1. A pyrosol process to deposit large-area SnO2:F thin films and its use as a transparent conducting substrate for CdTe solar cells
- Author
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S. Kumazawa, M. Tsuji, K. Omura, T. Aramoto, T. Arita, A. Hanafusa, J. Nakajima, P. Veluchamy, H. Higuchi, H. Ohyama, T. Nishio, T. Hibino, and S. Shibutani
- Subjects
Materials science ,Aqueous solution ,Renewable Energy, Sustainability and the Environment ,Analytical chemistry ,Mineralogy ,Substrate (electronics) ,Cadmium sulfide ,Cadmium telluride photovoltaics ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,law.invention ,chemistry.chemical_compound ,chemistry ,Electrical resistivity and conductivity ,law ,Solar cell ,Thin film ,Sheet resistance - Abstract
Highly transparent, low-resistance SnO 2 :F films suitable as a substrate material for thin-film CdS/CdTe solar cells have been developed on 10 × 10, 30 x 60 and 82 x 71 cm 2 glass substrates by an ultrasonic spray pyrolysis (pyrosol) process. Dimethyltin dichloride, NH 4 F and HF dissolved in water served as the source solution. A fine spray of the source solution has been transported using air as a carrier gas onto hot glass plates in a belt furnace maintained at 500-530°C. A very high growth rate of > 15 nm/s and a high throughput of 3 min/glass plate (82 x 71 cm 2 size) have been achieved with films showing greater uniformity, low sheet resistance and high optical transmission. Typical films exhibited a thickness of 500 nm, a sheet resistance of 8.1 Ω/sq., a mobility of 43.8 cm 2 /V s and a donor concentration of 3.5 x 10 20 cm -3 . A thin-film CdS/CdTe solar cell fabricated on a 30 x 60 cm 2 SnO 2 :F transparent conducting substrate exhibited a solar energy conversion efficiency maximum of 14.95% for 1 cm 2 cell and an average efficiency of 14.24% for 178 isolated 1 cm 2 cells.
- Published
- 2001
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