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Your search keyword '"Dominic Schmid"' showing total 4 results
Start Over Author "Dominic Schmid" Topic inorganic chemistry
4 results on '"Dominic Schmid"'

1. Synthesis of a lithium–cyclopentadienide complex by addition of LiNTf2 to a zwitterionic fulvalene

Author

Doris Kunz, Klaus Eichele, Dominic Schmid, and Alexander Seyboldt

Subjects
Fulvalene, Structure analysis, 010405 organic chemistry, Chemistry, Chemical shift, Inorganic chemistry, Solid-state, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, 0104 chemical sciences, Inorganic Chemistry, chemistry.chemical_compound, Crystallography, Lithium, Benzene
Abstract

The synthesis of a η5-coordinated LiCp complex by simple addition of a Li-salt in benzene is presented. A strongly zwitterionic fulvalene serves as the Cp-precursor. Evidence for the coordination of Li+ was obtained by the characterisitic 7Li NMR chemical shifts, variable temperature experiments in solution and by X-ray structure analysis in the solid state.

Published
2017
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3. Reaction of Iron- and Tungsten Carbonyls with a Zwitterionic Fulvalene

Author

Alexander Seyboldt, Dominic Schmid, and Doris Kunz

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Fulvalene, Cyclopentadienyl complex, chemistry, Moiety, Infrared spectroscopy, chemistry.chemical_element, Irradiation, Tungsten, Fulvenes, Fulvalenes, Photochemistry
Abstract

The highly dipolar fulvalene 1 reacts with pentacarbonyl iron(0) and hexacarbonyl tungsten(0) complexes under irradiation with UV light. The cyclopentadienyl complexes 2 and 3 formed are analysed by means of NMR and IR spectroscopy as well as X-ray analysis. They are the first zwitterionic carbonyl complexes of fulvenes or fulvalenes. In the case of iron, the dinuclear complex 2 consisting of a dicarbonyliron(+I)-tetracarbonylferrat(–I) moiety is formed, whereas in the case of tungsten, the mononuclear tricarbonyl tungsten(0) complex 3 is obtained.

Published
2015
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4. ChemInform Abstract: Characterization of Ax[W6I14] as Key Compounds for Ligand-Substituted A2[W6I8L6] Clusters

Author

David Enseling, Markus Stroebele, Thomas Juestel, H.‐Juergen Meyer, Thorsten Hummel, and Dominic Schmid

Subjects
Crystallography, Chemistry, Ligand, Yield (chemistry), Inorganic chemistry, Solid-state, General Medicine, Crystallite, Alkali metal, Stoichiometry
Abstract

Polycrystalline Mx[W6I14] (M: Na, K, Rb, Cs) is prepared by solid state reaction of stoichiometric amounts of MI and W3I12 (

Published
2016
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