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Identifying infall motions is crucial for our understanding of accretion processes in regions of star formation. The NH3 (1,1) hyperfine intensity anomaly (HIA) has been proposed to be a readily usable tracer for such infall motions in star-forming regions harboring young stellar objects at very early evolutionary stages. In this paper, we seek to study the HIA toward 15 infall candidate regions in order to assess its reliability as an infall tracer. Using deep observations of the NH3 (1, 1) transition with the Effelsberg 100 m telescope, we identified HIAs toward all 15 targets. Of the 15 sources, 14 exhibit anomalous intensities in either the inner or outer satellite lines. All the derived HIAs conform to the framework of the existing two models, namely hyperfine selective trapping (HST) and systematic contraction or expansion motion (CE) models. In our sample of infall candidates, the majority of the HIAs remain consistent with the HST model. Only in three targets are the HIAs consistent with infall motions under the CE model. Thus, the HIA could indeed be used as an infall tracer, but does not appear to be highly sensitive to infall motions in our single-dish data. Nevertheless, the emission could be blended with emission from outflow activities. HIAs consistent with the HST model show stronger anomalies with increasing kinetic temperatures (TK), which is expected based on the HST model. On the other hand, HIAs consistent with infall motions show little dependence on Tk. Therefore, HIAs may preferably trace the infall of cold gas. [ABSTRACT FROM AUTHOR]

Context. CF+ has been established as a valuable diagnostic tool for investigating photodissociation regions (PDRs) and fluorine abundances in the Milky Way. However, its role in extragalactic environments remains largely uncharted. Aims. Our objective is to explore the significance of CF+ in the Large Magellanic Cloud (LMC) and assess its utility as a probe for examining C+ and fluorine abundances in external galaxies. Methods. We performed pointed CF+ observations toward an active star-forming region, N113 in the LMC, using the Atacama Pathfinder EXperiment 12 m submillimeter telescope. Results. We report the first discovery of CF+ in the LMC through the successful detection of the CF+ (2→1) and (3→2) lines. The excitation models indicate that CF+ emission originates from dense PDRs characterized by an H2 number density of (0.5–7.9) × 104 cm−3 in N113. Our observations provide the first constraint on the fluorine abundance in molecular clouds in the LMC, ≲1.7 × 10−9. This value is about an order of magnitude lower than those previously measured toward red giants in the LMC, indicative of fluorine deficiency in the molecular gas. The estimated column density ratio between C+ and CF+ appears to be lower than the anticipated equilibrium ratio derived from the fluorine abundance in red giants. Both phenomena can be explained by the deficiency of CF+ caused by the freeze-out of its primary chemical precursor, HF, onto dust grains. Conclusions. The deficiency of CF+ within molecular clouds suggests that the measurements presented in this work serve exclusively as conservative estimates, establishing lower bounds for both the fluorine abundance and C+ column densities in external galaxies. [ABSTRACT FROM AUTHOR]

Context. The 1°.3 (G1.3) and 1°.6 (G1.6) cloud complexes in the central molecular zone (CMZ) of our Galaxy have been proposed to possibly reside at the intersection region of the X1 and X2 orbits for several reasons. This includes the detection of co-spatial low- and high-velocity clouds, high velocity dispersion, high fractional molecular abundances of shock-tracing molecules, and kinetic temperatures that are higher than for usual CMZ clouds. Aims. By investigating the morphology and deriving physical properties as well as chemical composition, we want to find the origin of the turbulent gas and, in particular, whether evidence of an interaction between clouds can be identified. Methods. We mapped both cloud complexes in molecular lines in the frequency range from 85 to 117 GHz with the IRAM 30 m telescope. The APEX 12m telescope was used to observe higher frequency transitions between 210 and 475 GHz from selected molecules that are emitted from higher energy levels. We performed non-local thermodynamic equilibrium (non-LTE) modelling of the emission of an ensemble of CH3CN lines to derive kinetic temperatures and H2 volume densities. These were used as starting points for non-LTE modelling of other molecules, for which column densities and abundances were determined and compared with values found for other sources in the CMZ. Results. The kinematic structure of G1.3 reveals an 'emission bridge' at intermediate velocities (~150 km s−1) connecting low-velocity (~100 km s−1) and high-velocity (~180 km s−1) gas and an overall fluffy shell-like structure. These may represent observational evidence of cloud-cloud interactions. Low- and high-velocity gas components in G1.6 do not show this type of evidence of an interaction, suggesting that they are spatially separated. We selected three positions in each cloud complex for further analysis. Each position reveals several gas components at various peak velocities and of various line widths. We derived kinetic temperatures of 60–100 K and H2 volume densities of 104–105 cm−3 in both complexes. Molecular abundances relative to H2 suggest a similar chemistry of the two clouds, which is moreover similar to that of other GC clouds and, especially, agrees well with that of G+0.693 and G−0.11. Conclusions. We conclude that G1.3 may indeed exhibit signs of cloud-cloud interactions. In particular, we propose an interaction of gas that is accreted from the near-side dust lane to the CMZ, with gas pre-existing at this location. Low- and high-velocity components in G1.6 are rather coincidentally observed along the same line of sight. They may be associated with either overshot decelerated gas from the far-side dust line or actual CMZ gas and high-velocity gas moving on a dust lane. These scenarios would be in agreement with numerical simulations. [ABSTRACT FROM AUTHOR]

Context. One of the surprises of the Herschel mission was the detection of ArH+ towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the Galaxy, the existing data suggest that ArH+ ubiquitously and exclusively probes the diffuse atomic regions of the interstellar medium. Aims. In this study, we extend the coverage of ArH+ to other parts of the Galaxy with new observations of its J = 1−0 transition along seven Galactic sight lines towards bright sub-millimetre continuum sources. We aim to benchmark its efficiency as a tracer of purely atomic gas by evaluating its correlation (or lack of correlation as suggested by chemical models) with other well-known atomic gas tracers such as OH+ and H2O+ and the molecular gas tracer CH. Methods. The observations of the J = 1−0 line of ArH+ near 617.5 GHz were made feasible with the new, sensitive SEPIA660 receiver on the APEX 12 m telescope. Furthermore, the two sidebands of this receiver allowed us to observe the NKaKc = 11,0−10,1 $N_{K_{a}K_{c}}\,{=}\,1_{1,0}{-}1_{0,1}$ N K a K c   =   1 1 , 0 − 1 0 , 1 transitions of para-H2O+ at 607.227 GHz simultaneously with the ArH+ line. Results. We modelled the optically thin absorption spectra of the different species and subsequently derived their column densities. By analysing the steady state chemistry of OH+ and o-H2O+, we derive on average a cosmic-ray ionisation rate, ζp(H), of (2.3 ± 0.3) × 10−16 s−1 towards the sight lines studied in this work. Using the derived values of ζp(H) and the observed ArH+ abundances we constrain the molecular fraction of the gas traced by ArH+ to lie below 2 × 10−2 with a median value of 8.8 × 10−4. Combined, our observations of ArH+, OH+, H2O+, and CH probe different regimes of the interstellar medium, from diffuse atomic to diffuse and translucent molecular clouds. Over Galactic scales, we see that the distribution of N(ArH+) is associated with that of N(H), particularly in the inner Galaxy (within 7 kpc of the Galactic centre) with potentially even contributions from the warm neutral medium phase of atomic gas at larger galactocentric distances. We derive an average ortho-to-para ratio for H2O+ of 2.1 ± 1.0, which corresponds to a nuclear spin temperature of 41 K, consistent with the typical gas temperatures of diffuse clouds. [ABSTRACT FROM AUTHOR]

Context. Spectral lines of minor isotopic species of molecules that are abundant in space may also be detectable. Their respective isotopic ratios may provide clues about the formation of these molecules. Emission lines of acetone in the hot molecular core Sagittarius B2(N2) are strong enough to warrant a search for its singly substituted 13C isotopologs. Aims. We want to study the rotational spectra of CH313 CH 3 13 $ \mathrm{CH}_3^{13} $ C(O)CH3 and 13CH3C(O)CH3 and search for them in Sagittarius B2(N2). Methods. We investigated the laboratory rotational spectrum of isotopically enriched CH313 CH 3 13 $ \mathrm{CH}_3^{13} $ C(O)CH3 between 40 GHz and 910 GHz and of acetone between 36 GHz and 910 GHz in order to study 13CH3C(O)CH3 in natural isotopic composition. In addition, we searched for emission lines produced by these species in a molecular line survey of Sagittarius B2(N) carried out with the Atacama Large Millimeter/submillimeter Array (ALMA). Discrepancies between predictions of the main isotopic species and the ALMA spectrum prompted us to revisit the rotational spectrum of this isotopolog. Results. We assigned 9711 new transitions of CH313 CH 3 13 $ \mathrm{CH}_3^{13} $ C(O)CH3 and 63 new transitions of 13CH3C(O)CH3 in the laboratory spectra. More than 1000 additional transitions were assigned for the main isotopic species. We modeled the ground state data of all three isotopologs satisfactorily with the ERHAM program. We find that models of the torsionally excited states v12 = 1 and v17 = 1 of CH3C(O)CH3 improve only marginally. No transitrrrion of CH313 CH 3 13 $ \mathrm{CH}_3^{13} $ C(O)CH3 is clearly detected toward the hot molecular core Sgr B2(N2). However, we report a tentative detection of 13CH3C(O)CH3 with a 12C/13C isotopic ratio of 27 that is consistent with the ratio previously measured for alcohols in this source. Several dozens of transitions of both torsional states of the main isotopolog are detected as well. Conclusion. Our predictions of CH313 CH 3 13 $ \mathrm{CH}_3^{13} $ C(O)CH3 and CH3C(O)CH3 are reliable into the terahertz region. The spectrum of 13CH3C(O)CH3 should be revisited in the laboratory with an enriched sample. The torsionally excited states v12 = 1 and v17 = 1 of CH3C(O)CH3 were not reproduced satisfactorily in our models. Nevertheless, transitions pertaining to both states could be identified unambiguously in Sagittarius B2(N2). [ABSTRACT FROM AUTHOR]

Methyl mercaptan (CH3SH) is an important sulfur-bearing species in the interstellar medium, terrestrial environment, and potentially in planetary atmospheres. The aim of the present study is to provide accurate spectroscopic parameters for the most abundant minor isotopolog CH334SH to support radio astronomical observations at millimeter and submillimeter wavelengths. The rotational spectrum of CH334SH, which is complicated by the large-amplitude internal rotation of the CH3 group versus the 34SH frame, was investigated in the 49−510 GHz and 1.1−1.5 THz frequency ranges in natural isotopic abundance. The analysis of the spectrum was performed up to the second excited torsional state, and the obtained data were modeled with the RAM36 program. A fit within experimental accuracy was obtained with a RAM Hamiltonian model that uses 72 parameters. Predictions based on this fit are used to search for CH334SH with the Atacama Large Millimeter/submillimeter Array (ALMA) toward the hot molecular core Sgr B2(N2), but blends with emission lines of other species prevent its firm identification in this source. [ABSTRACT FROM AUTHOR]

Isocyanic acid (HNCO), the most stable of the simplest molecules containing the four main elements essential for organic chemistry, has been observed in several astrophysical environments such as molecular clouds, star-forming regions, external galaxies, and comets. In this work, we model HNCO spectral line profiles towards the low-mass solar type protostar IRAS 16293−2422 observed with the ALMA interferometer, the IRAM, JCMT, and APEX single-dish radio telescopes, and the HIFI instrument on board the Herschel Space Observatory. In star-forming environments, the HNCO emission is not always in Local Thermodynamical Equilibrium (LTE). A non-LTE radiative transfer approach is necessary to properly interpret the line profiles, and accurate collisional rate coefficients are needed. Here, we used the radex package with a completely new set of collisional quenching rates between HNCO and both ortho-H2 and para-H2 obtained from quantum chemical calculations yielding a novel potential energy surface in the rigid rotor approximation. We find that the lines profiles towards IRAS 16293−2422 are very well reproduced if we assume that the HNCO emission arises from a compact, dense, and hot physical component associated with the hot corino, a warm component associated with the internal part of the protostellar envelope, and a cold and more extended component associated with the outer envelope. The derived HNCO abundances from our model agree well with those computed with the Nautilus chemical code. [ABSTRACT FROM AUTHOR]

As first realised in the late 1980s, methanol masers come in two varieties, termed Class I and Class II. While Class II masers had observationally been extensively studied in the past, until recently relatively little attention was paid to Class I methanol masers due to their low luminosities compared to other maser transitions. In this review, we will focus on the recent progress in our understanding of Class I methanol masers both from an observational and from a theoretical point of view. [ABSTRACT FROM AUTHOR]

Trends observed in galaxies, such as the Gao & Solomon relation, suggest a linear relationship between the star formation rate and the mass of dense gas available for star formation. Validation of such trends requires the establishment of reliable methods to trace the dense gas in galaxies. One frequent assumption is that the HCN (J = 1-0) transition is unambiguously associated with gas at H2 densities ≫ 104 cm-3. If so, the mass of gas at densities ≫ 104 cm-3 could be inferred from the luminosity of this emission line, LHCN (1-0). Here we use observations of the Orion A molecular cloud to show that the HCN (J = 1-0) line traces much lower densities ~ 103 cm-3 in cold sections of this molecular cloud, corresponding to visual extinctions AV ≈ 6 mag. We also find that cold and dense gas in a cloud like Orion produces too little HCN emission to explain LHCN (1-0) in star forming galaxies, suggesting that galaxies might contain a hitherto unknown source of HCN emission. In our sample of molecules observed at frequencies near 100 GHz (also including 12CO, 13CO, C18O, CN, and CCH), N2H+ is the only species clearly associated with relatively dense gas. [ABSTRACT FROM AUTHOR]

The molecular clouds in the Central Molecular Zone of our Galaxy (CMZ; inner ~200 pc) show systematically higher gas than dust temperatures (>50 K vs <30 K) in recent H2CO line and dust continuum surveys. This discrepancy is puzzling since gas and dust temperatures should become equal over short times at the high densities observed in these clouds. In deep H2CO(3–2) and (4–3) observations of seven clouds in the CMZ, we detected not only large temperature differences between the clouds but also large gradients within the clouds. Comparing the temperatures and the main H2CO lines at 218 and 291 GHz, we found a positive correlation between those two parameters, indicating that turbulence plays an important role in the heating of the gas. As a follow-up, we mapped the temperature tracers CH3CCH and CH3CN in these seven clouds to derive multiple temperature estimates and test the accuracy of high gas temperatures. [ABSTRACT FROM PUBLISHER]

We report on observations of the hydroxyl radical (OH) within The HI, OH, Recombination line survey (THOR) pilot region. The region is bounded approximately between Galactic coordinates l = 29.°2 to 31.°5 and b = -1. ° 0 to +1.°0 and includes the high-mass star-forming region W43. We identify 103 maser sites, including 72 with 1612 MHz masers, 42 showing masers in either of the main-line transitions at 1665 and 1667MHzand four showing 1720MHz masers. Most maser sites with either main-line or 1720 MHz emission are associated with star formation, whereas most of the 1612 MHz masers are associated with evolved stars. We find that nearly all of the main-line maser sites are co-spatial with an infrared source, detected by GLIMPSE. We alsofind diffuse OH emission, as well as OH in absorption towards selected unresolved or partially resolved sites. Extended OH absorption is found towards the wellknown star-forming complex W43 Main. [ABSTRACT FROM AUTHOR]

Using the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared, we have performed mapping observations of the 620.701 GHz 532–441 transition of ortho-H2O within a ∼1.5 × 1.5 region encompassing the Kleinmann–Low nebula in Orion (Orion-KL), and pointed observations of that transition toward the Orion South condensation and the W49N region of high-mass star formation. Using the Effelsberg 100 m radio telescope, we obtained ancillary observations of the 22.23508 GHz 616–523 water maser transition; in the case of Orion-KL, the 621 GHz and 22 GHz observations were carried out within 10 days of each other. The 621 GHz water line emission shows clear evidence for strong maser amplification in all three sources, exhibiting narrow (∼1 km s−1 FWHM) emission features that are coincident (kinematically and/or spatially) with observed 22 GHz features. Moreover, in the case of W49N—for which observations were available at three epochs spanning a 2 yr period—the spectra exhibited variability. The observed 621 GHz/22 GHz line ratios are consistent with a maser pumping model in which the population inversions arise from the combined effects of collisional excitation and spontaneous radiative decay, and the inferred physical conditions can plausibly arise in gas heated by either dissociative or non-dissociative shocks. The collisional excitation model also predicts that the 22 GHz population inversion will be quenched at higher densities than that of the 621 GHz transition, providing a natural explanation for the observational fact that 22 GHz maser emission appears to be a necessary but insufficient condition for 621 GHz maser emission. [ABSTRACT FROM AUTHOR]

Accurate techniques that allow for the derivation of the spatial density in star formation regions are rare. A technique that has found application for the derivation of spatial densities in Galactic star formation regions utilizes the density-sensitive properties of the K-doublet transitions of formaldehyde (H2CO). In this paper, we present an extension of our survey of the formaldehyde 110-111 (λ = 6.2 cm) and 211-212 (λ = 2.1 cm) K-doublet transitions of H2CO in a sample of 56 starburst systems. We have extended the number of galaxies in which both transitions have been detected from 5 to 13. We have improved our spatial density measurements by incorporating kinetic temperatures based upon NH3 measurements of 11 of the galaxies with a total of 14 velocity components in our sample. Our spatial density measurements lie in a relatively narrow range from 104.5 to 105.5 cm-3. This implies that the Schmidt-Kennicutt relation between LIR andMdense (1) is an indication of the dense gas mass reservoir available to form stars and (2) is not directly dependent upon a higher average density driving the star formation process in the most luminous starburst galaxies. We have also used our H2CO measurements to derive two separate measures of the dense gas mass which are generally smaller, in many cases by a factor of 102-103, than those derived using HCN. This disparity suggests that H2CO traces a denser, more compact component of the giant molecular clouds in our starburst galaxy sample. We also report measurements of the rotationally excited λ = 6.3 cm2Π1/2J = 1/2 state of OH and the H111α radio recombination line taken concurrently with our H2CO 110-111 measurements. [ABSTRACT FROM AUTHOR]

We present the results from an ongoing long-term monitoring of the 22 GHz H2O maser in W49N with the 100-m Effelsberg radio telescope from February 2014 to September 2017. The unique Effelsbergs spectral line observation capability provides a broad velocity range coverage from −500 to +500 km s−1 with a spectral resolution better than 0.1 km/s. Following the strong major outburst in W49N in late 2013, we have started a long-term monitoring programme at Effelsberg. The major outburst feature (up to 80,000 Jy at VLSR − 98 km s−1) faded away by June 2014. However, we found that the site is still active with several high velocity outbursts (both blue and redshifted). Some features appear at extremely high velocities (up to ±280 km s−1) and show rapid flux variations within a 1-2 month period. This sub-year scale variability implies that the water masers could be excited by episodic shock propagation caused by a high-velocity protostellar jet. [ABSTRACT FROM AUTHOR]

We report a multi-wavelength study of a recent major flare (~ 80,000 Jy at VLSR ~ -98.1 km s−1) of the 22-GHz water maser in W49A. In February 2014, we started monthly monitoring with the Effelsberg 100-m radio telescope. In May 2014, we carried out the nearly simultaneous observations of the 22-GHz transition with selected submillimeter water transitions using the IRAM 30-m telescope (at 183 GHz) and the Atacama Pathfinder Experiment (APEX) 12-m telescope (from 321 to 475 GHz). We have also performed interferometric observations using the NRAO Very Long Baseline Array (VLBA) at 22 GHz and the Submillimeter Array (SMA) at 321 and 325 GHz. One remarkable result is the detection of very high velocity emission features in several transitions. Our data also represent its first detection of the 475-GHz water transition in a star-forming region. Studying these multiple masing transitions in conjunction with theoretical modeling of their excitation not only places strong constraints on the physical conditions of the masing gas but also allows us to study their association with the embedded massive stellar cluster in W49A. [ABSTRACT FROM PUBLISHER]