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In this paper, a temperature sensing scheme with a miniature MZI structure based on the principle of inter-mode interference is proposed. The sensing structure mainly comprises single mode–coreless–multimode–coreless–single mode fibers (SCMCSs), which have been welded together, with different core diameters. The light beam has been expanded after passing through the coreless optical fiber and is then coupled into a multimode optical fiber. Due to the light passing through the cladding and core mode of the multimode optical fiber with different optical paths, a Mach–Zehnder interferometer is formed. Moreover, due to the thermo-optic and thermal expansion effects of optical fibers, the inter-mode interference spectrum of a multimode fiber shifts when the external temperature changes. Through theoretical analysis, it is found that the change in the length of the sensing fiber during temperature detection has less of an effect on the sensitivity of the sensing structure. During the experiment, temperature changes between 20 and 100 °C are measured at sensing fiber lengths of 1.5 cm, 2.0 cm, 2.5 cm, 3.0 cm, 3.5 cm, and 4.0 cm, respectively, and the corresponding sensitivities are 65.98 pm/°C, 72.70 pm/°C, 67.75 pm/°C, 66.63 pm/°C, 74.80 pm/°C, and 72.07 pm/°C, respectively. All the corresponding correlation coefficients are above 0.9965. The experimental results indicate that in the case of a significant change in the length of the sensing fiber, the sensitivity of the sensing structure changes slightly, which is consistent with the theory that the temperature sensitivity is minimally affected by a change in the length of the sensing fiber. Therefore, the effect of the length on sensitivity in a cascade-based fiber structure is well solved. The sensing scheme has an extensive detection range, small size, good linearity, simple structure, low cost, and high sensitivity. It has a good development prospect in some detection-related application fields. [ABSTRACT FROM AUTHOR]