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Context. Supernovae remnants (SNRs) represent a major source of feedback from stars on the interstellar medium of galaxies. During the latest stage of supernova explosions (which lasts 10–100 kyr), shock waves produced by the initial blast modify the chemistry of gas and dust, inject kinetic energy in the surroundings, and may alter star formation characteristics. Simultaneously, γ-ray emission is generated by the interaction between the ambient medium and cosmic rays, in particular those locally accelerated in the early stages of the explosion. Aims. We aim to estimate the total molecular mass, local density, and total column density of H2 and the temperature structure in a shocked clump interacting with the supernova remnant IC443 located in a region where cosmic rays interact with the interstellar medium. Measuring the mass of the dense and neutral component of the medium is a prerequisite to understanding the chemistry, energetics, and GeV to TeV γ-ray emission. Methods. Assuming that the emission of H2 pure rotational lines is produced by a collection of gas layers with variable temperature, we compared Spitzer/IRS emission maps for the ν = 0–0 S(0) to S(7) lines with a thermal admixture model. Our description is based on a power-law distribution of thermalized components with temperatures varying between Tmin = 25 K and Tmax = 1500 K. Results. Our thermal admixture model allows the level populations of H2 to be described by a power-law distribution dN = ΛT−ΓdT, with Γ ~ 2.2−4.7. We measured a total mass MH2 = 220−80+110M⊙ across the Spitzer/IRS field of observations. Conclusions. Our analysis shows that an estimate of the cold molecular gas temperature is paramount to accurately constraining the H2 mass, although the mass remains affected by significant uncertainties due to the assumptions on the gas temperature distribution. [ABSTRACT FROM AUTHOR]

Context. Shocks are ubiquitous in the interstellar and intergalactic media, where their chemical and radiative signatures reveal the physical conditions in which they arise. Detailed astrochemical models of shocks at all velocities are necessary to understand the physics of many environments including protostellar outflows, supernova remnants, and galactic outflows. Aims. We present an accurate treatment of the self-generated ultraviolet (UV) radiation in models of intermediate velocity (VS = 25–60 km s−1), stationary, weakly magnetised, J-type, molecular shocks. We show how these UV photons modify the structure and chemical properties of shocks and quantify how the initial mechanical energy is reprocessed into line emission. Methods. We develop an iterative scheme to calculate the self-consistent UV radiation field produced by molecular shocks. The shock solutions computed with the Paris–Durham shock code are post-processed using a multi-level accelerated Λ-iteration radiative transfer algorithm to compute Lyman α, Lyman β, and two-photon continuum emission. The subsequent impacts of these photons on the ionisation and dissociation of key atomic and molecular species as well as on the heating by the photoelectric effect are calculated by taking the wavelength dependent interaction cross-sections and the fluid velocity profile into account. This leads to an accurate description of the propagation of photons and the thermochemical properties of the gas in both the postshock region and in the material ahead of the shock called the radiative precursor. With this new treatment, we analyse a grid of shock models with velocities in the range VS = 25–60 km s−1, propagating in dense (nH ≥ 104 cm−3) and shielded gas. Results. Self-absorption traps Lyα photons in a small region in the shock, though a large fraction of this emission escapes by scattering into the line wings. We find a critical velocity VS ~ 30 km s−1 above which shocks generate Lyα emission with a photon flux exceeding the flux of the standard interstellar radiation field. The escaping photons generate a warm slab of gas (T ~ 100 K) ahead of the shock front as well as pre-ionising C and S. Intermediate velocity molecular shocks are traced by bright emission of many atomic fine structure (e.g. O and S) and metastable (e.g. O and C) lines, substantive molecular emission (e.g. H2, OH, and CO), enhanced column densities of several species including CH+ and HCO+, as well as a severe destruction of H2O. As much as 13–21% of the initial kinetic energy of the shock escapes in Lyα and Lyβ photons if the dust opacity in the radiative precursor allows it. Conclusions. A rich molecular emission is produced by interstellar shocks regardless of the input mechanical energy. Atomic and molecular lines reprocess the quasi totality of the kinetic energy, allowing for the connection of observable emission to the driving source for that emission. [ABSTRACT FROM AUTHOR]

Context. The amount of data collected by spectrometers from radio to ultraviolet (UV) wavelengths opens a new era where the statistical and chemical information contained in the observations can be used concomitantly to investigate the thermodynamical state and the evolution of the interstellar medium (ISM). Aims. In this paper, we study the statistical properties of the HI-to-H2 transition observed in absorption in the local diffuse and multiphase ISM. Our goal is to identify the physical processes that control the probability of occurrence of any line of sight and the origins of the variations of the integrated molecular fraction from one line of sight to another. Methods. The turbulent diffuse ISM is modeled using the RAMSES code, which includes detailed treatments of the magnetohydrodynamics, the thermal evolution of the gas, and the chemistry of H2. The impacts of the UV radiation field, the mean density, the turbulent forcing, the integral scale, the magnetic field, and the gravity on the molecular content of the gas are explored through a parametric study that covers a wide range of physical conditions. The statistics of the HI-to-H2 transition are interpreted through analytical prescriptions and compared with the observations using a modified and robust version of the Kolmogorov-Smirnov test. Results. The analysis of the observed background sources shows that the lengths of the lines of sight follow a flat distribution in logarithmic scale from ~100 pc to ~3 kpc. Without taking into account any variation of the parameters along a line of sight or from one line of sight to another, the results of one simulation, convolved with the distribution of distances of the observational sample, are able to simultaneously explain the position, the width, the dispersion, and most of the statistical properties of the HI-to-H2 transition observed in the local ISM. The tightest agreement is obtained for a neutral diffuse gas modeled over ~200 pc, with a mean density n̅H̅ = 1−2 $\overline{n_{\textrm{H}}} =1{-}2$ n H ¯ = 1 − 2 cm−3, illuminated by the standard interstellar UV radiation field, and stirred up by a large-scale compressive turbulent forcing. Within this configuration, the 2D probability histogram of the column densities of H and H2, poetically called the kingfisher diagram, is remarkably stable and is almost unaltered by gravity, the strength of the turbulent forcing, the resolution of the simulation, or the strength of the magnetic field Bx, as long as Bx < 4 μG. The weak effect of the resolution and our analytical prescription suggest that the column densities of HI are likely built up in large-scale warm neutral medium and cold neutral medium (CNM) structures correlated in density over ~20 pc and ~10 pc, respectively, while those of H2 are built up in CNM structures between ~3 and ~10 pc. Conclusions. Combining the chemical and statistical information contained in the observations of HI and H2 sheds new light on the study of the diffuse matter. Applying this new tool to several atomic and molecular species is a promising perspective to understanding the effects of turbulence, magnetic field, thermal instability, and gravity on the formation and evolution of molecular clouds. [ABSTRACT FROM AUTHOR]

The interstellar medium (ISM) is typically a hostile environment: cold, dilute and irradiated. Nevertheless, it appears very fertile for molecules. The localized heating resulting from turbulence dissipation is a possible channel to produce and excite molecules. However, large-scale simulations cannot resolve the dissipative scales of the ISM. Here, we present two-dimensional small-scale simulations of decaying hydrodynamic turbulence using the chemses code, with fully resolved viscous dissipation, time-dependent heating, cooling, chemistry and excitation of a few rotational levels of H2. We show that molecules are produced and excited in the wake of strong dissipation ridges. We carefully identify shocks and we assess their statistics and contribution to the molecular yields and excitation. We find that the formation of molecules is strongly linked to increased density as a result of shock compression and to the opening of endothermic chemical routes because of higher temperatures. We identify a new channel for molecule production via H2 excitation, illustrated by CH+ yields in our simulations. Despite low temperatures and the absence of magnetic fields (favouring CH+ production through ion-neutral velocity drifts), the excitation of the first few rotational levels of H2 shrinks the energy gap to form CH+. The present study demonstrates how dissipative chemistry can be modelled by statistical collections of one-dimensional steady-state shocks. Thus, the excitation of higher J levels of H2 is likely to be a direct signature of turbulence dissipation, and an indirect probe for molecule formation. We hope these results will help to bring new tools and ideas for the interpretation of current observations of H2 rotational lines carried out using the Stratospheric Observatory for Infrared Astronomy (SOFIA), and pave the way for a better understanding of the high-resolution mapping of H2 emission by future instruments, such as the James Webb Space Telescope and the Space Infrared Telescope for Cosmology and Astrophysics. [ABSTRACT FROM AUTHOR]

Context. The recent discovery of excited molecules in starburst galaxies observed with ALMA and the Herschel space telescope has highlighted the necessity to understand the relative contributions of radiative and mechanical energies in the formation of molecular lines and explore the conundrum of turbulent gas bred in the wake of galactic outflows. Aims. The goal of the paper is to present a detailed study of the propagation of low velocity (5–25 km s−1) stationary molecular shocks in environments illuminated by an external ultraviolet (UV) radiation field. In particular, we intend to show how the structure, dynamics, energetics, and chemical properties of shocks are modified by UV photons and to estimate how efficiently shocks can produce line emission. Methods. We implemented several key physico-chemical processes in the Paris-Durham shock code to improve the treatment of the radiative transfer and its impact on dust and gas particles. We propose a new integration algorithm to find the steady-state solutions of magnetohydrodynamics equations in a range of parameters in which the fluid evolves from a supersonic to a subsonic regime. We explored the resulting code over a wide range of physical conditions, which encompass diffuse interstellar clouds and hot and dense photon-dominated regions. Results. We find that C-type shock conditions cease to exist as soon as G0 > 0.2 (nH/cm−3)1/2 $G_0\,{>}\,0.2\,\, ({n_{\textrm{H}}}/{\textrm{cm}^{-3}})^{1/2}$ G 0   >   0.2    (n H / cm − 3) 1 / 2 . Such conditions trigger the emergence of another category of stationary solutions, called C*-type and CJ-type shocks, in which the shocked gas is momentarily subsonic along its trajectory. These solutions are shown to be unique for a given set of physical conditions and correspond to dissipative structures in which the gas is heated up to temperatures comprised between those found in C-type and adiabatic J-type shocks. High temperatures combined with the ambient UV field favour the production or excitation of a few molecular species to the detriment of others, hence leading to specific spectroscopic tracers such as rovibrational lines of H2 and rotational lines of CH+. Unexpectedly, the rotational lines of CH+ may carry as much as several percent of the shock kinetic energy. Conclusions. Ultraviolet photons are found to strongly modify the way the mechanical energy of interstellar shocks is processed and radiated away. In spite of what intuition dictates, a strong external UV radiation field boosts the efficiency of low velocity interstellar shocks in the production of several molecular lines which become evident tracers of turbulent dissipation. [ABSTRACT FROM AUTHOR]

Context: Protostellar jets and outflows are key features of the star-formation process, and primary processes of the feedback of young stars on the interstellar medium. Understanding the underlying shocks is necessary to explain how jet and outflow systems are launched, and to quantify their chemical and energetic impacts on the surrounding medium. Aims: We performed a high-spectral resolution study of the [OI]63μm emission in the outflow of the intermediate-mass Class 0 protostar Cep E-mm. The goal is to determine the structure of the outflow, to constrain the chemical conditions in the various components, and to understand the nature of the underlying shocks, thus probing the origin of the mass-loss phenomenon. Methods: We present observations of the OI ³P1 → ³P2, OH between ²Π1/2J = 3/2 and J = 1/2 at 1837.8 GHz, and CO (16-15) lines with the GREAT receiver onboard SOFIA towards three positions in the Cep E protostellar outflow: Cep E-mm (the driving protostar), Cep E-BI (in the southern lobe), and Cep E-BII (the terminal position in the southern lobe). Results: The CO (16-15) line is detected at all three positions. The [OI]63μm line is detected in Cep E-BI and BII, whereas the OH line is not detected. In Cep E-BII, we identify three kinematical components in OI and CO. These were already detected in CO transitions and relate to spatial components: the jet, the HH377 terminal bow-shock, and the outflow cavity. We measure line temperature and line integrated intensity ratios for all components. The OI column density is higher in the outflow cavity than in the jet, which itself is higher than in the terminal shock. The terminal shock is the region where the abundance ratio of OI to CO is the lowest (about 0.2), whereas the jet component is atomic (N(OI)/N(CO)~2.7). In the jet, we compare the [OI]63μm observations with shock models that successfully fit the integrated intensity of 10 CO lines. We find that these models most likely do not fit the [OI]63μm data. Conclusions: The high intensity of OI emission points towards the propagation of additional dissociative or alternative FUV-irradiated shocks, where the illumination comes from the shock itself. A picture emerges from the sample of low-to-high mass protostellar outflows, where similar observations have been performed, with the effects of illumination increasing with the mass of the protostar. These findings need confirmation with more observational constraints and a larger sample. [ABSTRACT FROM AUTHOR]

Context. Tens of light hydrides and small molecules have now been detected over several hundreds sightlines sampling the diffuse interstellar medium (ISM) in both the solar neighbourhood and the inner Galactic disk. They provide unprecedented statistics on the first steps of chemistry in the diffuse gas. Aims. These new data confirm the limitations of the traditional chemical pathways driven by the UV photons and the cosmic rays (CR) and the need for additional energy sources, such as turbulent dissipation, to open highly endoenergetic formation routes. The goal of the present paper is to further investigate the link between specific species and the properties of the turbulent cascade in particular its space-time intermittency. Methods. We have analysed ten different atomic and molecular species in the framework of the updated model of turbulent dissipation regions (TDR). We study the influence on the abundances of these species of parameters specific to chemistry (density, UV field, and CR ionisation rate) and those linked to turbulence (the average turbulent dissipation rate, the dissipation timescale, and the ion-neutral velocity drift in the regions of dissipation). Results. The most sensitive tracers of turbulent dissipation are the abundances of CH+ and SH+, and the column densities of the J = 3, 4, 5 rotational levels of H2. The abundances of CO, HCO+, and the intensity of the 158 μm [CII] emission line are significantly enhanced by turbulent dissipation. The vast diversity of chemical pathways allows the independent determinations of free parameters never estimated before: an upper limit to the average turbulent dissipation rate, ε ≲ 10-23 erg cm-3 s-1 for nH = 20 cm-3, from the CH+ abundance; an upper limit to the ion-neutral velocity drift, vin ≲ 3.5 kms-1, from the SH+ to CH+ abundance ratio; and a range of dissipation timescales, 100 ≲ τv ≲ 1000 yr, from the CO to HCO+ abundance ratio. For the first time, we reproduce the large abundances of CO observed on diffuse lines of sight, and we show that CO may be abundant even in regions with UV-shieldings as low as 5 × 10-3 mag. The best range of parameters also reproduces the abundance ratios of OH, C2H, and H2O to HCO+ and are consistent with the known properties of the turbulent cascade in the Galactic diffuse ISM. Conclusions. Our results disclose an unexpected link between the dissipation of turbulence and the emergence of molecular richness in the diffuse ISM. Some species, such as CH+ or SH+, turn out to be unique tracers of the energy trail in the ISM. In spite of some degeneracy, the properties of the turbulent cascade, down to dissipation, can be captured through specific molecular abundances. [ABSTRACT FROM AUTHOR]

Context. Large-scale motions in galaxies (supernovae explosions, galaxy collisions, galactic shear etc.) generate turbulence, which allows a fraction of the available kinetic energy to cascade down to small scales before it is dissipated. Aims. We establish and quantify the diagnostics of turbulent dissipation in mildly irradiated diffuse gas in the specific context of shock structures. Methods. We incorporated the basic physics of photon-dominated regions into a state-of-the-art steady-state shock code. We examined the chemical and emission properties of mildly irradiated (G0 = 1) magnetised shocks in diffuse media (nH = 102 to 104 cm-3) at lowto moderate velocities (from 3 to 40 km s-1). Results. The formation of some molecules relies on endoergic reactions. Their abundances in J-type shocks are enhanced by several orders of magnitude for shock velocities as low as 7 km s-1. Otherwise most chemical properties of J-type shocks vary over less than an order of magnitude between velocities from about 7 to about 30 km s-1, where H2 dissociation sets in. C-type shocks display a more gradual molecular enhancement with increasing shock velocity. We quantified the energy flux budget (fluxes of kinetic, radiated and magnetic energies) with emphasis on the main cooling lines of the cold interstellar medium. Their sensitivity to shock velocity is such that it allows observations to constrain statistical distributions of shock velocities. We fitted various probability distribution functions (PDFs) of shock velocities to spectroscopic observations of the galaxy-wide shock in Stephan's Quintet and of a Galactic line of sight which samples diffuse molecular gas in Chamaeleon. In both cases, low velocities bear the greatest statistical weight and the PDF is consistent with a bimodal distribution. In the very low velocity shocks (below 5 km s-1), dissipation is due to ion-neutral friction and it powers H2 low-energy transitions and atomic lines. In moderate velocity shocks (20 km s-1 and above), the dissipation is due to viscous heating and accounts for most of the molecular emission. In our interpretation a significant fraction of the gas in the line of sight is shocked (from 4% to 66%). For example, C+ emission may trace shocks in UV irradiated gas where C+ is the dominant carbon species. Conclusions. Low- and moderate velocity shocks are important in shaping the chemical composition and excitation state of the interstellar gas. This allows one to probe the statistical distribution of shock velocities in interstellar turbulence. [ABSTRACT FROM AUTHOR]