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We implement a new observational method for mapping the aliphatic hydrocarbon content in the solid phase in our Galaxy, based on spectrophotometric imaging of the 3.4  |$\mu$| m absorption feature from interstellar dust. We previously demonstrated this method in a field including the Galactic Centre cluster. We applied the method to a new field in the Galactic Centre where the 3.4  |$\mu$| m absorption feature has not been previously measured and we extended the measurements to a field in the Galactic plane to sample the diffuse local interstellar medium, where the 3.4  |$\mu$| m absorption feature has been previously measured. We have analysed 3.4  |$\mu$| m optical depth and aliphatic hydrocarbon column density maps for these fields. Optical depths are found to be reasonably uniform in each field, without large source-to-source variations. There is, however, a weak trend towards increasing optical depth in a direction towards b  = 0° in the Galactic Centre. The mean value of column densities and abundances for aliphatic hydrocarbon were found to be about several |$\rm \times 10^{18} \, cm^{-2}$| and several tens × 10−6, respectively for the new sightlines in the Galactic plane. We conclude that at least 10–20 per cent of the carbon in the Galactic plane lies in aliphatic form. [ABSTRACT FROM AUTHOR]

In the interstellar medium, the cosmic elemental carbon abundance includes the total carbon in both gas and solid phases. The aim of the study was to trial a new method for measuring the amount and distribution of aliphatic carbon within interstellar dust over wide fields of view of our Galaxy. This method is based on the measurement of the 3.4- |$\mu$| m absorption feature from aliphatic carbonaceous matter. This can readily be achieved for single sources using infrared (IR) spectrometers. However, making such measurements over wide fields requires an imaging IR camera, equipped with narrow-band filters that are able to sample the spectrum. While this cannot produce as good a determination of the spectra, the technique can be applied to potentially tens to hundreds of sources simultaneously, over the field of view of the camera. We examined this method for a field in the centre of the Galaxy, and produced a map showing the variation of 3.4- |$\mu$| m optical depth across it. [ABSTRACT FROM AUTHOR]

Context. Recent attention has been directed on closed-shell aromatic cations as potential carriers of the diffuse interstellar bands. The spectra of mass-selected, matrix-isolated benzylium, and tropylium cations were recently reported. The visible spectrum of benzylium exhibits a large Franck-Condon (FC) envelope, inconsistent with diffuse interstellar band carriers. Aims. We perform a computational analysis of the experimentally studied benzylium spectrum before extending the methods to a range of larger, closed-shell aromatic cations to determine the potential for this class of systems as diffuse interstellar band carriers. Methods. Density functional theory (DFT), time-dependant ((TD)DFT), and multi-configurational self-consistent field second-order perturbation theory (MRPT2) methods in concert with multidimensional FC analysis is used to model the benzylium spectrum. These methods are extended to larger closed-shell aromatic hydrocarbon cations derived from resonance-stabilized radicals, which are predicted to show strong S0 → Sn transitions in the visible region. The ionization energies of a range of these systems are also calculated by DFT. Results. The simulated benzylium spectrum was found to yield excellent agreement with the experimental spectrum showing an extended progression in a low frequency (510 cm-1) ring distortion mode. The FC progression was found to be significantly quenched in the larger species: 1-indanylium, 1-naphthylmethylium, and fluorenium. Excitation and ionization energies of the closed-shell cations were found to be consistent with diffuse interstellar band carriers, with the former lying in the visible range and the latter straddling the Lyman limit in the 13-14 eV range. Conclusions. Large closed-shell polycyclic aromatic hydrocarbon cations remain viable candidate carriers of the diffuse interstellar bands. [ABSTRACT FROM AUTHOR]