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Context. Dense highly ionized boundary layers (IBLs) outside of the neutral Photon Dominated Regions (PDRs) have recently been detected via the 122 and 205 μm transitions of ionized nitrogen. These layers have higher densities than in the Warm Ionized Medium (WIM) but less than typically found in H II regions. Observations of [C II] emission, which is produced in both the PDR and IBL, do not fully define the characteristics of these sources. Observations of additional probes which just trace the PDRs, such as the fine structure lines of atomic oxygen, are needed derive their properties and distinguish among different models for [C II] and [N II] emissison. Aims. We derive the properties of the PDRs adjacent to dense highly ionized boundary layers of molecular clouds. Methods. We combine high-spectral resolution observations of the 63 μm [O I] fine structure line taken with the upGREAT HFA-band instrument on SOFIA with [C II] observations to constrain the physical conditions in the PDRs. The observations consist of samples along four lines of sight (LOS) towards the inner Galaxy containing several dense molecular clouds. We interpret the conditions in the PDRs using radiative transfer models for [C II] and [O I]. Results. We have a 3.5-σ detection of [O I] toward one source but only upper limits towards the others. We use the [O I] to [C II] ratio, or their upper limits, and the column density of C+ to estimate the thermal pressure, Pth, in these PDRs. In two LOS the thermal pressure is likely in the range 2–5 × 105 in units of K cm−3, with kinetic temperatures of order 75–100 K and H2 densities, n(H2) ~ 2–4 × 103 cm−3. For the other two sources, where the upper limits on [O I] to [C II] are larger, Pth ≲105 (K cm−3). We have also used PDR models that predict the [O I] to [C II] ratio, along with our observations of this ratio, to limit the intensity of the Far UV radiation field. Conclusions. The [C II] and [N II] emission with either weak, or without any, evidence of [O I] indicates that the source of dense highly ionized gas traced by [N II] most likely arises from the ionized boundary layers of clouds rather than from H II regions. [ABSTRACT FROM AUTHOR]

We present SOFIA/GREAT [C ii] ²P3/2 →²P1/2 (1.9005369 THz) observations of nearby clouds near the lines of sight towards the quasars B0355+508 and B0212+735. These clouds have previously been identified as warm non-LTE diffuse clouds with a temperature of T ≳ 30 K and sub-thermally excited CO lines. They are highly structured in CO with small-scale bright spots (I(CO J = 1-0) ~ 5-20 Kkm s-1), both spectrally and spatially. This small-scale structure has been interpreted as small-scale variations in the chemistry, not as density and column-density structure. We did not detect [C ii] 158 μm emission within the rms noise of ~0.1-0.3 K. Our non-detection in [C ii] contradicts the above scenario. In diffuse clouds, the effciency of photo-electric heating is highest. Under the assumption that [C ii] is the dominant coolant in diffuse clouds, we can calculate the predicted [C ii] emission arising from these clouds. Based on the derived hydrogen column densities for the diffuse clouds, a line width in [C ii] of similar order to that of CO, and when at least the minimum amount of heating in the clouds is due to cosmic-ray heating, [C ii] line intensities ≳1.5 to 5 Kkm s-1 are expected, which is a factor ~3 to 15 above the upper limits of the observations. The upper limits of the [C ii] and the observed CO line intensities are, however, consistent with the intensities predicted for photon-dominated region (PDR) surfaces on regular cold (T ~ 15 K) low-density cloud fragments. Lower temperatures lead to less excited [C ii]. The assumption of lower densities, which would equally lower the [C ii] excitation, contradicts the observed cloud sizes and column densities. The CO(2-1)/CO(1-0) line ratios observed in these clouds are consistent with cloud temperatures of T ~ 15 K. The KOSMA-τ PDRmodel of a cold moderate-density clump or an ensemble of such clumps with a canonical mass-size relation and mass spectrum, consistent with the total column densities derived for low density, shows that cold PDRs can reproduce the observed CO intensities, the observed CO(1-0) and CO(2-1) ratio, and the observed upper limits for [C ii]. [ABSTRACT FROM AUTHOR]