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Context. The diffuse interstellar bands (DIBs) are a set of hundreds of unidentified absorption features that appear almost ubiquitously throughout the interstellar medium. Most DIBs appear at optical wavelengths, but some are in the near-infrared. Aims. We aim to characterise near-infrared DIBs at high spectral resolving power towards multiple targets. Methods. We observed 76 early-type stars at a resolving power of 50 000 (velocity resolution 6 km s1) and signal-to-noise ratios of several hundreds using the CRyogenic high-resolution InfraRed Echelle Spectrograph (CRIRES). These data allow us to investigate the DIBs around 1318.1, 1527.4, 1561.1, 1565.1, 1567.0, 1574.4, and 1624.2 nm. We detected a total of six DIB features and 17 likely stellar features through comparisons with a model spectrum computed with CMFGEN. Additionally, we measured equivalent widths of the DIBs at 1318.1 and 1527.4 nm using observations with X-shooter towards ten very highly reddened (3:2 < E(BV) < 6:5) Cepheid variable stars and towards four stars observed at low values of precipitable water vapour as well as by using other archive data. Results. We measured correlations (correlation coefficient r 0:73-0.96, depending on the subsample used) between DIB equivalent width and reddening for the DIBs at 1318.1, 1561.1, 1565.1, and 1567.0 nm. Comparing the near-infrared DIBs with 50 of the strongest optical DIBs, we find correlations r > 0:8 between the 1318, 1527, 1561, 1565, and 1567 nm and the optical DIBs 5705, 5780, 6203, 6283, and 6269 Å. The 5797 Å DIB is less well correlated with the near-infrared DIBs. The DIB at 9632.1 Å, which is likely C+ 60, is not well correlated with the 1318.1 nm DIB. Partial correlation coefficients using E(B-V) as the covariate were also determined. For stars earlier than B2, the 1318.1 nm DIB is affected by an emission line on its blue wing that is likely stellar in nature, although we cannot rule out an interstellar or circumstellar origin for this line caused by, for example, a DIB in emission. The 1318.1 nm DIB also has an extended red wing. The line is reasonably well fitted by two Gaussian components, although neither the component equivalent width (EW) ratios nor the separation between components are obviously correlated with such indicators as --5780/5797 and reddening. The EW at 1318 nm correlates with H I with EW(1318 nm)/E(B V) decreasing with f (H2). Five pairs of stars within one arcmin of each other show very similar 1318.1 nm DIB profiles. Possible variation in the 1318.1 nm feature is seen between HD145501 and HD145502 (separated by 41 arcsec, equivalent to 7200 au) and HD168607 and HD168625 (separated by 67 arcsec, equivalent to 0.52 pc on the plane of the sky). Seventeen sightlines have repeat CRIRES observations separated by six to 14 months, and two sightlines have repeat X-shooter observations separated by 9.9 yr. No time variability was detected in the 1318.1 nm DIB in the CRIRES data nor in the 5780.5 Å, 5797.1 Å, 1318.1 nm, and 1527.4 nm DIBs. Tentative time variation is observed in the C+ 60 DIBs at 9577 and 9632 Å towards HD183143, although it is very close to the noise level and requires confirmation. Conclusions. The Near Infrared (NIR) DIBs observed occur more in more UV-irradiated regions than the 5797 Å DIB allowing the study of heavily reddened sightlines. Future searches for time variability in DIBs will require either higher quality data, larger intervals between epochs, or both. [ABSTRACT FROM AUTHOR]

It is well known that the dust properties of the di use interstellar medium exhibit variations towards di erent sight-lines on a large scale.We have investigated the variability of the dust characteristics on a small scale and from cloud-to-cloud.We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (⩾6 nm) silicates of prolate shape account for the observed polarisation. For 32 sight-lines we complement our data set with UVES archive high-resolution spectra, which enable us to establish the presence of single-cloud or multiple-clouds towards individual sight-lines. We find that the majority of these 35 sight-lines intersect two or more clouds, while eight of them are dominated by a single absorbing cloud. We confirm several correlations between extinction and parameters of the Serkowski law with dust parameters, but we also find previously undetected correlations between these parameters that are valid only in single-cloud sight-lines. We find that interstellar polarisation from multiple-clouds is smaller than from single-cloud sightlines, showing that the presence of a second or more clouds depolarises the incoming radiation. We find large variations of the dust characteristics from cloud-to-cloud. However, when we average a suffciently large number of clouds in single-cloud or multiple-cloud sight-lines, we always retrieve similar mean dust parameters. The typical dust abundances of the single-cloud cases are [C]/[H] = 92 ppm and [Si]/[H] = 20 ppm. [ABSTRACT FROM AUTHOR]

Context. Photodissociation regions (PDRs) contain a large portion of all of the interstellar matter in galaxies. Classical examples include the boundaries between ionized regions and molecular clouds in regions of massive star-formation, marking the point where all of the photons that are energetic enough to ionize hydrogen have been absorbed. Aims. To determine the physical properties of the PDRs associated with the star-forming regions IRAS 23133+6050 and S 106 and present them in the context of other Galactic PDRs associated with massive star-forming regions. Methods. We employ Herschel PACS and SPIRE spectroscopic observations to construct a full 55-650 μm spectrum of each object from which we measure the PDR cooling lines, other fine- structure lines, CO lines, and the total far-infrared flux. These measurements (and combinations thereof) are then compared to standard PDR models. Subsequently, detailed numerical PDR models are compared to these predictions, yielding additional insight into the dominant thermal processes in the PDRs and their structures. Results. We find that the PDRs of each object are very similar and can be characterized by a two-phase PDR model with a very dense, highly UV irradiated phase (n ∼ 106 cm-3, G0 ∼ 105) interspersed within a lower density, weaker radiation field phase (n ∼ 104 cm-3, G0 ∼ 104). We employed two different numerical models to investigate the data. We first used RADEX models to fit the peak of the 12CO ladder, which in conjunction with the properties derived, yielded a temperature of around 300 K. Subsequent numerical modeling with a full PDR model revealed that the dense phase has a filling factor of around 0.6 in both objects. The shape of the 12CO ladder was consistent with these components, with heating dominated by grain photoelectric heating. An extra excitation component for the heightest-J lines (J > 20) is required for S 106. [ABSTRACT FROM AUTHOR]

We compare and analyze the Spitzer mid-infrared spectrum of three fullerene-rich planetary nebulae in the Milky Way and the Magellanic Clouds: Tc1, SMP SMC 16, and SMP LMC 56. The three planetary nebulae share many spectroscopic similarities. The strongest circumstellar emission bands correspond to the infrared active vibrational modes of the fullerene species C60 and little or no emission is present from polycyclic aromatic hydrocarbons. The strengths of the fullerene bands in the three planetary nebulae are very similar, while the ratios of the [Ne III]15.5 μm/[Ne II]12.8 μm fine structure lines, an indicator of the strength of the radiation field, are markedly different. This raises questions about their excitation mechanism and we compare the fullerene emission to fluorescent and thermal models. In addition, the spectra show other interesting and common features, most notably in the 6-9 μm region, where a broad plateau with substructure dominates the emission. These features have previously been associated with mixtures of aromatic/aliphatic hydrocarbon solids. We hypothesize on the origin of this band, which is likely related to the fullerene formation mechanism, and compare it with modeled hydrogenated amorphous carbon that present emission in this region. [ABSTRACT FROM AUTHOR]

Our understanding on the role of amorphous carbon in the interstellar medium to form complex structures, such as carbon nanotube/graphene/fullerene, is limited to date. We have investigated how shocks may induce physico-chemical transformation in amorphous carbon by subjecting samples of carbon nanopowder to high-temperature shocks, ∼7300 K, in a hydrogen-free environment for about 2 ms using a shock tube. The shock conditions achieved in the laboratory mimics low velocity interstellar shocks. Post shock samples were analyzed using Raman Spectroscopy and High Resolution – Transmission Electron Microscopy. We have found compelling evidence for the formation of carbon nanotube, graphene, and various other carbon nanostructures induced by the shock. Our results show that shocks in the interstellar medium can provide important chemical pathways to the formation of fullerenes and suggests that other carbonaceous structures may be present as well. [ABSTRACT FROM AUTHOR]