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9 pags., 3 figs., Polar stratospheric ozone has decreased since the 1970s due to anthropogenic emissions of chlorofluorocarbons and halons, resulting in the formation of an ozone hole over Antarctica. The effects of the ozone hole and the associated increase in incoming UV radiation on terrestrial and marine ecosystems are well established; however, the impact on geochemical cycles of ice photoactive elements, such as iodine, remains mostly unexplored. Here, we present the first iodine record from the inner Antarctic Plateau (Dome C) that covers approximately the last 212 years (1800-2012 CE). Our results show that the iodine concentration in ice remained constant during the pre-ozone hole period (1800-1974 CE) but has declined twofold since the onset of the ozone hole era (~1975 CE), closely tracking the total ozone evolution over Antarctica. Based on ice core observations, laboratory measurements and chemistry-climate model simulations, we propose that the iodine decrease since ~1975 is caused by enhanced iodine re-emission from snowpack due to the ozone hole-driven increase in UV radiation reaching the Antarctic Plateau. These findings suggest the potential for ice core iodine records from the inner Antarctic Plateau to be as an archive for past stratospheric ozone trends., This project received funding from the European Union’s Horizon 2020 Research and Innovation program under grant agreement no. 689443 via project iCUPE (Integrative and Comprehensive Understanding on Polar Environments), part of the European Commission (ERA-PLANET) and by the “Programma Nazionale per la Ricerca in Antartide” (PNRA, project number PNRA16_00295). This study also received funding from the European Research Council Executive Agency under the European Union’s Horizon 2020 Research and Innovation programme (Project ‘ERC-2016-COG 726349 CLIMAHAL’). NCAR is sponsored by the National Science Foundation under Grant Number 1852977. R.P.F. would like to express thanks for the financial support from CONICET-UNCuyo (SIIP-06/M111) and ANPCyT (PICT 2015-0714). This research was also supported by the Korea Polar Research Institute (KOPRI) project (PE20030) and by the Grant to Department of Science, Roma Tre University (MIUR-Italy Dipartimenti di Eccellenza)

17 pags., 4 figs., 2 tabs., Sea ice plays a pivotal role in Earth's climate and its past reconstruction is crucial to investigate the connections and feedbacks with the other components of the climate system. Among the available archives that store information of past sea ice are marine and ice cores. Recent studies on the IP biomarker extracted from marine sediments has shown great skill to infer past changes of Arctic sea ice. In ice matrixes, sodium, bromine and iodine have shown potential to store the fingerprint of sea ice presence. The development of an unambiguous sea ice proxy from ice cores, however, has proven to be a challenging task especially in the Arctic realm. In this work we analyze the sodium, bromine and iodine records in the RECAP ice core, coastal eastern Greenland, to investigate the sea ice variability in the northern North Atlantic Ocean through the last 11,000 years of the current interglacial, i.e. the Holocene. We compare the RECAP records with marine sea ice proxy records available from the northern North Atlantic. We suggest that RECAP sodium concentrations can be associated with variability of sea ice extent, while the bromine-to-sodium ratios and iodine are associated respectively with seasonal sea ice and bioproductivity from open ocean and fresh sea ice surfaces. According to our interpretation, we find that sea ice was at its lowest extent and seasonal in nature during the early Holocene in all regions of the North Atlantic. Increasing sea ice signals are seen from ca. 8–9 ka b2k, in line with long-term Holocene cooling. The increasing sea ice trend appears uninterrupted in the Fram Strait and North Iceland while reaching a maximum ca. 5 ka b2k in the East Greenland region. Sea ice modifications during the last 5000 years display great variability in East Greenland with intermediate conditions between the early and mid Holocene, possibly associated with local fjord dynamics. The last sea ice maximum was reached across all regions 1000 years b2k., The RECAP ice coring effort was financed by the Danish Research Council through a Sapere Aude grant, the NSF through the Division of Polar Programs, the Alfred Wegener Institute, and the European Research Council under the European Community's Seventh Framework Programme (FP7/2007e2013)/ERC grant agreement The RECAP ice coring effort was financed by the Danish Research Council through a Sapere Aude grant, the NSF through the Division of Polar Programs, the Alfred Wegener Institute, and the European Research Council under the European Community's Seventh Framework Programme (FP7/2007e2013)/ERC grant agreement 610055 through the Ice2Ice project. Additional funding support for the paper has been provided by the Centre for Climate Dynamics at the Bjerknes Centre. through the Ice2Ice project. Additional funding support for the paper has been provided by the Centre for Climate Dynamics at the Bjerknes Centre.

The biogeochemistry of iodine in temperate coastal ecosystems is largely mediated by macroalgae, which act as a major biological sink and source of iodine. Their capacity to accumulate, retain and release iodine has been associated with abiotic and biotic stressors, but quantitative information is limited. We evaluated the seasonal iodine retention capacity of eleven macroalgal species belonging to different systematic groups, collected from two sites in Ireland. Iodine accumulation and retention were then further quantified in Fucus vesiculosus and Laminaria digitata in relation to I- concentrations in seawater and temperature. In general, iodine contents were ~101 -102 μmol · (g dw)-1 for Laminariales, 100 -101 μmol · (g dw)-1 for Fucales, 10-1 -100 μmol · (g dw)-1 for Rhodophyta, and 10-1 μmol · (g dw)-1 for Chlorophyta. Typically, algal iodine contents were above average in winter and below average in summer. Iodine accumulation in F. vesiculosus and L. digitata depended on I- availability and followed the Michaelis-Menten kinetic. The ratio of maximum accumulation rate to half accumulation coefficient (ρmax : Kt ) was 2.4 times higher for F. vesiculosus than for L. digitata, suggesting that F. vesiculosus was more efficient in iodine accumulation. Both species exhibited a temperature-dependent net loss of iodine, and only an exposure to sufficient external I- concentrations compensated for this loss. This study revealed that both environmental (e.g., I- in seawater, temperature) and organismal (e.g., the status of the iodine storage pool) variables determine retention and variability in iodine in temperate seaweeds.

An international comparison of two I-2-stabilized frequency-doubled Nd:YAG lasers at lambda = 532 nm has been performed between the Istituto di Metrologia ``G. Colonnetti'' (IMGC)/Politecnico di Milano (PoliMI) and the Physikalisch-Technische Bundesanstalt (PTB). Both lasers used saturated absorption of the P(54) 32-0 iodine transition as a frequency reference. The signals for stabilizing the lasers were obtained using the frequency modulation spectroscopy technique with an external iodine cell. A minimum value for the relative Allan standard deviation of 7 x 10(-14) was reached after an integration time of 40 s. The hyperfine line separations were measured by the beat-frequency method and compared with the frequency values recently reported by Ye and co-workers. Three different iodine cells were investigated. The range of frequency differences for the iodine cells IMGC(QU) and PTB1/98 between the two lasers was from -9 kHz to 7.3 kHz with a mean of 1.2 kHz and a standard deviation of 3.5 kHz. Taking into account the measured frequency offsets of the different iodine cells, the evaluated frequency repeatability of the optical standards was within 2.5 kHz.

We present investigations of the reactive iodine species (RIS) IO, OIO and I2 in a coastal region from a field campaign simultaneously employing active long path differential optical absorption spectroscopy (LP-DOAS) as well as passive multi-axis differential optical absorption spectroscopy (MAX-DOAS). The campaign took place at the Martin Ryan Institute (MRI) in Carna, County Galway at the Irish West Coast about 6 km south-east of the atmospheric research station Mace Head in summer 2007. In order to study the horizontal distribution of the trace gases of interest, we established two almost parallel active LP-DOAS light paths, the shorter of 1034 m length just crossing the intertidal area, whereas the longer one of 3946 m length also crossed open water during periods of low tide. In addition we operated two passive Mini-MAX-DOAS instruments with the same viewing direction. While neither OIO nor I2 could be unambiguously identified with any of the instruments, IO could be detected with active as well as passive DOAS. The IO column densities seen at both active LP-DOAS light paths are almost the same. Thus it can be concluded that coastal IO is almost exclusively located in the intertidal area, where we detected mixing ratios of up to 29±8.8 ppt (equivalent to pmol/mol). Nucleation events with particle concentrations of 106 cm−3 particles were observed each day correlating with high IO mixing ratios. Therefore we feel that our detected IO concentrations confirm the results of model studies, which state that in order to explain such particle bursts, IO mixing ratios of 50 to 100 ppt in so called "hot-spots" are required.