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Due to the growing interest in environmental concerns, synthetic and natural esters have become the key focus of the picture in the last two decades as insulating fluids for high-voltage equipment. This is because, unlike mineral oil, ester liquids are biodegradable, nontoxic, and safe for the environment and human health. These fluids are derived from renewable sources and have high fire resistance. However, synthetic and natural ester fluids are still used in a rather limited number of electrical equipment for several reasons (high cost, high viscosity and density, increased tendency toward electrostatic charge, faster propagation of streamers in an inhomogeneous electric field, etc.). Besides, a huge amount of equipment is filled with mineral oils. The massive replacement of oil-filled equipment with natural or synthetic esters may be extremely expensive to utilities and transformer owners. In addition, in the event of partial or complete retrofilling of mineral oil with an ester fluid, the equipment may evidently contain a mixture of two insulating fluids, and therefore, demanding the scope for research on mixed insulating liquids. The intent of this article is to present a comprehensive review of the literature on the blend of mineral oil and other alternative dielectric fluids. The critical research progresses, highlights, and challenges related to mixed liquids along with significant tutorial elements as well as some analyses are discussed. This review should be useful for researchers, utilities, and transformer owners concerned with ester liquids and retrofilling aspects. [ABSTRACT FROM AUTHOR]

Application of low pour point esters in transformers insulation serving in cold climatic regions is still a challenge. To address this concern, the pre-breakdown and breakdown analyses of thermally aged low pour point ester fluids are investigated. The breakdown measurements are performed at different aging conditions under AC stress. Needle-plane electrode geometry (with varying radii of the tip) is employed since this configuration is necessary for any practical diagnostic based on partial discharge (PD). This allows studying the effect of the chemical impurities (aging by-products) as assessed by some physicochemical properties (acidity, particles count, turbidity, and dissolved decay products) on the partial discharge and breakdown characteristics. The complete analysis is carried out for liquids having the pour points less than -50 °C, including a mineral oil (MO) and two synthetic ester liquids (SE1 and SE2). Changes in the streamer properties, such as partial discharge inception voltage (PDIV), breakdown-streamer inception voltage, and breakdown voltage are reported as a function of the needle tip radius and aging condition. It is observed that the breakdown properties of SE1 are better than that of SE2 and are comparable to MO. To understand the influence of aging on the PD, correlations between decay products, acidity, BSIV, and PDIV are reported. It is observed that the acidity and concentration of decay products directly impact the PD characteristics. [ABSTRACT FROM AUTHOR]

Natural ester dielectric fluids are being used as alternatives for mineral insulating oils in oil-filled power apparatuses. Although partial discharges (PDs) are recognised as one of the main causes of degradation of dielectrics used in power equipment, their characteristic voltages appear to be temperature-dependent. In this contribution, the pre-breakdown and breakdown behaviour of two natural ester fluids, extracted from canola oil (NE1) and soybean oil (NE2) is reported. To assess the effectiveness of the temperature dependence, −5, 0, and + 20°C have been identified as test temperatures. It was found that the different pre-breakdown and breakdown characteristic voltages increase with increasing temperature for both types of esters. The delay time is always longer for canola oil when compared to soybean oil regardless of the test temperature. The analysis of the average propagation velocity of NE1 and NE2 indicates that PDs propagate faster in NE2 than in NE1. The field strength at the tip of the needle electrode during the inception of the streamers leading to breakdown indicates that streamers in both oils are propagating in the slow mode. It is found that the temperature has a significant influence on the PDs' parameters for both fluids. [ABSTRACT FROM AUTHOR]

In view of the contemporary scenario and importance of alternative liquid dielectrics, IEEE DEIS Technical Committee on Liquid Dielectrics laid emphasis on pre-breakdown phenomena of ester dielectric fluids. The present article reports the background knowledge on the breakdown theories and behavior of streamers in insulating oils. The major influencing properties of the streamers aroused in liquid insulating systems are discussed keeping in view of the ester based dielectric fluids. Importantly, modelling of streamers, testing approaches, and review of pre-breakdown phenomena in ester dielectric fluids has been presented. [ABSTRACT FROM AUTHOR]

In this article, two synthetic esters along with a natural ester are investigated to monitor the generation of colloidal and dissolved decay particles under thermal aging. The thermal aging of the oils is carried out as per a modified ASTM D1934 in the presence of cellulose and copper at elevated temperatures. Later, the colloidal and dissolved decay particles are monitored as per ASTM D1698 (centrifuge treatment) and ASTM D7150 (Fuller's earth filtration), respectively. The aged and treated dielectric liquids are characterized for the number of decay particles, oil absorbance curves, the concentration of dissolved decay content, and turbidity as per ASTM standards. The evolution of colloidal and dissolved decay contents is individually reported for ester fluids and mineral oils. The degradation in mineral oils has been witnessed by both dissolved and colloidal particles. The generation of colloidal particles following the degradation of ester fluids is almost negligible, whereas dissolved decay content is noticed with thermal degradation time. Importantly, the obtained results depict the ability of esters to dissolve more sludge. This is due to the high (oxidative) stability of ester leading to reduced radical decomposition products. Also, the temperature solvent nature of the ester group tends to dissolve sludge particles back to the liquid phase into the bulk liquid. [ABSTRACT FROM AUTHOR]

The intent of this work is to evaluate the influence of cellulose insulation paper on gassing tendency of transformer oil under electrical discharge conditions. For comprehensive enumeration, insulation oil was thermally stressed at 115°C as per ASTM D 1934 with a controlled thermal aging history. The thermally aged oils were considered for gassing tendency evaluation as per ASTM D 6180 (5 hours, 10 kV AC) in the presence of cellulose. Different cellulose Kraft paper proportions including 0, 10, 20, and 30% of aged oil were introduced in to discharge cell. Different cellulose proportions and aging conditions were considered to understand the impact of cellulose while understanding the decomposition aspects of insulation. Diagnostic measurements with those including dissolved gas analysis, moisture, interfacial tension, turbidity, dissolved decay contents, acidity, and dissipation factor were performed before and after gassing tendency evaluation. It was found that, cellulose paper aids significantly in increasing dissolved gases and moisture in oil during electrical discharge. Importantly, diagnostic measurements have shown the ability of paper to absorb certain decomposition products during the discharge process. [ABSTRACT FROM AUTHOR]

Transformers are one of the most strategic components in balancing the voltage levels and hence a high priority is given to their performance [1]. It is established that, insulation technology plays a critical role in judging the performance and service life in oil filled apparatus [2]. Performance of the insulation system depends mainly on the deterioration behavior of insulation oil and paper. The mechanisms that are responsible for premature aging of oil/paper insulation are almost the same in all the oil filled apparatus. Yet, there will be a significant difference in the intensity of the aging mechanisms in different apparatus. This intensity is attributable to rating, design, and duration of operation for different machines. The detailed discussions on these mechanisms are presented in the subsequent sections of this paper. However, aging of service insulants is unavoidable and is to be maintained at a lower rate or arrested to the greatest possible extent, such that, catastrophic failures and unscheduled outages may be mitigated [3]. Normally, utilities follow scheduled condition monitoring activities to avoid the consequences of premature aging. Hence, knowledge on these in-service condition monitoring activities will be helpful in understanding the exact deterioration rate of the insulation system. Real time in-service experience of several transformer fleets that belong to United Kingdom utilities are reported in [4]. An early degradation of insulation is noticed through increase in acidity and furan concentration in oil for several transformers in the fleet. Authors investigated this early degradation in different perspectives including loading conditions, manufacturers, and oil chemistry changes. It is inferred that changes in oil chemistry is an important attribute for early degradation and hence utilities are advised to adopt different asset management strategies for affected and unaffected transformers in a fleet. Recently, failure rate data of service aged transformer fleets of an Australian utility were analyzed to establish the relationship between aging and different failure types [5]. It is noticed that degradation of the insulation system will be rapid after 20 years of service aging thus entailing the frequent condition monitoring activities after 20 years to identify premature aging failures. [ABSTRACT FROM AUTHOR]

Study of alternate fluids for transformer and their combination with traditional ones is an interesting area of research. The intent of this work is to investigate the thermal ageing performance of ester oils (synthetic and natural), and mixed oil vis‐à‐vis mineral oil. All the samples were thermally stressed at 110, 140, 160, and 185°C for 2 weeks each. Dissolved decay contents in oil and linear thermal expansion coefficients of solid insulation have been studied using ultraviolet visible infrared spectroscopy and dilatometry analysis, respectively, as per ASTM standards. Change in functional groups of the insulation oils with ageing have been understood by Fourier transform infrared spectroscopy analysis. Additionally, diffusion of oil–moisture mixture into paper with ageing and the corresponding effect on dielectric strength of paper has been also examined using ASTM standards. It is observed that the use of synthetic ester (SE) and addition of SE to mineral insulating oil lead to improved performance of oil–paper insulation system with retarding the rate of degradation of the insulation system. [ABSTRACT FROM AUTHOR]

In this work, thermal aging aspects of mineral oil, ester oils (synthetic and natural), mixed oil have been reported. All the samples were thermally stressed at 110°C, 140°C, 160°C, and 185°C for 2 weeks each. Concentration of dissolved decay contents in oil, flash point of insulation oil, and linear thermal expansion coefficients of solid insulation with aging have been studied using ultraviolet visible spectroscopy, flash point and dilatometry analysis respectively. Change in functional groups of the insulation oils with aging have been understood by Fourier Transform Infrared Spectroscopy analysis. Additionally, diffusion of oil-moisture mixture into paper with aging and corresponding effect on dielectric strength of paper has been also examined. Further, design and monitoring aspects of ester and mixed oil filled transformers have been also emphasized. It is observed that ester dielectric fluids and ester content as an additive in mineral oil improves the performance of solid insulation. Importantly, blended oil offer an advantage of retarding the degradation of oil as well as solid insulation accompanied by reduced cost of oil when compared to pure synthetic esters. [ABSTRACT FROM AUTHOR]

Mineral oils have been used in transformers for cooling and insulation for many years. Despite their long-time success, mineral oils are facing critiques by the electrical power industry in terms of thermal performance?mineral oils have relatively low flashpoint and fire point and will burn in the event of a fault [1], [2], [3]; environmental performance?mineral oils are less biodegradable, toxic in nature, and hazardous in the soil and water [4]; and risk assessment?mineral oils are imperilling near hospitals, near high rise buildings, and in residential areas. [ABSTRACT FROM PUBLISHER]

Transformers are generally considered to be the costliest assets in a power network. The lifetime of a transformer is mainly attributable to the condition of its solid insulation, which in turn is measured and described according to the degree of polymerization (DP) of the cellulose. Since the determination of the DP index is complex and time-consuming and requires the transformer to be taken out of service, utilities prefer indirect and non-invasive methods of determining the DP based on the byproduct of cellulose aging. This paper analyzes solid insulation degradation by measuring the furan concentration, recently introduced methanol, and dissolved gases like carbon oxides and hydrogen, in the insulating oil. A group of service-aged distribution transformers were selected for practical investigation based on oil samples and different kinds of tests. Based on the maintenance and planning strategy of the power utility and a weighted combination of measured chemical indicators, a neural network was also developed to categorize the state of the transformer in certain classes. The method proved to be able to improve the diagnostic capability of chemical indicators, thus providing power utilities with more reliable maintenance tools and avoiding catastrophic failure of transformers. [ABSTRACT FROM AUTHOR]