paper also examines the shear hardening capacity and the level of tensile stress over the critical net area with the results of finite element analysis, in which the fracture simulation is considered. It shows that the block shear capacities of lean duplex stainless steel welded connections can be predicted accurately using tensile stress equal to 1.25Fu, as proposed in the literature.

The proposed study describes the development of a carbon nanotube (CNT)-based gas sensor capable of detecting the presence of hydrogen (H2) gas at room temperature. CNT yarn used in the proposed sensor was fabricated from synthesized CNT arrays. Subsequently, the yarn was treated by means of a simple one-step procedure, called acid treatment, to facilitate removal of impurities from the yarn surface and forming functional species. To verify the proposed sensor’s effectiveness with regard to detection of H2 gas at room temperature, acid-treated CNT and pure yarns were fabricated and tested under identical conditions. Corresponding results demonstrate that compared to the untreated CNT yarn, the acid-treated CNT yarn exhibits higher sensitivity to the presence of H2 gas at room temperature. Additionally, the acid-treated CNT yarn was observed to demonstrate excellent selectivity pertaining to H2 gas.

Wearable sensors for tracking human body motion are being increasingly applied in medical systems and are considered important components of human–machine interfaces. This study proposes a flexible sandwich-like capacitive pressure sensor that consists of carbon nanotube–polydimethylsiloxane (CNT–PDMS) composite electrodes and a porous polymer dielectric layer. CNT yarn and polymer materials help fabricate a pressure sensor without complex patterns, easily and quickly. The dielectric layer is made of a porous polymer to improve the sensor sensitivity. The high porosity of the dielectric layer increases its deformation under pressure and enhances the sensitivity (to approximately 5.6 kPa−1 (%)) even under low pressures ( Owing to the high porosity of the dielectric layer and flexibility of the CNT yarn, the capacitive pressure sensor proposed in this study exhibits good performance in detecting even a slight change in stimulus. The proposed pressure sensor can be applied in wearable applications such as human-friendly interfaces and sensitive electronic skins.

The areal capacity ratio of negative to positive electrodes (N/P ratio) is the most important factor to design the lithium ion batteries with high performance in the consideration of balanced electrochemical reactions. In this study, the effect of N/P ratio (1.10, 1.20, and 1.30) on electrochemical properties has been investigated with a lithium polymer battery with PVdF-coated separator and 1.40 Ah of capacity. The N/P ratio is controlled by adjusting the anode thickness with a fixed anode density. The cell with an N/P ratio higher than 1.10 effectively suppresses the lithium plating at the 0.85C-rate charging at 25 °C and the cell with 1.20 of N/P ratio shows the enhanced cycle performance in comparison with other cells. Among the cells with differently designed N/P ratios, significant difference was not observed in the aging test with fully charged batteries at 25 and 45 °C. The effect of N/P ratio on electrochemical properties of lithium batteries can help to design the safe full cell without lithium plating.

modified powder is almost same as that of the pristine NiOpowder. The existence of Ti is identified through energydispersive spectroscopy (EDS) and these data demonstratethe homogeneous distribution of Ti without severe agglome-ration after annealing.The structural change in the modified powders after surfacemodification was investigated by X-ray diffraction (XRD).Figure 2 shows XRD data of the samples annealed at 650

This paper proposes a simple and efficient method to develop a nanocomposite by depositing platinum (Pt) nanoparticles on a carbon nanotube (CNT) sheet, and experimentally verifies the applicability of the proposed nanocomposite as a reliable and sensitive carbon monoxide (CO) gas sensor that operates at room temperature. A Pt-CNT nanocomposite shows improved CO gas sensing properties compared with the pristine CNT sheet. Owing to its large surface area and high conductivity, a CNT sheet exhibits improved sensitivity and fast response and recovery times. Based on the Pt-CNT nanocomposite implemented by the proposed method, we fabricated a Pt-CNT sheet-based CO gas sensor operating at room temperature and experimentally verified its stable and reliable room temperature sensing properties and excellent structural flexibility.

The layered lithium-manganese oxide () as a cathode material of lithium ion secondary batteries was prepared and characterized the physico-chemical and electrochemical properties. The morphological and structural changes of MnO(OH) and are closely connected to the changes of electrochemical properties. The crystallinity of is enhanced as the annealing temperature increase, but its capacity is reduced due to the easier structural changes of less crystalline than highly crystalline one. Moreover, the addition of buffer material such as MnO(OH) into cathode causes to reduce the morphological and structural changes of layered and increase the discharge capacity and cycleability.

The degradation of cathode materials due to the so-called ‘NiO dissolution’ problem, is one of the most critical issues restricting the long-term operation of molten carbonate fuel cells (MCFCs). To overcome this problem, a modified NiO powder is prepared by the annealing of a pre-mixed powder consisting of Ni powder and Co 3 O 4 nano-particles ( n -Co 3 O 4 ) at 650 °C. Annealing above 300 °C plays an important role in converting the physically bound mixed oxide system to a chemically bound system and, therefore, the separation of n -Co 3 O 4 from Ni is prevented. This modification leads to the formation of a Ni 0.9 Co 0.1 O solid solution, and the lithiated Ni 0.9 Co 0.1 O has a core–shell structure that consists of different Li contents. Whereas the core phase has a low concentration of lithium, the outer layer is a highly lithiated phase. Since the highly lithiated outer phase, acting as a barrier, minimizes the dissolution of NiO, the modified cathode demonstrates good electrochemical properties and chemical stability under actual operating conditions. This study can provide an effective way to mass produce MCFC cathode materials.

To evaluate the analgesic efficacy of bilateral superficial cervical plexus block and combined superficial and deep cervical plexus block for incision pain, headache and posterior neck pain after thyroidectomy.Ninety patients were divided into a control group (group C, n = 30), a bilateral superficial cervical plexus group (group S, n = 30) and a bilateral combined superficial and deep cervical plexus block group (group CO, n = 30). Before general anaesthesia, we performed bilateral superficial cervical plexus block (18 ml) and combined superficial (14 ml) and deep (4 ml) cervical plexus block with 0.25% bupivacaine. Anaesthesia was maintained with propofol-remifentanil-N2O-O2.The average concentration of remifentanil was significantly reduced in group S compared with group C and group CO (1.1 +/- 0.3, 1.8 +/- 0.4, 1.8 +/- 0.7 ng ml, respectively; P0.05). The incision pain at rest and on swallowing were significantly reduced at 0, 2 and 4 h in group S compared with group C (P0.05). Headache showed a tendency to be reduced in group S and group CO, but the posterior neck pain was not different among the three groups. After surgery, the opioid and nonopioid requirement was significantly reduced in group S (P0.05). There were fewer side effects and greater patients' satisfaction in group S.Superficial cervical plexus block is a more effective technique than combined superficial and deep cervical plexus block to reduce the pain during and immediately after thyroidectomy.

The velocities, turbulence intensities, Reynolds shear stresses, and turbulent kinetic energies of the flow fields around two square cylinders in a tandem arrangement were investigated using particle image velocimetry (PIV). The experiments were made for the spacing between the two cylinders ranging from s/D = 0.5 to 10.0 and two Reynolds numbers of 5,300 and 16,000. The results showed that the flow patterns at s/D≤2.0 were drastically different from those at s/D≥2.5 for both Reynolds numbers. The sudden change in the flow patterns depended on the reattachment of the shear layer separated from the upstream cylinder.

CeO 2 -coated LiMn 2 O 4 spinel cathode was synthesized using two-step synthesis method. All the samples exhibited a pure cubic spinel structure without any impurities in the XRD patterns. The results of the electrochemical performances on CeO 2 -coated electrode are compared to those of electrodes based on LiMn 2 O 4 spinel without CeO 2 coating. CeO 2 -coated LiMn 2 O 4 cathode improved the cycling stability of the electrode. The capacity retention of 2 wt% CeO 2 -coated LiMn 2 O 4 was more than 82% after 150 cycles between 3.0 and 4.4 V at room temperature and 82% after 40 cycles at elevated temperature of 60 °C. The amounts of dissolved manganese-ions in CeO 2 -coated LiMn 2 O 4 significantly are smaller than pristine LiMn 2 O 4 systems especially at elevated temperatures. Surface-modified LiMn 2 O 4 can suppress the dissolution reaction of manganese-ions at elevated temperature and clearly improve the cyclability of the spinel LiMn 2 O 4 cathode materials.

A novel method, a hydrothermal method, was firstly employed to prepare a catalyst of Pt supported on carbon nanotubes (Pt/CNTs) used in a proton exchange membrane fuel cell (PEMFC) in the present work. The catalyst was characterized through the IR spectrum, XRD, TEM and Image-Pro PLUS2 software. The results show that the pretreatment using a HNO 3 –H 2 O 2 redox system on CNTs opened the ports and removed a large quantity of impurities. Reaction temperature and time are important factors to determine the Pt granule size. The average size of the Pt nanoparticles is less than 1.94 nm with homogenous dispersion and narrow distribution under the optimal reaction conditions with a reaction time of 1.5 h at 140 °C. The hydrothermal method using the conventional Pt precursor H 2 PtCl 6 ·2H 2 O together with HCHO with brief operation will be a promising method to yield Pt nanoparticles for the Pt/CNTs catalyst.

LiNi 1− x Ti x O 2 (0 ≤ x ≤ 0.1) compounds have been synthesized by a direct molten-salt method that uses a eutectic mixture of LiNO 3 and LiOH salts. According to X-ray diffraction analysis, these materials have a well-developed layered structure (R3-m) and are an isostructure of LiNiO 2 . The LiNi 1− x Ti x O 2 (0 ≤ x ≤ 0.1) compounds have average particle sizes of 1–5 μm depending on the amount of Ti salt. Charge–discharge tests show that a LiNi 1− x Ti x O 2 (0 ≤ x ≤ 0.1) cathode prepared at 700 °C has an initial discharge capacity as high as 171 mA h g −1 and excellent capacity retention in the range 4.3–2.8 V at a current density of 0.2 mA cm −2 .

Olivine structure LiFePO 4 /C composite powders are synthesized as cathode materials for Li-ion batteries via a conventional solid-state reaction. Improvement in electrochemical performance has been achieved by using poly(vinyl alcohol) as the carbon sources for the as-prepared materials. The influence of the heat treatment on the physical and the electrochemical properties of LiFePO 4 /C materials is investigated. To examine the effect of added carbon content on the properties of materials, a one-step heat treatment has been employed with control of the PVA content in the precursor. Six samples were prepared with 0, 1, 3, 5, 10 and 30 wt.% PVA added to the raw materials. The particle size of LiFePO 4 decreases as the carbon content increases. Materials with medium carbon contents have a small charge-transfer resistance and thus exhibit superior electrochemical performance. Interestingly, for a LiFePO 4 /C composite with a low PVA content, an unusual plateau at 4.3 V is observed. It is considered that this is due to the Fe 3+ /Fe 4+ redox reaction of Fe 3+ compounds that are present as an impurity. For samples with a high PVA amount, a thicker carbon coating provides an obstacle to improve the electrochemical properties.

The dissolution of nickel oxide cathode in the electrolyte is one of the major technical obstacles to the commercialization of molten carbonate fuel cell (MCFC). To improve the MCFC cathode stability, the alternative cathode material for MCFC was prepared, which was made of Co/Ce-coated on the surface of Ni powder using a polymeric precursor based on the Pechini method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDAX) were employed in characterization of the alternative cathode materials. The Co/Ce-coated Ni cathode prepared by the tape-casting technique. The solubility of the Co/Ce-coated Ni cathode was about 80% lower when compare to that of pure Ni cathode under CO2:O2 (66.7:33.3%) atmosphere at 650 °C. Consequently, the fine Co/Ce-coated Ni powder could be confirmed as a new alternative cathode material for MCFC.

The properties of a new cathode material of nano-sized TiO 2 -coated Ni powder for application in molten carbonate fuel cells (MCFCs) are investigated. The material is prepared by a sol–gel method. X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM) with energy dispersive X-ray analysis (EDAX), transmission electron microscopy (TEM) and Raman spectroscopy are employed to characterize the cathode material. The nano-sized TiO 2 particles are homogenously coated on the surface of the Ni powder. A stable LiTi 1− x Ni x O 2 phase is formed on the surface of the Ni powder during immersion in molten carbonate at 650 °C. The solubility of the TiO 2 -coated Ni cathode is about 50% lower compare with that of a pure Ni cathode.

CeO2-coated LiCoO2 particles were successfully synthesized by a sol–gel coating of CeO2 on the surface of the LiCoO2 powder and subsequent heat treatment at 700 °C for 5 h. The surface-modified and pristine LiCoO2 powders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Auger electron spectroscopy (AES), slow rate cyclic voltammogram (CV), and differential scanning calorimetry (DSC). Cyclic voltammetry curves suggested that the CeO2 coating suppressed the phase transitions. Unlike pristine LiCoO2, the CeO2-coated LiCoO2 cathode exhibited better capacity retention than the pristine LiCoO2 electrode in the higher cutoff voltage. Differential scanning calorimetric data revealed the higher thermal stability of the CeO2-coated LiCoO2 electrode.

The flow fields including velocities, turbulence intensities, Reynolds shear stress and turbulent kinetic energy were investigated using particle image velocimetry(PIV) to study the flow characteristics around two square cylinders in a tandem arrangement. The experiments were carried out in the range of the spacing from 1.0 to 4.0 widths of cylinder, Reynolds number of 5.310 and 1.610 respectively. Discontinuous jumping at the drag coefficient variation was found for two cylinders simultaneously when the spacing between two cylinders is varied. This phenomenon is attributed to a sudden change of the flow pattern which depends on the reattachment of the shear layer separated from the upstream cylinder. Near such a critical spacing, the changes of the flow fields as well as the effect of Reynolds number were studied in detail.

Layered Li[Ni0.5−xMn0.5−xZr2x]O2 (x = 0, 0.025) have been prepared by the mixed hydroxide and molten-salt synthesis method. The individual particles of synthesized materials have a sub-microsize range of 200–500 nm, and LiNi0.475Mn0.475Zr0.05O2 has a rougher surface than that of LiNi0.5Mn0.5O2. The Li/Li[Ni0.5−xMn0.5−xZr2x]O2 (x = 0, 0.025) electrodes were cycled between 4.5 and 2.0 V at a current density of 15 mA/g, the discharge capacity of both cells increased during the first ten cycles. The discharge capacity of the Li/LiNi0.475Mn0.475Zr0.05O2 cell increased from 150 to 220 mAh/g, which is 50 mAh/g larger than that of the Li/LiNi0.5Mn0.5O2 cell. We found that the oxidation of oxygen and the Mn3+ ion concerned this phenomenon from the cyclic voltammetry (CV). Thermal stability of the charged Li[Ni0.5−xMn0.5−xZr2x]O2 (x = 0, 0.025) cathode was improved by Zr doping.

A high-performance LiNi 0.8 Co 0.2 O 2 cathode was successfully fabricated by a sol–gel coating of CeO 2 to the surface of the LiNi 0.8 Co 0.2 O 2 powder and subsequent heat treatment at 700 °C for 5 h. The surface-modified and pristine LiNi 0.8 Co 0.2 O 2 powders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), slow rate cyclic voltammogram (CV), and differential scanning calorimetry (DSC). Unlike pristine LiNi 0.8 Co 0.2 O 2 , the CeO 2 -coated LiNi 0.8 Co 0.2 O 2 cathode exhibits no decrease in its original specific capacity of 182 mAh/g (versus lithium metal) and excellent capacity retention (95% of its initial capacity) between 4.5 and 2.8 V after 55 cycles. The results indicate that the surface treatment should be an effective way to improve the comprehensive properties of the cathode materials for lithium ion batteries.

Co/Mg solid solution coated Ni powder, where Mg-doped LiCoO2 is coated on NiO in molten carbonate, has been used as a new cathode material to reduce the solubility of NiO and to maintain the advantages of NiO cathode. The (Co/Mg)-coated NiO cathode was prepared by a coating Co/Mg solid solution on the surface of the Ni powder using a PVA assisted sol–gel method. The phase changes of the (Co/Mg)-coated Ni powder after immersed into Li/K eutectic carbonate mixtures at 550 °C ∼ 850 °C for 48 h was performed by XRD and Raman. SEM was used to study the particle morphologies. Co/Mg solid solution was coated on the surface of the Ni powder and Li(NiCoMg)O2 is formed on NiO in molten carbonate. It is expected that the Li(NiCoMg)O2 phase will reduce the solubility of NiO cathode in molten carbonate.

In this study, we made a novel alternative cathode material of molten carbonate fuel cell (MCFC) using electroless deposition of Co on the surface of the Ni powder. Using this manufacturing method, we expect that economical and large-scale cathode can be made easily. The cathode prepared by this method formed LiCo 1− y Ni y O 2 phase in molten (Li 0.62 K 0.38 ) 2 CO 3 at 650 °C under CO 2 :O 2 =66.7:33.3% atmosphere, its solubility is 40% lower than that of NiO cathode. In the unit cell test, the performance of the cell composed of Co-coated Ni cathode was same as that of the cell composed of NiO cathode. Thus the cathode made by Co-coated Ni powder used as an alternative cathode can maintain the advantages of NiO cathode and lengthen the lifetime of MCFC.

This paper presents a thermal convection-based sensor, which is fabricated using carbon nanotube (CNT) yarn. The key element in this device is the non-symmetrically distributed, heated air medium around the heater, particularly when it experiences acceleration and/or changes in inclination. Therefore, it can withstand much higher accelerations/inclination than conventional sensors that use a proof mass. However, a major challenge for the design of this type of sensor is the high heating power (in the order of tens of milliwatts) required to facilitate thermal convection in a sealed chamber. In order to reduce the high heating power, CNTs are investigated as materials for both the heater and the temperature sensors. Moreover, this paper discusses experiments that were performed by varying several parameters, such as the heating power, distance between the heater and temperature sensors, the gas medium used, and air pressure.

Lithiated NiO cathode dissolution has been a major problem for the development of molten carbonate fuel cells (MCFCs). Many studies have been contributed to find new alternative cathodes; here, lithium cobalt oxide, LiCoO2, was coated onto the commonly used NiO cathode by the electroplating method and the resulting cathode showed much reduced solubility compared with that of the common nickel oxide cathode. Thin film lithium cobalt oxide was prepared by the oxidation of Co metal deposited on a nickel plate in molten (Li,K)2CO3 at 650 °C under a CO2–O2 (2 ∶ 1 vol%) atmosphere. When this coated nickel plate was oxidized, the open circuit potential (OCP) decayed gradually, indicating two well-defined potential plateaux; the oxide films produced at each potential plateau were identified by X-ray diffraction methods. The surface product at the first plateau was CoO. LiCoO2 was formed at the second OCP plateau [around −0.47 V vs. CO2–O2 (2 ∶ 1 vol%) reference electrode]. By the same method, LiCoO2 was coated onto a porous nickel cathode in order to produce a MCFC. For 300 h steady operation of the cells, the mean voltages of the cells were 0.80 V using a NiO cathode and 0.85 V for a LC-NiO(EP) cathode at a current density of 150 mA cm−2. In addition to the cell efficiency improvement, the solubility of the LC-NiO(EP) cathode was much lower than that of the NiO cathode.

because it has high electrical conductivity, good thermal and chemical stability, high specific capacity, and the promotion of the reduction reaction of the cathode. Hence, it is expected that the use of the highly conductive PEDOT may serve as an outer layer to assist the transportation of Li ions.The pristine LiFePO

The solubility of a nickel oxide cathode in molten carbonate fuel cell (MCFC) electrolyte is one of the major technical obstacles to the commercialization of such fuel cells. Lithium cobalt oxide, LiCoO 2 , has been selected as a candidate material for MCFC cathodes because its solubility is small and the rate of dissolution into the melt is slower than that for nickel oxide. On the other hand, the electrical conductivity of LiCoO 2 is lower than that of nickel oxide. Thus, nickel oxide has been coated with stable LiCoO 2 in carbonate by a PVA-assisted sol–gel method to give a LiCoO 2 -coated NiO (LC-NiO) cathode. Raman spectra show that the structure of LC-NiO is different from that of nickel oxide, and that a LiCo 1− y Ni y O 2 phase is formed during heat-treatment of the LC-NiO cathode. The coating of LiCoO 2 on NiO electrode increases with increase in the dipping and heating times. The performance of unit cells show that the mean voltage of the cells is 0.80 V using a NiO cathode and 0.85 V with a LC-NiO cathode at a current density of 150 mA cm −2 . The solubility of the LC-NiO cathode in molten carbonate electrolyte is half that of NiO cathode after 300 h at 650°C.

The amorphous silk fibroin films were prepared by casting from lithium bromide aqueous solution. It was found on the basis of the X-ray diffraction patterns that the amorphous phase was crystallized into two different crystalline forms, Silk I and SilkII, by the short-time annealing at 200°C. The fibroin films of untreated sample was found to be crystallized into silk I type in the process of heating by the DSC. The metastable Silk I type was partly transformed into Silk II type by longer annealing. The films were stretched up to 2.7 times after being immersed in 80% ethanol aqueous solution for 30s. The strength and Young's modulus of the drawn films increased and elongation decreased with increasing the draw ratio. In the case of low draw ratio, crystallization occurred without any orientation. The degree of crystal orientation of Silk I and Silk II types increased, with the increase in the draw ratio of sample. The increase in the degree of crystallinity caused by annealing and stretching treatment was accompanied by the phase transformation from amorphous to Silk II. This fact was also supported by the DSC result.

The dissolution of nickel oxide cathodes in the electrolyte is one of the major technical obstacles to the commercialization of molten carbonate fuel cells (MCFC). A novel alternative cathode material for MCFC was synthesized, which was made of nano-size Co3O4 coated on the surface of Ni powder using a polymeric precursor based on the Pechini method. X-Ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDAX), electron microprobe analysis (EPMA), and Raman spectrometry were employed in characterization of the novel alternative cathode materials. The Co-coated Ni cathode prepared by the tape-casting technique has a lower solubility in the molten carbonate than in the NiO cathode under CO2 ∶ O2 (67 ∶ 33) atmosphere at 650 °C. The reason is that the nano-size Co3O4-coated Ni powder can significantly retard the dissolution of NiO in molten carbonate due to the formation of the stable LiCo1−yNiyO2 phase on the surface of NiO in molten carbonate. During 300 h cell operation, the closed-circuit voltage (CCV) of unit cells using NiO and Co-coated Ni cathodes were found to be 0.80 V and 0.82 V, respectively, at a current density of 150 mA cm−2. The results show that the Co-coated Ni cathode used as an alternative cathode could resolve the problems in scale-up of the electrode and lengthen the lifetime of MCFC.